1,668 research outputs found
Electronic structure, vibrational stability, infra-red, and Raman spectra of B24N24 cages
We examine the vibrational stability of three candidate structures for the
B24N24 cage and report their infra-red (IR) and Raman spectra. The candidate
structures considered are a round cage with octahedral O symmetry, a cage with
S_4 symmetry that satisfies the isolated square rule, and a cage of S_8
symmetry, which combines the caps of the (4,4) nanotube, and contains two extra
squares and octagons. The calculations are performed within density functional
theory, at the all electron level, with large basis sets, and within the
generalized gradient approximation. The vertical ionization potential (VIP) and
static dipole polarizability are also reported. The
S_4 and S_8 cages are energetically nearly degenerate and are favored over
the O cage which has six extra octagons and squares. The IR and Raman spectra
of the three clusters show notable differences providing thereby a way to
identify and possibly synthesize the cages.Comment: (Uses Elsevier style file; To appear in Chemical Physics Letters
Two-Stage Rotational Disordering of a Molecular Crystal Surface: C60
We propose a two-stage mechanism for the rotational surface disordering phase
transition of a molecular crystal, as realized in C fullerite. Our
study, based on Monte Carlo simulations, uncovers the existence of a new
intermediate regime, between a low temperature ordered state,
and a high temperature disordered phase. In the intermediate
regime there is partial disorder, strongest for a subset of particularly
frustrated surface molecules. These concepts and calculations provide a
coherent understanding of experimental observations, with possible extension to
other molecular crystal surfaces.Comment: 4 pages, 2 figure
Raman scattering in C_{60} and C_{48}N_{12} aza-fullerene: First-principles study
We carry out large scale {\sl ab initio} calculations of Raman scattering
activities and Raman-active frequencies (RAFs) in
aza-fullerene. The results are compared with those of .
Twenty-nine non-degenerate polarized and 29 doubly-degenerate unpolarized RAFs
are predicted for . The RAF of the strongest Raman
signal in the low- and high-frequency regions and the lowest and highest RAFs
for are almost the same as those of .
The study of reveals the importance of electron correlations and
the choice of basis sets in the {\sl ab initio} calculations. Our best
calculated results for with the B3LYP hybrid density functional
theory are in excellent agreement with experiment and demonstrate the desirable
efficiency and accuracy of this theory for obtaining quantitative information
on the vibrational properties of these molecules.Comment: submitted to Phys.Rev.
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Studies of Bs2∗(5840)0 and Bs1(5830)0 mesons including the observation of the Bs2∗(5840)0→B0KS0 decay in proton-proton collisions at s=8TeV.
Measurements of Bs2∗(5840)0 and Bs1(5830)0 mesons are performed using a data sample of proton-proton collisions corresponding to an integrated luminosity of , collected with the CMS detector at the LHC at a centre-of-mass energy of 8TeV . The analysis studies P-wave Bs0 meson decays into B(∗)+K- and B(∗)0KS0 , where the B+ and B0 mesons are identified using the decays B+→J/ψK+ and B0→J/ψK∗(892)0 . The masses of the P-wave Bs0 meson states are measured and the natural width of the Bs2∗(5840)0 state is determined. The first measurement of the mass difference between the charged and neutral B∗ mesons is also presented. The Bs2∗(5840)0 decay to B0KS0 is observed, together with a measurement of its branching fraction relative to the Bs2∗(5840)0→B+K- decay
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Search for MSSM Higgs bosons decaying to μ+μ-in proton-proton collisions at √s=13TeV
A search is performed for neutral non-standard-model Higgs bosons decaying to two muons in the context of the minimal supersymmetric standard model (MSSM). Proton-proton collision data recorded by the CMS experiment at the CERN Large Hadron Collider at a center-of-mass energy of 13TeVwere used, corresponding to an integrated luminosity of 35.9fb-1. The search is sensitive to neutral Higgs bosons produced via the gluon fusion process or in association with a bbquark pair. No significant deviations from the standard model expectation are observed. Upper limits at 95% confidence level are set in the context of the mmod+hand phenomenological MSSM scenarios on the parameter tanβas a function of the mass of the pseudoscalar Aboson, in the range from 130 to 600GeV. The results are also used to set a model-independent limit on the product of the branching fraction for the decay into a muon pair and the cross section for the production of a scalar neutral boson, either via gluon fusion, or in association with bquarks, in the mass range from 130 to 1000GeV
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