28 research outputs found
Synthesis of α-hydroxy(polyprenyl) bisphosphonates
Get PDFBisphosphonates derived from natural terpenes were synthesized by phosphonylation of corresponding aldehydes. The general strategy of introduction of the phosphonate groups into the polyprenol molecule involves successive treatment of a hydroxyl compound by Swern reagent to oxidize the C-OH group into C=O and a (EtO)3P/[PyH]+ClO - 4 mixture to phosphylate the resulting carbonyl compound. © 2014 Pleiades Publishing, Ltd
Synthesis of α-hydroxy(polyprenyl) bisphosphonates
No full textBisphosphonates derived from natural terpenes were synthesized by phosphonylation of corresponding aldehydes. The general strategy of introduction of the phosphonate groups into the polyprenol molecule involves successive treatment of a hydroxyl compound by Swern reagent to oxidize the C-OH group into C=O and a (EtO)3P/[PyH]+ClO - 4 mixture to phosphylate the resulting carbonyl compound. © 2014 Pleiades Publishing, Ltd
Synthesis of α-hydroxy(polyprenyl) bisphosphonates
No full textBisphosphonates derived from natural terpenes were synthesized by phosphonylation of corresponding aldehydes. The general strategy of introduction of the phosphonate groups into the polyprenol molecule involves successive treatment of a hydroxyl compound by Swern reagent to oxidize the C-OH group into C=O and a (EtO)3P/[PyH]+ClO - 4 mixture to phosphylate the resulting carbonyl compound. © 2014 Pleiades Publishing, Ltd
Umsetzung von 1,5-Dimethyl-2,3,3,4-tetrachlor-1,5,2,4-diazadiphosphorinan-6-on mit Anilinderivaten, Heptamethyldisilazan und tert
No full textReactions of ethoxyethynylphosphines with phenyl azide and nucleophiles. 1,5-Alkylotropic migration in phosphorus(IV)-substituted ketene acetals
No full text
