22 research outputs found
Kinetics of the Rhodium‐Catalyzed Hydroaminomethylation of 1‐Decene in a Thermomorphic Solvent System
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Untersuchung zur Reaktionskinetik der Palladium-katalysierten Methoxycarbonylierung von 1-Decen in einem thermomorphen Loesungsmittelsystem
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Kinetic Modeling of Rhodium-Catalyzed Reductive Amination of Undecanal in Different Solvent Systems
Get PDFThe homogenously rhodium-catalyzed reductive amination of 1-undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization.Projekt DEAL 202
Kinetics of the palladium-catalyzed isomerizing methoxycarbonylation of long chain olefins in thermomorphic solvent systems
No full textMechanistic Kinetic Modelling of the Biocatalysed Formation of Galacto- Oligosaccharides with Enzymes of Different Origins
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