2 research outputs found
New Metal-Only Lewis Pairs: Elucidating the Electronic Influence of <i>N</i>-Heterocyclic Carbenes and Phosphines on the Dative Pt-Al Bond
The synthesis and full characterization of a new heteroleptic <i>N</i>-heterocyclic carbene (NHC)–phosphine platinum(0)
complex and formation of its corresponding alane adduct is reported.
The influence of the ligands on the Lewis basic properties was studied
via multinuclear NMR-spectroscopy, X-ray analyses, and density functional
theory (DFT) calculations. Consistently, the effect of changing the
halogens upon the Lewis acid properties of aluminum halides was studied
by X-ray analysis and DFT calculations
New Metal-Only Lewis Pairs: Elucidating the Electronic Influence of <i>N</i>-Heterocyclic Carbenes and Phosphines on the Dative Pt-Al Bond
The synthesis and full characterization of a new heteroleptic <i>N</i>-heterocyclic carbene (NHC)–phosphine platinum(0)
complex and formation of its corresponding alane adduct is reported.
The influence of the ligands on the Lewis basic properties was studied
via multinuclear NMR-spectroscopy, X-ray analyses, and density functional
theory (DFT) calculations. Consistently, the effect of changing the
halogens upon the Lewis acid properties of aluminum halides was studied
by X-ray analysis and DFT calculations