4,5,12,13-Tetrabromo[2.2]paracyclophane - A New Bis(aryne) Equivalent

The reaction of 2 with nBuLi at -78°C generates aryne intermediates within the aromatic rings of [2.2]paracyclophane which are trapped in Diels-Alder reactions with dienes like furan, 1,9-diphenylisobenzofuran, or cyclopentadiene. Reductive deoxygenation with low-valent titanium reagents or TMSI converts the adducts of furan and isobenzofuran into anti-[2.2]paracyclophanes 4 and 5, respectively. The reaction of two aryne intermediates with [2.2](2,5)furanophane (7) yields 8 with three [2.2]paracyclophane units arranged in a stair-like fashion; yet, in this compound the highly shielded oxygen atoms cannot be removed anymore by reduction

Irradiated atmospheres of accreting magnetic white dwarfs with an application to the polar AM Herculis

We present a pilot study of atmospheres of accreting magnetic white dwarfs irradiated by intense fluxes at ultraviolet to infrared wavelengths. The model uses a standard LTE stellar atmosphere code which is expanded by introducing an angle-dependent external radiation source. The present results are obtained for an external source with the spectral shape of a 10 000 K blackbody and a freely adjustable spectral flux. The model provides an explanation for the observed largely filled-up Lyman lines in the prototype polar AM Herculis during its high states. It also confirms the hypotheses (i) that irradiation by cyclotron radiation and other radiation sources is the principle cause for the large heated polar caps surrounding the accretion spots on white dwarfs in polars and (ii) that much of the reprocessed light appears in the far ultraviolet and not in the soft X-ray regime as suggested in the original simple theories. We also briefly discuss the role played by hard X-rays in heating the polar cap

Theory of ferromagnetism in (A,Mn)B semiconductors

A brief review of theory of ferromagnetism of dilute magnetic semiconductors of the form (A,Mn)B based on the double exchange model is first given. A systematic investigation of the phenomena extending the current theory is outlined. We begin with an investigation of the regions of instability of the nonmagnetic towards the ferromagnetic state of a system of Mn-atoms doped in AB-type semiconductor. A self-consistent many-body theory of the ferromagnetic state is then developed, going beyond the mean field approaches by including fluctuations of the Mn-spins and the itinerant hole-gas. A functional theory suitable for computation of system properties such as Curie temperature as a function of hole and the Mn-concentration, spin-current, etc. is formulated.Comment: 16 page

Diversity of chemistry and excitation conditions in the high-mass star forming complex W33

The object W33 is a giant molecular cloud that contains star forming regions at various evolutionary stages from quiescent clumps to developed H II regions. Since its star forming regions are located at the same distance and the primary material of the birth clouds is probably similar, we conducted a comparative chemical study to trace the chemical footprint of the different phases of evolution. We observed six clumps in W33 with the Atacama Pathfinder Experiment (APEX) telescope at 280 GHz and the Submillimeter Array (SMA) at 230 GHz. We detected 27 transitions of 10 different molecules in the APEX data and 52 transitions of 16 different molecules in the SMA data. The chemistry on scales larger than $\sim$0.2 pc, which are traced by the APEX data, becomes more complex and diverse the more evolved the star forming region is. On smaller scales traced by the SMA data, the chemical complexity and diversity increase up to the hot core stage. In the H II region phase, the SMA spectra resemble the spectra of the protostellar phase. Either these more complex molecules are destroyed or their emission is not compact enough to be detected with the SMA. Synthetic spectra modelling of the H$_{2}$CO transitions, as detected with the APEX telescope, shows that both a warm and a cold component are needed to obtain a good fit to the emission for all sources except for W33 Main1. The temperatures and column densities of the two components increase during the evolution of the star forming regions. The integrated intensity ratios N$_{2}$H$^{+}$(3$-$2)/CS(6$-$5) and N$_{2}$H$^{+}$(3$-$2)/H$_{2}$CO(4$_{2,2}$$-$3$_{2,1}$) show clear trends as a function of evolutionary stage, luminosity, luminosity-to-mass ratio, and H$_{2}$ peak column density of the clumps and might be usable as chemical clocks.Comment: 66 pages, 28 figures, 8 tables, accepted for publication at A&

Influence of non-local exchange on RKKY interactions in III-V diluted magnetic semiconductors

The RKKY interaction between substitutional Mn local moments in GaAs is both spin-direction-dependent and spatially anisotropic. In this Letter we address the strength of these anisotropies using a semi-phenomenological tight-binding model which treats the hybridization between Mn d-orbitals and As p-orbitals perturbatively and accounts realistically for the non-local exchange interaction between their spins. We show that exchange non-locality, valence-band spin-orbit coupling, and band-structure anisotropy all play a role in determining the strength of both effects. We use these results to estimate the degree of ground-state magnetization suppression due to frustrating interactions between randomly located Mn ions.Comment: 4 pages RevTeX, 2 figures included, v2: replacement because of font proble

APP Expression in Primary Neuronal Cell Cultures fromP6 Mice during in vitro Differentiation

Primary neuronal cell cultures from P6 mice were investigated in order to study amyloid protein precursor (APP) gene expression in differentiating neurons. Cerebellar granule cells which strongly express APP 695 allowed the identification of three distinct isoforms of neuronal APP 695. The high-molecular-weight form of APP 695 is sialylated. The expression pattern of neuronal APP 695 changes during in vitro differentiation. Sialylated forms become more abundant upon longer cultivation time. The secreted forms of sialylated, neuronal APP 695 are shown to comigrate with APP isolated from cerebrospinal fluid. We suggest that the different sialylation states of APP 695 may reflect the modulation of cell-cell and cell-substrate interactions during in vitro differentiation and regeneration

Cotunneling at resonance for the single-electron transistor

We study electron transport through a small metallic island in the perturbative regime. Using a recently developed diagrammatic technique, we calculate the occupation of the island as well as the conductance through the transistor in forth order in the tunneling matrix elements, a process referred to as cotunneling. Our formulation does not require the introduction of a cut-off. At resonance we find significant modifications of previous theories and good agreement with recent experiments.Comment: 5 pages, Revtex, 5 eps-figure