Fabrication of Well-Defined Mushroom-Shaped Structures for Biomimetic Dry Adhesive by Conventional Photolithography and Molding

Biomimetic dry adhesives have many attractive features, such as reversible and repeatable adhesion against various surfaces. This paper presents a method for the simple fabrication of biomimetic dry adhesives composed of a mushroom-shaped structure, which is based on conventional photolithography and molding. Firstly a masked and a maskless exposure are performed on the top and bottom of a photoresist, respectively, that generates microholes with an undercut after development. This structured photoresist is then used for molding, leading to mushroom-shaped structural features after sacrificing the photoresist. Because of the convenience of photolithography, the proposed method has the potential to fabricate various dry adhesives cost-efficiently

Adhesion Circle: A New Approach To Better Characterize Directional Gecko-Inspired Dry Adhesives

The number of different designs of directional gecko-inspired adhesives has proliferated over the past 15 years, but some basic characterization tools are still nonstandardized, which can make direct comparisons of different adhesives in the literature difficult. By far the most common type of test for directional adhesives, the load-drag-pull (LDP) test is useful but can miss substantial information on the exact behavior of gecko-inspired adhesives in a variety of loading conditions. Other test techniques, including angled approaches and pull-offs, have been employed by a few groups but they are not as widely adopted; peel tests can be employed but require a larger amount of adhesive material to use in the test, which is not always practical given some current manufacturing constraints. Very few tests have looked at the effect of off-main axis loads on the performance of directional adhesives, however, and this quality of performance may be very important in applications where direct control over displacements or angle of pull-off in pitch and yaw of the peeling interface may not be practical or possible. To address this overlooked area of characterization, we introduce a new test concept for anisotropic adhesives, the adhesion circle, and also compare how the radial normal adhesion performance is altered depending on whether the pull-off comes after a displacement drag or when pulled at a constant angle from vertical after a preload. Testing directional adhesive designs made with different geometries shows that unexpected behaviors at pull-off angles not in the direction of the strong–weak axis can sometimes be seen. The complete adhesion circle tests should help better design directional adhesives for scaled up performance, and can be completed with relatively simple hardware that is typically used in most current directional adhesive tests

Electrically Templated Dewetting of a UV-Curable Prepolymer Film for the Fabrication of a Concave Microlens Array with Well-Defined Curvature

This paper presents an economic method, based on electrically templated dewetting of a UV-curable prepolymer, for fabricating a concave microlens array (MLA) of high quality and high density. In our strategy, a voltage is applied to an electrode pair consisting of a conductive substrate coated with a UV-curable prepolymer film and a microhole-arrayed silicon template, sandwiching an air gap, to dewet the prepolymer film into a curved air–liquid interface. At or beyond a critical voltage, the curved prepolymer can be pulled quickly into contact with the protrusive underside of the silicon template. Contact of the prepolymer with the template can be detected by monitoring the leaky current in the polymer, followed by a UV curing of the prepolymer. Finally, by separating the mold from the solidified polymer, a concave MLA is obtained. The curvature of the MLA can be well-defined simply by changing the air gap between the mold and prepolymer film. Besides, the dewetting strategy results in a much smaller adhesion area between the mold and solidified polymer structures, which allows for easy separation of the mold from the MLA in a large-area operation

Electrically Modulated Microtransfer Molding for Fabrication of Micropillar Arrays with Spatially Varying Heights

The ability to generate a large area micropillar array with spatially varying heights allows for exploring numerous new interesting applications in biotechnology, surface engineering, microfluidics, and so forth. This Letter presents a clever and straightforward method, called electrically modulated microtransfer molding (EM3), for generating such unique microstructures from a silicon mold arrayed with microholes. The key to the process is an application of electrically tunable wettability caused by a spatially modulated voltage, which electrohydrodynamically drives a photocurable and dielectric prepolymer to fill the microholes to a depth depending on the voltage amplitude. Using EM3, micropillar arrays with stepwise or continuously varying heights are successfully fabricated, with the diameter scalable to 1.5 μm and with the maximum height being equal to the depth of the high-aspect-ratio (more than 10:1) microholes

UV-Catalytic Preparation of Polypyrrole Nanoparticles Induced by H₂O₂

As a green oxidant, H₂O₂ can be used to induce the polymerization of pyrrole. This approach avoids the issue of metal residue in the polymer caused by metal oxidants, whereas the reaction efficiency is low and the corresponding reaction mechanism not clear. In this study, uniform polypyrrole (PPy) nanoparticles were prepared using H₂O₂ as an oxidant under UV irradiation in the presence of polyvinylpyrrolidone (PVP). The morphology characterization indicated that the spherical PPy nanoparticles were capped by a PVP shell. Through the investigation of reaction process, it was found that the photolysis of H₂O₂ led to the formation of hydroxyl radicals, which then initiated the oxidative polymerization of pyrrole. The coalescence of small PPy particles formed nanoparticles which were stabilized by PVP. The effects of several reaction conditions on the polymerization rate and the size distribution of nanoparticles were investigated in detail, including radiation intensity (0–30 W), temperature (0–50 °C), and the concentrations of PVP (5–20 g/L), H₂O₂ (0.06–0.6 M), H₂SO₄ (0–0.<i>2</i>2 M), and the monomer pyrrole (0.03–0.2 M), respectively. UV-catalytic preparation of PPy nanoparticles induced by H₂O₂ is an effective and environmentally friendly approach, which could be expected to be extended to other conductive polymers

Polydopamine-Coated Main-Chain Liquid Crystal Elastomer as Optically Driven Artificial Muscle

Optically driven active materials have received much attention because their deformation and motion can be controlled remotely, instantly, and precisely in a contactless way. In this study, we investigated an optically actuated elastomer with rapid response: polydopamine (PDA)-coated liquid crystal elastomer (LCE). Because of the photothermal effect of PDA coating and thermal responsiveness of LCE, the elastomer film contracted significantly with near-infrared (NIR) irradiation. With a fixed strain, light-induced actuating stress in the film could be as large as 1.5 MPa, significantly higher than the maximum stress generated by most mammalian skeletal muscle (0.35 MPa). The PDA-coated LCE films could also bend or roll up by surface scanning of an NIR laser. The response time of the film to light exposure could be as short as 1/10 of a second, comparable to or even faster than that of mammalian skeletal muscle. Using the PDA-coated LCE film, we designed and fabricated a prototype of robotic swimmer that was able to swim near the water–air interface by performing “swimming strokes” through reversible bending and unbending motions induced and controlled by an NIR laser. The results presented in this study clearly demonstrated that PDA-coated LCE is a promising optically driven artificial muscle, which may have great potential for applications of soft robotics and optomechanical coupling devices

Polydopamine-Coated Main-Chain Liquid Crystal Elastomer as Optically Driven Artificial Muscle

Optically driven active materials have received much attention because their deformation and motion can be controlled remotely, instantly, and precisely in a contactless way. In this study, we investigated an optically actuated elastomer with rapid response: polydopamine (PDA)-coated liquid crystal elastomer (LCE). Because of the photothermal effect of PDA coating and thermal responsiveness of LCE, the elastomer film contracted significantly with near-infrared (NIR) irradiation. With a fixed strain, light-induced actuating stress in the film could be as large as 1.5 MPa, significantly higher than the maximum stress generated by most mammalian skeletal muscle (0.35 MPa). The PDA-coated LCE films could also bend or roll up by surface scanning of an NIR laser. The response time of the film to light exposure could be as short as 1/10 of a second, comparable to or even faster than that of mammalian skeletal muscle. Using the PDA-coated LCE film, we designed and fabricated a prototype of robotic swimmer that was able to swim near the water–air interface by performing “swimming strokes” through reversible bending and unbending motions induced and controlled by an NIR laser. The results presented in this study clearly demonstrated that PDA-coated LCE is a promising optically driven artificial muscle, which may have great potential for applications of soft robotics and optomechanical coupling devices

Polydopamine-Coated Main-Chain Liquid Crystal Elastomer as Optically Driven Artificial Muscle

Optically driven active materials have received much attention because their deformation and motion can be controlled remotely, instantly, and precisely in a contactless way. In this study, we investigated an optically actuated elastomer with rapid response: polydopamine (PDA)-coated liquid crystal elastomer (LCE). Because of the photothermal effect of PDA coating and thermal responsiveness of LCE, the elastomer film contracted significantly with near-infrared (NIR) irradiation. With a fixed strain, light-induced actuating stress in the film could be as large as 1.5 MPa, significantly higher than the maximum stress generated by most mammalian skeletal muscle (0.35 MPa). The PDA-coated LCE films could also bend or roll up by surface scanning of an NIR laser. The response time of the film to light exposure could be as short as 1/10 of a second, comparable to or even faster than that of mammalian skeletal muscle. Using the PDA-coated LCE film, we designed and fabricated a prototype of robotic swimmer that was able to swim near the water–air interface by performing “swimming strokes” through reversible bending and unbending motions induced and controlled by an NIR laser. The results presented in this study clearly demonstrated that PDA-coated LCE is a promising optically driven artificial muscle, which may have great potential for applications of soft robotics and optomechanical coupling devices

Spray-Coated CsPbBr₃ Quantum Dot Films for Perovskite Photodiodes

Large-area film deposition and high material utilization ratio are the crucial factors for large-scale application of perovskite optoelectronics. Recently, all-inorganic halide perovskite CsPbBr₃ has attracted great attention because of its high phase stability, thermal stability, and photostability. However, most reported perovskite devices were fabricated by spin-coating, suffering from a low material utilization ratio of 1% and a small coverage area. Here, we developed a spray-coating technique to fabricate a CsPbBr₃ quantum dot (QD) film photodiode which had a high material utilization ratio of 32% and a deposition rate of 9 nm/s. The film growth process was studied, and substrate temperature and spray time were two key factors for the deposition of uniform and crack-free QD films. The spray-coated photodiode was demonstrated to be more suitable for working in the photodetector mode because a low dark current density of 4 × 10^–4 mA cm^–2 resulting from an extremely low recombination current contributed to a high detectivity of 1 × 10¹⁴ Jones. A high responsivity of 3 A W^–1 was obtained at −0.7 V under 365 nm illumination, resulting from a low charge-transfer resistance and a high charge recombination resistance. We believe that the spray deposition technique will benefit the fabrication of perovskite QD film optoelectronics on a large scale

Polydopamine-Coated Main-Chain Liquid Crystal Elastomer as Optically Driven Artificial Muscle

Optically driven active materials have received much attention because their deformation and motion can be controlled remotely, instantly, and precisely in a contactless way. In this study, we investigated an optically actuated elastomer with rapid response: polydopamine (PDA)-coated liquid crystal elastomer (LCE). Because of the photothermal effect of PDA coating and thermal responsiveness of LCE, the elastomer film contracted significantly with near-infrared (NIR) irradiation. With a fixed strain, light-induced actuating stress in the film could be as large as 1.5 MPa, significantly higher than the maximum stress generated by most mammalian skeletal muscle (0.35 MPa). The PDA-coated LCE films could also bend or roll up by surface scanning of an NIR laser. The response time of the film to light exposure could be as short as 1/10 of a second, comparable to or even faster than that of mammalian skeletal muscle. Using the PDA-coated LCE film, we designed and fabricated a prototype of robotic swimmer that was able to swim near the water–air interface by performing “swimming strokes” through reversible bending and unbending motions induced and controlled by an NIR laser. The results presented in this study clearly demonstrated that PDA-coated LCE is a promising optically driven artificial muscle, which may have great potential for applications of soft robotics and optomechanical coupling devices