1 research outputs found
Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with <i>N</i>‑Acyloxyphthalimides
A visible-light-mediated decarboxylative
cyclization of <i>N</i>-acyloxylphthalimides with vinyl
azides has been developed
under metal-free conditions. This protocol features mild conditions,
a broad substrate scope, and an excellent functional group tolerance,
thus providing a facile and efficient access to substituted phenanthridines.
Control experiments revealed that the reaction proceeded via a radical
process