2 research outputs found
Porous Field-Effect Transistors Based on a Semiconductive Metal–Organic Framework
Recently,
the emergence of conductive metal–organic frameworks
(MOFs) has given great prospects for their applications as active
materials in electronic devices. In this work, a high-quality, free-standing
conductive MOF membrane was prepared by an air–liquid interfacial
growth method. Accordingly, field-effect transistors (FETs) possessing
a crystalline microporous MOF channel layer were successfully fabricated
for the first time. The porous FETs exhibited p-type behavior, distinguishable
on/off ratios, and excellent field-effect hole mobilities as high
as 48.6 cm<sup>2</sup> V<sup>–1</sup> s<sup>–1</sup>, which is even comparable to the highest value reported for solution-processed
organic or inorganic FETs
Immobilization of Volatile and Corrosive Iodine Monochloride (ICl) and I<sub>2</sub> Reagents in a Stable Metal–Organic Framework
The
major discovery here is a robust and water-stable metal–organic
framework (MOF) material capable of reversible binding of the volatile
and reactive molecules of ICl and I<sub>2</sub>. The immobilization
of I<sub>2</sub> and ICl, as well as their controllable release thus
achieved, is to facilitate the wide-ranging applications of these
volatile species as catalysts and reagents in chemical and industrial
processes. The framework material TMBP·CuI (hereafter TCuI) can
be conveniently prepared in quantitative yields by heating CuI and
the organic linker TMBP (3,3′,5,5′-tetramethyl-4,4′-bipyrazol)
in acetonitrile. The microporous three-dimensional net of TCuI features
CuI chains that contribute to efficient and reversible binding of
ICl and I<sub>2</sub> molecules, to result in the stoichiometrically
well-defined adducts of TCuI·ICl and TCuI·I<sub>2</sub>,
respectively. Moreover, the confinement of a volatile compound like
ICl within the MOF medium provides unique opportunities to enhance
its reactivity and selectivity as a chemical reagent, as is exemplified
by the iodination reactions examined herein. With this exemplary study,
we intend to stimulate interest in further exploring MOFs and other
porous media (e.g., porous polymers) for entrapping ICl and other
volatile reagents (e.g., Br<sub>2</sub>, SCl<sub>2</sub>, S<sub>2</sub>Cl<sub>2</sub>, and SOCl<sub>2</sub>) and for potentially novel reactivity
associated with the porous medium