50 research outputs found
Synthesis and crystal structures of palladium complexes based on -amino-oximes derived from ()-limonene and their application in allylic alkylation of 1,3-dioxo compounds
Coordination compounds Pd(L1)Cl, Pd(L2)Cl, and Pd(L3)Cl have been synthesized from optically pure -amino-oxime ligands L1–L3 based on -limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These -amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds
Synthesis and crystal structures of palladium complexes based on -amino-oximes derived from ()-limonene and their application in allylic alkylation of 1,3-dioxo compounds
Coordination compounds Pd(L1)Cl, Pd(L2)Cl, and Pd(L3)Cl have been synthesized from optically pure -amino-oxime ligands L1–L3 based on -limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These -amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds
Synthesis of chiral bifunctional ligands based on α-pinene and their use in ruthenium catalyzed asymmetric transfer hydrogenation
Diabetes care in Switzerland: good, but perfectible: a population-based cross-sectional survey
Chiral ionic liquids just not a solvent: evidence of supramolecular assistance in organometallic catalysis
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Medium impact on organometallic catalytic reactions : application of imidazolium liqui salts as chiral supramolecular networks
Effet supramoléculaire des triflates d'imidazoliums chiraux sur les propriétés intrinsèques du système catalytique palladium/phosphine en alkylation allylique
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Assistance supramoleculaire des sels d'imidazolium chiraux en catalyse organométallique
Nouvelles avancées pour la synthèse d’éthers insaturés dérivés de polyols par transformation du butadiène
National audienc
Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction
International audienceThe catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono- and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers