3 research outputs found
Efficient Polymer Solar Cells Enabled by Low Temperature Processed Ternary Metal Oxide as Electron Transport Interlayer with Large Stoichiometry Window
Highly efficient organic photovoltaic
cells are demonstrated by
incorporating low temperature solution processed indium zinc oxide
(IZO) as cathode interlayers. The IZOs are synthesized using a combustion
synthesis method, which enables low temperature processes (150–250
°C). We investigated the IZO films with different electron mobilities
(1.4 × 10<sup>–3</sup> to 0.23 cm<sup>2</sup>/(V·s)),
hydroxide–oxide content (38% to 47%), and surface roughness
(0.19–5.16 nm) by modulating the ternary metal oxide stoichiometry.
The photovoltaic performance was found to be relatively insensitive
to the composition ratio of In:Zn over the range of 0.8:0.2 to 0.5:0.5
despite the differences in their electrical and surface properties,
achieving high power conversion efficiencies of 6.61%–7.04%.
Changes in composition ratio of IZO do not lead to obvious differences
in energy levels, diode parameters and morphology of the photoactive
layer, as revealed by ultraviolet photoelectron spectroscopy (UPS),
dark current analysis and time-of-flight secondary ion mass spectrometry
(TOF-SIMS) measurements, correlating well with the large IZO stoichiometry
window that enables efficient photovoltaic devices. Our results demonstrate
the robustness of this ETL system and provide a convenient approach
to realize a wide range of multicomponent oxides and compatible with
processing on flexible plastic substrates
Improving the Efficiency of Hematite Nanorods for Photoelectrochemical Water Splitting by Doping with Manganese
Here,
we report a significant improvement of the photoelectrochemical
(PEC) properties of hematite (α-Fe<sub>2</sub>O<sub>3</sub>)
to oxidize water by doping with manganese. Hematite nanorods were
grown on a fluorine-treated tin oxide (FTO) substrate by a hydrothermal
method in the presence on Mn. Systematic physical analyses were performed
to investigate the presence of Mn in the samples. Fe<sub>2</sub>O<sub>3</sub> nanorods with 5 mol % Mn treatment showed a photocurrent
density of 1.6 mA cm<sup>–2</sup> (75% higher than that of
pristine Fe<sub>2</sub>O<sub>3</sub>) at 1.23 V versus RHE and a plateau
photocurrent density of 3.2 mA cm<sup>–2</sup> at 1.8 V versus
RHE in a 1 M NaOH electrolyte solution (pH 13.6). We attribute the
increase in the photocurrent density, and thus in the oxygen evolving
capacity, to the increased donor density resulting from Mn doping
of the Fe<sub>2</sub>O<sub>3</sub> nanorods, as confirmed by Mott–Schottky
measurement, as well as the suppression of electron–hole recombination
and enhancement in hole transport, as detected by chronoamperometry
measurements