Wideband saturable absorption in few-layer molybdenum diselenide (MoSe₂) for Q-switching Yb-, Er- and Tm-doped fiber lasers.

We fabricate a free-standing molybdenum diselenide (MoSe2) saturable absorber by embedding liquid-phase exfoliated few-layer MoSe2 flakes into a polymer film. The MoSe2-polymer composite is used to Q-switch fiber lasers based on ytterbium (Yb), erbium (Er) and thulium (Tm) gain fiber, producing trains of microsecond-duration pulses with kilohertz repetition rates at 1060 nm, 1566 nm and 1924 nm, respectively. Such operating wavelengths correspond to sub-bandgap saturable absorption in MoSe2, which is explained in the context of edge-states, building upon studies of other semiconducting transition metal dichalcogenide (TMD)-based saturable absorbers. Our work adds few-layer MoSe2 to the growing catalog of TMDs with remarkable optical properties, which offer new opportunities for photonic devices.EJRK and TH acknowledge support from the Royal Academy of Engineering (RAEng), through RAEng Fellowships.This is the author accepted manuscript. The final version is available from the Optical Society of Amercia via http://dx.doi.org/ via http://dx.doi.org/10.1364/OE.23.02005

Few-layer MoS<inf>2</inf> saturable absorbers for short-pulse laser technology: Current status and future perspectives [Invited]

Few-layer molybdenum disul de (MoS2) is emerging as a promising quasi-two-dimensional material, further extending the library of suitable layered nanomaterials with exceptional optical properties for use in saturable absorber devices that enable short-pulse generation in laser systems. In this article, we catalog and review the nonlinear optical properties of few-layer MoS2, summarize recent progress in processing and integration into saturable absorber devices and comment on the current status and future perspectives of MoS2-based pulsed lasers.The authors would like to thank J. R. Taylor for fruitful discussions. EJRK and TH acknowledge support from the Royal Academy of Engineering (RAEng).This is the author accepted manuscript. The final version is available from OSA via https://www.osapublishing.org/prj/abstract.cfm?URI=prj-3-2-A30

Inkjet-printed graphene electrodes for dye-sensitized solar cells

We present a stable inkjet printable graphene ink, formulated in isopropyl alcohol via liquid phase exfoliation of chemically pristine graphite with a polymer stabilizer. The rheology and low deposition temperature of the ink allow uniform printing. We use the graphene ink to fabricate counter electrodes (CE) for natural and ruthenium-based dye-sensitized solar cells (DSSCs). The repeatability of the printing process for the CEs is demonstrated through an array of inkjet-printed graphene electrodes, with ∼5% standard deviation in the sheet resistance. As photosensitizers, we investigate natural tropical dye extracts from Pennisetum glaucum, Hibiscus sabdariffa and Caesalpinia pulcherrima. Among the three natural dyes, we find extracts from C. pulcherrima exhibit the best performance, with ∼0.9% conversion efficiency using a printed graphene CE and a comparable ∼1.1% efficiency using a platinum (Pt) CE. When used with N719 dye, the inkjet-printed graphene CE shows a ∼3.0% conversion efficiency, compared to ∼4.4% obtained using Pt CEs. Our results show that inkjet printable graphene inks, without any chemical functionalization, offers a flexible and scalable fabrication route, with a material cost of only ∼2.7% of the equivalent solution processed Pt-based electrodes.Authors acknowledge support from CAPREX, Cambridge Africa Alborada Fund, Carnegie-University of Ghana Next Generation of Africa Academics programme and the Royal Academy of Engineering (RAEng) through a research fellowship (Graphlex)

Solution processed MoS2-PVA composite for sub-bandgap mode-locking of a wideband tunable ultrafast Er:fiber laser

Abstract We fabricate a free-standing few-layer molybdenum disulfide (MoS2)-polymer composite by liquid phase exfoliation of chemically pristine MoS2 crystals and use this to demonstrate a wideband tunable, ultrafast mode-locked fiber laser. Stable, picosecond pulses, tunable from 1,535 nm to 1,565 nm, are generated, corresponding to photon energies below the MoS2 material bandgap. These results contribute to the growing body of work studying the nonlinear optical properties of transition metal dichalcogenides that present new opportunities for ultrafast photonic applications.MZ wishes to acknowledge funding from the EPSRC (EP/K03705), RCTH from the EPSRC (EP/G037221/1), GH from a CSC Cambridge International Scholarship, EJRK from the Royal Academy of Engineering (RAEng), through a RAEng Fellowship and TH from the RAEng (Graphlex).This is the final version. It was first published by Springer at http://link.springer.com/article/10.1007%2Fs12274-014-0637-

CMOS integration of inkjet-printed graphene for humidity sensing.

We report on the integration of inkjet-printed graphene with a CMOS micro-electro-mechanical-system (MEMS) microhotplate for humidity sensing. The graphene ink is produced via ultrasonic assisted liquid phase exfoliation in isopropyl alcohol (IPA) using polyvinyl pyrrolidone (PVP) polymer as the stabilizer. We formulate inks with different graphene concentrations, which are then deposited through inkjet printing over predefined interdigitated gold electrodes on a CMOS microhotplate. The graphene flakes form a percolating network to render the resultant graphene-PVP thin film conductive, which varies in presence of humidity due to swelling of the hygroscopic PVP host. When the sensors are exposed to relative humidity ranging from 10-80%, we observe significant changes in resistance with increasing sensitivity from the amount of graphene in the inks. Our sensors show excellent repeatability and stability, over a period of several weeks. The location specific deposition of functional graphene ink onto a low cost CMOS platform has the potential for high volume, economic manufacturing and application as a new generation of miniature, low power humidity sensors for the internet of things.S.S. acknowledges Department of Science and Technology (DST), India for Ramanujan Fellowship to support the work (project no. SR/S2/RJN-104/2011). This work was (partly) supported through the EU FP7 project MSP (611887). T.H. acknowledges support from the Royal Academy of Engineering through a fellowship (Graphlex).This is the final version of the article. It was first available from NPG via http://dx.doi.org/10.1038/srep1737

102 fs pulse generation from a long-term stable, inkjet-printed black phosphorus-mode-locked fiber laser.

We demonstrate a long-term stable, all-fiber, erbium-doped femtosecond laser mode-locked by a black phosphorus saturable absorber. The saturable absorber, fabricated by scalable and highly controllable inkjet printing technology, exhibits strong nonlinear optical response and is stable for long-term operation against intense irradiation, overcoming a key drawback of this material. The oscillator delivers self-starting, 102 fs stable pulses centered at 1555 nm with 40 nm spectral bandwidth. This represents the shortest pulse duration achieved from black phosphorus in a fiber laser to date. Our results demonstrate the great potential for black phosphorus as an excellent candidate for long-term stable ultrashort pulse generation

Ultrafast nonlinear photoresponse of single-wall carbon nanotubes: a broadband degenerate investigation.

Understanding of the fundamental photoresponse of carbon nanotubes has broad implications for various photonic and optoelectronic devices. Here, Z-scan and pump-probe spectroscopy performed across 600-2400 nm were combined to give a broadband 'degenerate' mapping of the nonlinear absorption properties of single-wall carbon nanotubes (SWNTs). In contrast to the views obtained from non-degenerate techniques, sizable saturable absorption is observed from the visible to the near-infrared range, including the spectral regions between semiconducting excitonic peaks and metallic tube transitions. In addition, the broadband mapping unambiguously reveals a photobleaching to photoinduced absorption transition feature within the first semiconducting excitonic band ∼2100 nm, quantitatively marking the long-wavelength cut-off for saturable absorption of the SWNTs investigated. Our findings present a much clearer physical picture of SWNTs' nonlinear absorption characteristics, and help provide updated design guidelines for SWNT based nonlinear optical devices.This work is supported by the National Key Basic Research Program of China (2014CB921101), the National Natural Science Foundation of China (61378025,61450110087,61427812,51522201,11474006), Jiangsu Province Shuangchuang Team program, and State Key Laboratory of Advanced Optical Communication Systems Networks, ChinaThis is the author accepted manuscript. The final version is available from the Royal Society of Chemistry via http://dx.doi.org/10.1039/C6NR00652

New Approach for Thickness Determination of Solution-Deposited Graphene Thin Films

Solution processing-based fabrication techniques such as liquid phase exfoliation may enable economically feasible utilization of graphene and related nanomaterials in real-world devices in the near future. However, measurement of the thickness of the thin film structures fabricated by these approaches remains a significant challenge. By using surface plasmon resonance (SPR), a simple, accurate, and quick measurement of the deposited thickness for inkjet-printed graphene thin films is reported here. We show that the SPR technique is convenient and well-suited for the measurement of thin films formulated from nanomaterial inks, even at sub-10 nm thickness. We also demonstrate that the analysis required to obtain results from the SPR measurements is significantly reduced compared to that required for atomic force microscopy (AFM) or stylus profilometer, and much less open to interpretation. The gathered data implies that the film thickness increases linearly with increasing number of printing repetitions. In addition, SPR also reveals the complex refractive index of the printed thin films composed of exfoliated graphene flakes, providing a more rigorous explanation of the optical absorption than that provided by a combination of AFM/profilometer and the extinction coefficient of mechanically exfoliated graphene flakes. Our results suggest that the SPR method may provide a new pathway for the thickness measurement of thin films fabricated from any nanomaterial containing inks.We acknowledge Dr. Lauri Riuttanen for the development of the code for the Metropolis fitting algorithm that we have modified for this work. H.J. acknowledges the Jenny ja Antti Wihuri foundation for the funding used for the research visit to Cambridge which facilitated this work. T.A.-O. acknowledges funding from EPSRC grant EP/L016087/1. H.Y. acknowledges funding from China Scholarship Council and Nokia Foundation. G.H. acknowledges funding from Cambridge Trust and China Scholarship Council. S.A. acknowledges the Scientific and Technological Research Council of Turkey (TÜBİTAK). R.C.T.H. acknowledges funding from an EPSRC Cambridge NanoDTC Translational Fellowship (EPSRC grant EP/G037221/1). Z.S. acknowledges funding from the European Union’s Seventh Framework Programme (REA grant agreement No. 631610), the Academy of Finland (Nos.: 276376, 284548, 295777), TEKES (OPEC), Nokia foundation, and Aalto University. T.H. acknowledges funding from RAEng Fellowship (Graphlex)

Inkjet Printed Large-Area Flexible Few-Layer Graphene Thermoelectrics

Graphene-based organic nanocomposites have ascended as promising candidates for thermoelectric energy conversion. In order to adopt existing scalable printing methods for developing thermostable graphene-based thermoelectric devices, optimizations of both the material ink and the thermoelectric properties of the resulting films are required. Here, inkjet printed large-area flexible graphene thin films with outstanding thermoelectric properties are reported. The thermal and electronic transport properties of the films reveal the so-called phonon-glass electron-crystal character (i.e. electrical transport behaviour akin to that of few-layer graphene flakes with quenched thermal transport arising from the disordered nanoporous structure). As a result, the all-graphene films show a room-temperature thermoelectric power factor of 18.7 µW m−1 K−2, representing over a three-fold improvement to previous solution-processed all-graphene structures. Our demonstration of inkjet printed thermoelectric devices underscores the potential for future flexible, scalable and low-cost thermoelectric applications, such as harvesting energy from body heat in wearable applications.EPSRC (EP/L016087/1) Royal Academy of Engineering (Graphlex