4 research outputs found
Determination of Mass Transfer Coefficient of Methane in Heavy Oil-Saturated Unconsolidated Porous Media Using Constant-Pressure Technique
Measuring
the solubility and diffusivity of methane in porous media
saturated with oil is critical for analyzing the process of solvent-based
recovery of heavy oil reservoir. In this study, a modified pressure-pulse
decay (PPD) method is presented to measure the mass transfer coefficients
of methane in porous media saturated with heavy oil as well as the
solubility and diffusivity of methane in bulk oil under the same experimental
conditions as those used in a comparison. The experiments are conducted
under constant boundary pressure in a PVT cell, and the pressure is
controlled using an auto pump, which continuously compresses the volume
of an intermediate container. The accumulated volume change instead
of the pressure change is recorded with time. The nonequilibrium boundary
condition (BC) model is used to analyze the experimental process.
The general solution of the mathematical model is derived using the
Laplace transform and the approximate analytical solution of the accumulated
dissolved gas is further presented for post processing of the experimental
data. The mass transfer coefficients are estimated through using a
multilevel single-linkage (MLSL) method to match the approximate solution
with the recorded experimental data. The estimation of the parameters
shows that the mass transfer coefficients are pressure dependent and
that a high boundary pressure contributes to the mass transfer of
methane in heavy oil due to a reduction in viscosity or density. The
interface mass transfer coefficient (<i>k</i><sub>int</sub>) and interface saturated concentration (<i>c</i><sub>int</sub>) in porous media saturated with oil and bulk oil are almost the
same under the same experimental conditions. The sensitivity analysis
shows that the increase of the effective diffusion coefficient (<i>D</i><sub>eff</sub>) and <i>k</i><sub>int</sub> contributes
to enhancing the rate of mass transfer in the oil phase and that Henry’s
law constant (<i>H</i>) has no effect on the equilibrium
time but only affects the initial saturated concentration at the interface
or the total dissolved gas. The modified PPD method is robust, efficient,
and easy to use in the laboratory
Effect of PEO-PPO-ph-PPO-PEO and PPO-PEO-ph-PEO-PPO on the Rheological and EOR Properties of Polymer Solutions
The
rheological properties of partially hydrolyzed polyacrylamide
(HPAM) and PEO-PPO-ph-PPO-PEO (BPE) or PPO-PEO-ph-PEO-PPO (BEP) block
polyether solutions are investigated here. Another hydrophobically
associating polymer (HMPAM) is chosen as a contrast. The rheological
results show that the elastic modulus (G′) and viscous modulus
(G″) of HPAM/BPE and HPAM/BEP solutions first increase then
decrease, while the viscosities of HMPAM/BPE and HMPAM/BEP solutions
decrease with the increase of block polyether concentration. The HPAM/BPE
solution has a larger viscosity than HPAM/BEP, while the HMPAM/BPE
solution has a lower viscosity than HMPAM/BEP. The polymer solutions
containing BEP have larger G′ and G″ values than the
solutions with BPE. Furthermore, the block polyethers reduce the sensitivity
of viscosity to temperature. BEP is more effective to stabilize the
viscoelastic property and improve the temperature resistance than
BPE in HMPAM system. BEP has a better property to enhance the salt
tolerance of the polymer solution than BPE. Moreover, the enhanced
oil recovery (EOR) experiments show that HPAM/block polyether mixed
solution has a larger oil recovery than HPAM, and HPAM/BEP system
has a larger enhanced effect than HPAM/BPE solution
Phase Behavior for Poly(vinylacetate) + Carbon Dioxide + Cosolvent Ternary Systems
Experimental
cloud point and bubble point data of ternary mixtures
for polyÂ(vinylacetate) (PVAc) and cosolvents in carbon dioxide (CO<sub>2</sub>) are studied using the supercritical CO<sub>2</sub> phase
behavior device. The cloud point and bubble point pressures are determined
by measuring the resistance variation of photoresistance. Acetate
acid and ethyl acetate have been selected as the cosolvents. These
systems show phase behavior over a temperature range of 308.2–338.2
K and pressure of up to 50 MPa. The transition point pressure increases
as the temperature increases. The transition point isopleths for the
PVAc + CO<sub>2</sub> + cosolvent ternary systems show upper critical
solution pressure types. The cloud point and bubble point curves for
the PVAc + CO<sub>2</sub> + cosolvent systems decrease rapidly as
the cosolvent concentration increases. When the mass ratio of PVAc
and cosolvents is fixed at 1:7, the transition point pressures increase
as CO<sub>2</sub> increases. Compared with acetic acid and ethyl acetate,
the transition point pressures of the PVAc + CO<sub>2</sub> mixtures,
containing the two cosolvents, show that the pressure for acetate
acid is less than that of ethyl acetate under the same conditions.
The phase behaviors of these ternary systems are calculated using
the perturbed-chain statistical associating fluid theory equation
of state by adjusting the binary interaction parameter <i>k</i><sub>ij</sub>. Our models are in very good agreement with the experimental
data
Aggregation Behaviors of PEO-PPO-ph-PPO-PEO and PPO-PEO-ph-PEO-PPO at an Air/Water Interface: Experimental Study and Molecular Dynamics Simulation
The block polyethers PEO-PPO-ph-PPO-PEO (BPE) and PPO-PEO-ph-PEO-PPO
(BEP) are synthesized by anionic polymerization using bisphenol A
as initiator. Compared with Pluronic P123, the aggregation behaviors
of BPE and BEP at an air/water interface are investigated by the surface
tension and dilational viscoelasticity. The molecular construction
can influence the efficiency and effectiveness of block polyethers
in decreasing surface tension. BPE has the most efficient ability
to decrease surface tension of water among the three block polyethers.
The maximum surface excess concentration (Γ<sub>max</sub>) of
BPE is larger than that of BEP or P123. Moreover, the dilational modulus
of BPE is almost the same as that of P123, but much larger than that
of BEP. The molecular dynamics simulation provides the conformational
variations of block polyethers at the air/water interface