43 research outputs found
Unravelling the role of the interface for spin injection into organic semiconductors
Whereas spintronics brings the spin degree of freedom to electronic devices,
molecular/organic electronics adds the opportunity to play with the chemical
versatility. Here we show how, as a contender to commonly used inorganic
materials, organic/molecular based spintronics devices can exhibit very large
magnetoresistance and lead to tailored spin polarizations. We report on giant
tunnel magnetoresistance of up to 300% in a (La,Sr)MnO3/Alq3/Co nanometer size
magnetic tunnel junction. Moreover, we propose a spin dependent transport model
giving a new understanding of spin injection into organic materials/molecules.
Our findings bring a new insight on how one could tune spin injection by
molecular engineering and paves the way to chemical tailoring of the properties
of spintronics devices.Comment: Original version. Revised version to appear in Nature Physics
INORGANIC RING-SYSTEMS OF PHYSIOLOGICAL IMPORTANCE .3. STRUCTURE AND CYTOSTATIC ACTIVITY INVITRO OF AZIRIDINO CYCLOPHOSPHA(THIA)ZENES
INORGANIC RING-SYSTEMS OF PHYSIOLOGICAL IMPORTANCE .3. STRUCTURE AND CYTOSTATIC ACTIVITY INVITRO OF AZIRIDINO CYCLOPHOSPHA(THIA)ZENES
INORGANIC RING-SYSTEMS OF PHYSIOLOGICAL IMPORTANCE .3. STRUCTURE AND CYTOSTATIC ACTIVITY INVITRO OF AZIRIDINO CYCLOPHOSPHA(THIA)ZENES
INORGANIC RING-SYSTEMS OF PHYSIOLOGICAL IMPORTANCE .3. STRUCTURE AND CYTOSTATIC ACTIVITY INVITRO OF AZIRIDINO CYCLOPHOSPHA(THIA)ZENES
Upscaling, integration and electrical characterization of molecular junctions
The ultimate target of molecular electronics is to combine different types of functional molecules into integrated circuits, preferably through an autonomous self-assembly process. Charge transport through self-assembled monolayers has been investigated previously, but problems remain with reliability, stability and yield, preventing further progress in the integration of discrete molecular junctions. Here we present a technology to simultaneously fabricate over 20,000 molecular junctions—each consisting of a gold bottom electrode, a self-assembled alkanethiol monolayer, a conducting polymer layer and a gold top electrode—on a single 150-mm wafer. Their integration is demonstrated in strings where up to 200 junctions are connected in series with a yield of unity. The statistical analysis on these molecular junctions, for which the processing parameters were varied and the influence on the junction resistance was measured, allows for the tentative interpretation that the perpendicular electrical transport through these monolayer junctions is factorized.
NEW DESIGNS AND STRUCTURE ACTIVITY RELATIONSHIPS IN ANTITUMORAL AZIRIDINYL CYCLOPHOSPHA(THIA)ZENES
Metallic nanoparticle contacts for high-yield, ambient-stable molecular-monolayer devices
Accessing the intrinsic functionality of molecules for electronic applications; 1-3; , light emission; 4; or sensing; 5; requires reliable electrical contacts to those molecules. A self-assembled monolayer (SAM) sandwich architecture; 6; is advantageous for technological applications, but requires a non-destructive, top-contact fabrication method. Various approaches ranging from direct metal evaporation; 6; over poly(3,4-ethylenedioxythiophene) polystyrene sulfonate; 7; (PEDOT:PSS) or graphene; 8; interlayers to metal transfer printing; 9; have been proposed. Nevertheless, it has not yet been possible to fabricate SAM-based devices without compromising film integrity, intrinsic functionality or mass-fabrication compatibility. Here we develop a top-contact approach to SAM-based devices that simultaneously addresses all these issues, by exploiting the fact that a metallic nanoparticle can provide a reliable electrical contact to individual molecules; 10; . Our fabrication route involves first the conformal and non-destructive deposition of a layer of metallic nanoparticles directly onto the SAM (itself laterally constrained within circular pores in a dielectric matrix, with diameters ranging from 60 nanometres to 70 micrometres), and then the reinforcement of this top contact by direct metal evaporation. This approach enables the fabrication of thousands of identical, ambient-stable metal-molecule-metal devices. Systematic variation of the composition of the SAM demonstrates that the intrinsic molecular properties are not affected by the nanoparticle layer and subsequent top metallization. Our concept is generic to densely packed layers of molecules equipped with two anchor groups, and provides a route to the large-scale integration of molecular compounds into solid-state devices that can be scaled down to the single-molecule level