WISE morphological study of Wolf-Rayet nebulae

We present a morphological study of nebulae around Wolf-Rayet (WR) stars using archival narrow-band optical and Wide-field Infrared Survey Explorer (WISE) infrared images. The comparison among WISE images in different bands and optical images proves to be a very efficient procedure to identify the nebular emission from WR nebulae, and to disentangle it from that of the ISM material along the line of sight. In particular, WR nebulae are clearly detected in the WISE W4 band at 22 $\mu$m. Analysis of available mid-IR Spitzer spectra shows that the emission in this band is dominated by thermal emission from dust spatially coincident with the thin nebular shell or most likely with the leading edge of the nebula. The WR nebulae in our sample present different morphologies that we classified into well defined WR bubbles (bubble ${\cal B}$-type nebulae), clumpy and/or disrupted shells (clumpy/disrupted ${\cal C}$-type nebulae), and material mixed with the diffuse medium (mixed ${\cal M}$-type nebulae). The variety of morphologies presented by WR nebulae shows a loose correlation with the central star spectral type, implying that the nebular and stellar evolutions are not simple and may proceed according to different sequences and time-lapses. We report the discovery of an obscured shell around WR35 only detected in the infrared.Comment: 11 pages, 6 figures, plus 23 appendix figures; to appear in Astronomy and Astrophysic

Optical Absorptivity versus Molecular Composition of Model Organic Aerosol Matter

Aerosol particles affect the Earth’s energy balance by absorbing and scattering radiation according to their chemical composition, size, and shape. It is generally believed that their optical properties could be deduced from the molecular composition of the complex organic matter contained in these particles, a goal pursued by many groups via high-resolution mass spectrometry, although: (1) absorptivity is associated with structural chromophores rather than with molecular formulas, (2) compositional space is a small projection of structural space, and (3) mixtures of polar polyfunctional species usually exhibit supramolecular interactions. Here we report a suite of experiments showing that the photolysis of aqueous pyruvic acid (a proxy for aerosol α-dicarbonyls absorbing at λ > 300 nm) generates mixtures of identifiable aliphatic polyfunctional oligomers that develop absorptions in the visible upon standing in the dark. These absorptions and their induced fluorescence emissions can be repeatedly bleached and retrieved without carbon loss or ostensible changes in the electrospray mass spectra of the corresponding mixtures and display unambiguous signatures of supramolecular effects. The nonlinear additivity of the properties of the components of these mixtures supports the notion that full structural speciation is insufficient and possibly unnecessary for understanding the optical properties of aerosol particles and their responses to changing ambient conditions

Interference pattern in the collision of structures in the BEC dark matter model: comparison with fluids

In order to explore nonlinear effects on the distribution of matter during collisions within the Bose-Einstein condensate (BEC) dark matter model driven by the Schr\"odinger-Poisson system of equations, we study the head-on collision of structures and focus on the interference pattern formation in the density of matter during the collision process. We explore the possibility that the collision of two structures of fluid matter modeled with an ideal gas equation of state also forms interference patterns and found a negative result. Given that a fluid is the most common flavor of dark matter models, we conclude that one fingerprint of the BEC dark matter model is the pattern formation in the density during a collision of structures.Comment: 7 pages, 22 eps figure

Thermochromism of Model Organic Aerosol Matter

Laboratory experiments show that the optical absorptivity of model organic matter is not an intrinsic property, but a strong function of relative humidity, temperature, and insolation. Suites of representative polyfunctional C_(x)H_(y)O_(z) oligomers in water develop intense visible absorptions upon addition of inert electrolytes. The resulting mixtures reach mass absorption cross sections σ(532 nm) ~ 0.1 m^(2)/gC in a few hours, absorb up to 9 times more solar radiation than the starting material, can be half-bleached by noon sunlight in ~ 1 h, and can be repeatedly recycled without carbon loss. Visible absorptions red-shift and evolve increasingly faster in subsequent thermal aging cycles. Thermochromism and its strong direct dependences on ionic strength and temperature are ascribed to the dehydration of >CH−C(OH)C═C< unsaturations by a polar E1 mechanism, and bleaching to photoinduced retrohydration. These transformations are deemed to underlie the daily cycles of aerosol absorption observed in the field, and may introduce a key feedback in the earth’s radiative balance

The IRAM-30m line survey of the Horsehead PDR: III. High abundance of complex (iso-)nitrile molecules in UV-illuminated gas

Complex (iso-)nitrile molecules, such as CH3CN and HC3N, are relatively easily detected in our Galaxy and in other galaxies. We constrain their chemistry through observations of two positions in the Horsehead edge: the photo-dissociation region (PDR) and the dense, cold, and UV-shielded core just behind it. We systematically searched for lines of CH3CN, HC3N, C3N, and some of their isomers in our sensitive unbiased line survey at 3, 2, and 1mm. We derived column densities and abundances through Bayesian analysis using a large velocity gradient radiative transfer model. We report the first clear detection of CH3NC at millimeter wavelength. We detected 17 lines of CH3CN at the PDR and 6 at the dense core position, and we resolved its hyperfine structure for 3 lines. We detected 4 lines of HC3N, and C3N is clearly detected at the PDR position. We computed new electron collisional rate coefficients for CH3CN, and we found that including electron excitation reduces the derived column density by 40% at the PDR position. While CH3CN is 30 times more abundant in the PDR than in the dense core, HC3N has similar abundance at both positions. The isomeric ratio CH3NC/CH3CN is 0.15+-0.02. In the case of CH3CN, pure gas phase chemistry cannot reproduce the amount of CH3CN observed in the UV-illuminated gas. We propose that CH3CN gas phase abundance is enhanced when ice mantles of grains are destroyed through photo-desorption or thermal-evaporation in PDRs, and through sputtering in shocks. (abridged)Comment: Accepted for publication in Astronomy & Astrophysic

Multi-component symmetry-projected approach for molecular ground state correlations

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a multi-component, systematically-improvable approach, that accounts for all ground state correlations. Our approach is based on linear combinations of symmetry-projected configurations built out of a set of non-orthogonal, variationally optimized determinants. The resulting wavefunction preserves the symmetries of the original Hamiltonian even though it is written as a superposition of deformed (broken-symmetry) determinants. We show how short expansions of this kind can provide a very accurate description of the electronic structure of simple chemical systems such as the nitrogen and the water molecules, along the entire dissociation profile. In addition, we apply this multi-component symmetry-projected approach to provide an accurate interconversion profile among the peroxo and bis($\mu$-oxo) forms of [Cu$_2$O$_2$]$^{2+}$, comparable to other state-of-the-art quantum chemical methods

On the Space Time of a Galaxy

We present an exact solution of the averaged Einstein's field equations in the presence of two real scalar fields and a component of dust with spherical symmetry. We suggest that the space-time found provides the characteristics required by a galactic model that could explain the supermassive central object and the dark matter halo at once, since one of the fields constitutes a central oscillaton surrounded by the dust and the other scalar field distributes far from the coordinate center and can be interpreted as a halo. We show the behavior of the rotation curves all along the background. Thus, the solution could be a first approximation of a ``long exposition photograph'' of a galaxy.Comment: 8 pages REVTeX, 11 eps figure

Excited electronic states from a variational approach based on symmetry-projected Hartree--Fock configurations

Recent work from our research group has demonstrated that symmetry-projected Hartree--Fock (HF) methods provide a compact representation of molecular ground state wavefunctions based on a superposition of non-orthogonal Slater determinants. The symmetry-projected ansatz can account for static correlations in a computationally efficient way. Here we present a variational extension of this methodology applicable to excited states of the same symmetry as the ground state. Benchmark calculations on the C$_2$ dimer with a modest basis set, which allows comparison with full configuration interaction results, indicate that this extension provides a high quality description of the low-lying spectrum for the entire dissociation profile. We apply the same methodology to obtain the full low-lying vertical excitation spectrum of formaldehyde, in good agreement with available theoretical and experimental data, as well as to a challenging model $C_{2v}$ insertion pathway for BeH$_2$. The variational excited state methodology developed in this work has two remarkable traits: it is fully black-box and will be applicable to fairly large systems thanks to its mean-field computational cost

Internal Kinematics of Luminous Compact Blue Galaxies

We describe the dynamical properties which may be inferred from HST/STIS spectroscopic observations of luminous compact blue galaxies (LCBGs) between 0.1<z<0.7. While the sample is homogeneous in blue rest-frame color, small size and line-width, and high surface-brightness, their detailed morphology is eclectic. Here we determine the amplitude of rotation versus random, or disturbed motions of the ionized gas. This information affirms the accuracy of dynamical mass and M/L estimates from Keck integrated line-widths, and hence also the predictions of the photometric fading of these unusual galaxies. The resolved kinematics indicates this small subset of LCBGs are dynamically hot, and unlikely to be embedded in disk systems.Comment: To appear in "Starbursts: from 30 Doradus to Lyman Break Galaxies" 2005, eds. R. de Grijs and R. M. Gonzalez Delgado (Kluwer