Dynamic HAADF-STEM Observation of a Single-Atom Chain as the Transient State of Gold Ultrathin Nanowire Breakdown

Ultrathin chemically grown gold nanowires undergo irremediable structural modification under external stimuli. Thanks to dynamic high-angle annular dark-field imaging, electron-beam-induced damage was followed, revealing the formation of linear chains of gold atoms as well as reactive clusters on the side, opening fascinating prospects for applications in both catalysis and electronic transport

Dynamic HAADF-STEM Observation of a Single-Atom Chain as the Transient State of Gold Ultrathin Nanowire Breakdown

Ultrathin chemically grown gold nanowires undergo irremediable structural modification under external stimuli. Thanks to dynamic high-angle annular dark-field imaging, electron-beam-induced damage was followed, revealing the formation of linear chains of gold atoms as well as reactive clusters on the side, opening fascinating prospects for applications in both catalysis and electronic transport

Dynamic HAADF-STEM Observation of a Single-Atom Chain as the Transient State of Gold Ultrathin Nanowire Breakdown

Ultrathin chemically grown gold nanowires undergo irremediable structural modification under external stimuli. Thanks to dynamic high-angle annular dark-field imaging, electron-beam-induced damage was followed, revealing the formation of linear chains of gold atoms as well as reactive clusters on the side, opening fascinating prospects for applications in both catalysis and electronic transport

Dynamic HAADF-STEM Observation of a Single-Atom Chain as the Transient State of Gold Ultrathin Nanowire Breakdown

Ultrathin chemically grown gold nanowires undergo irremediable structural modification under external stimuli. Thanks to dynamic high-angle annular dark-field imaging, electron-beam-induced damage was followed, revealing the formation of linear chains of gold atoms as well as reactive clusters on the side, opening fascinating prospects for applications in both catalysis and electronic transport

Growth and Self-Assembly of Ultrathin Au Nanowires into Expanded Hexagonal Superlattice Studied by in Situ SAXS

We report the self-assembly of gold nanowires into hexagonal superlattices in liquid phase followed by in situ small-angle X-ray scattering and give new insights into their growth mechanism. The unprecedented large interwire distance of 8 nm strongly suggests the stabilization of the ultrathin gold nanowires by a ligand’s double layer composed of oleylamine and oleylammonium chloride. The one-dimensional growth is discussed, opening perspectives toward the control growth and self-assemblies of metallic nanowires