1,140 research outputs found

    Challenges to Political Campaigns in the Media: Commercialization, Framing, and Personalization

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    Due to an increasing interdependence between mass communication and political processes, the role of media in political campaigns generated much debate.In this paper, we identify commercialization, framing and personalization as three key challenges to the way the media face political campaigns. We theoretically derive three hypotheses, one for each of those challenges. Based on data from expert interviews as well as from a content analysis, the validity of each hypothesis is surveyed. The results do not confi rm an assumed lack of providing campaign relevant news in the media coverage as proposed by considering the media as purely commercially driven organizations. Further they demonstrate the use of different frames for the presentation of competing positions in a political debate. Finally, personalization appears as an important strategy of news selection, focusing on a small number of prominent actors

    Discordant Supramolecular Fibres Reversibly Depolymerised by Temperature and Light

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    Synthetic stimuli responsive supramolecular polymers attract increasing interest for their ability to mimic the unique properties of natural assemblies. Here we focus on the well-studied benzene-1,3,5-tricarboxamide (BTA) motif, and substitute it with two (S)-3,7-dimethyloctyl groups and an azobenzene photoswitch. We demonstrate the UV (λ=365 nm) induced depolymerisation of the helical hydrogen-bonded polymers in methylcyclohexane (MCH) through circular dichroism and UV-vis spectroscopy in dilute solution (15 μm), and NMR and iPAINT super-resolution microscopy in concentrated solution (300 μm). The superstructure can be regenerated after thermal depolymerization, whilst repeated depolymerisation can be reversed without degradation by irradiating at λ=455 nm. Molecular dynamics simulations show that the most energetically favourable configuration for these polymers in MCH is a left-handed helical network of hydrogen-bonds between the BTA cores surrounded by two right-handed helices of azobenzenes. The responsiveness to two orthogonal triggers across a broad concentration range holds promise for use in, for example, photo-responsive gelation

    Magnetic Doppler imaging of alpha^2 Canum Venaticorum in all four Stokes parameters. Unveiling the hidden complexity of stellar magnetic fields

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    Strong organized magnetic fields have been studied in the upper main sequence chemically peculiar stars for more than half a century. However, only recently have observational methods and numerical techniques become sufficiently mature to allow us to record and interpret high-resolution four Stokes parameter spectra, leading to the first assumption-free magnetic field models of these stars. Here we present a detailed magnetic Doppler imaging analysis of the spectropolarimetric observations of the prototypical magnetic Ap star alpha^2 CVn. The surface abundance distributions of Fe and Cr and a full vector map of the stellar magnetic field are reconstructed in a self-consistent inversion using our state-of-the-art magnetic Doppler imaging code Invers10. We succeeded in reproducing most of the details of the available spectropolarimetric observations of alpha^2 CVn with a magnetic map which combines a global dipolar-like field topology with localized spots of higher field intensity. We demonstrate that these small-scale magnetic structures are inevitably required to fit the linear polarization spectra; however, their presence cannot be inferred from the Stokes I and V observations alone. Our magnetic Doppler imaging analysis of alpha^2 CVn and previous results for 53 Cam support the view that the upper main sequence stars can harbour fairly complex surface magnetic fields which resemble oblique dipoles only at the largest spatial scales. Spectra in all four Stokes parameters are absolutely essential to unveil and meaningfully characterize this field complexity in Ap stars. We therefore suggest that understanding magnetism of stars in other parts of the H-R diagram is similarly incomplete without investigation of their linear polarization spectra.Comment: 16 pages, 12 figures; Accepted for publication by Astronomy & Astrophysic

    Histological Evaluation of the Biocompatibility of Polyurea Crosslinked Silica Aerogel Implants in a Rat Model: A Pilot Study

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    Background: Aerogels are a versatile group of nanostructured/nanoporous materials with physical and chemical properties that can be adjusted to suit the application of interest. In terms of biomedical applications, aerogels are particularly suitable for implants such as membranes, tissue growth scaffolds, and nerve regeneration and guidance inserts. The mesoporous nature of aerogels can also be used for diffusion based release of drugs that are loaded during the drying stage of the material. From the variety of aerogels polyurea crosslinked silica aerogels have the most potential for future biomedical applications and are explored here. Methodology: This study assessed the short and long term biocompatibility of polyurea crosslinked silica aerogel implants in a Sprague-Dawley rat model. Implants were inserted at two different locations a) subcutaneously (SC), at the dorsum and b) intramuscularly (IM), between the gluteus maximus and biceps femoris of the left hind extremity. Nearby muscle and other internal organs were evaluated histologically for inflammation, tissue damage, fibrosis and movement (travel) of implant. Conclusion/Significance: In general polyurea crosslinked silica aerogel (PCSA) was well tolerated as a subcutaneous and an intramuscular implant in the Sprague-Dawley rat with a maximum incubation time of twenty months. In some cases a thin fibrous capsule surrounded the aerogel implant and was interpreted as a normal response to foreign material. No noticeable toxicity was found in the tissues surrounding the implants nor in distant organs. Comparison was made with control rats without any implants inserted, and animals with suture material present. No obvious or noticeable changes were sustained by the implants at either location. Careful necropsy and tissue histology showed age-related changes only. An effective sterilization technique for PCSA implants as well as staining and sectioning protocol has been established. These studies further support the notion that silica-based aerogels could be useful as biomaterials. © 2012 Sabri et al

    Spots structure and stratification of helium and silicon in the atmosphere of He-weak star HD 21699

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    The magnetic star HD 21699 possesses a unique magnetic field structure where the magnetic dipole is displaced from the centre by 0.4 +/- 0.1 of the stellar radius (perpendicularly to the magnetic axis), as a result, the magnetic poles are situated close to one another on the stellar surface with an angular separation of 55o^o and not 180o^o as seen in the case of a centred dipole. Respectively, the two magnetic poles form a large "magnetic spot". High-resolution spectra were obtained allowing He I and Si II abundance variations to be studied as a function of rotational phase. The results show that the helium abundance is concentrated in one hemisphere of the star, near the magnetic poles and it is comparatively weaker in another hemisphere, where magnetic field lines are horizontal with respect to the stellar surface. At the same time, the silicon abundance is greatest between longitudes of 180 - 320o^o, the same place where the helium abundance is the weakest. These abundance variations (with rotational phase) support predictions made by the theory of atomic diffusion in the presence of a magnetic field. Simultaneously, these result support the possibility of the formation of unusual structures in stellar magnetic fields. Analysis of vertical stratification of the silicon and helium abundances shows that the boundaries of an abundance jump (in the two step model) are similar for each element; Ď„5000\tau_{5000} = 0.8-1.2 for helium and 0.5-1.3 for silicon. The elemental abundances in the layers of effective formation of selected absorption lines for various phases are also correlated with the excitation energies of low transition levels: abundances are enhanced for higher excitation energy and higher optical depth within the applied model atmosphere.Comment: accepted by MN, 7 pagers, 10 figs, 3 table

    Evidence for multiple colonisations and Wolbachia infections shaping the genetic structure of the widespread butterfly Polyommatus icarus in the British Isles

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    The paradigm of isolation in southern refugia during glacial periods followed by expansions during interglacials, producing limited genetic differentiation in northern areas, dominates European phylogeography. However, the existence of complex structured populations in formerly glaciated areas, and islands connected to mainland areas during glacial maxima, call for alternative explanations. We reconstructed the mtDNA phylogeography of the widespread Polyommatus icarus butterfly with an emphasis on the formerly glaciated and connected British Isles. We found distinct geographical structuring of CO1 haplogroups, with an ancient lineage restricted to the marginal European areas, including Northern Scotland and Outer Hebrides. Population genomic analyses, using ddRADSeq genomic markers, also reveal substantial genetic structuring within Britain. However, there is negligble mito-nuclear concordance consistent with independent demographic histories of mitochondrial vs. nuclear DNA. While mtDNA-Wolbachia associations in northern Britain could account for the geographic structuring of mtDNA across most of the British Isles, for nuclear DNA markers (derived from ddRADseq data) butterflies from France cluster between northern and southern British populations – an observation consistent with a scenario of multiple recolonisation. Taken together our results suggest that contemporary mtDNA structuring in the British Isles (and potentially elsewhere in Europe) largely results from Wolbachia infections, however, nuclear genomic structuring suggests a history of at least two distinct colonisations. This two-stage colonisation scenario has previously been put forth to explain genetic diversity and structuring in other British flora and fauna. Additionally, we also present preliminary evidence for potential Wolbachia-induced feminization in the Outer Hebrides

    Reasoning about Communicating Agents in the Semantic Web

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    Abstract. In this article we interpret the Semantic Web and Web Service issues in the framework of multi-agent interoperating systems. We will advocate the application of results achieved in the research area of reasoning about actions and change by showing scenarios and techniques that could be applied.
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