Carrier multiplication yields in CdSe and CdTe nanocrystals by transient photoluminescence

Engineering semiconductors to enhance carrier multiplication (CM) could lead to increased photovoltaic cell performance and a significant widening of the materials range suitable for future solar technologies. Semiconductor nanocrystals (NCs) have been proposed as a favourable structure for CM enhancement, and recent measurements by transient absorption have shown evidence for highly efficient CM in lead chalcogenide and CdSe NCs. We report here an assessment of CM yields in CdSe and CdTe NCs by a quantitative analysis of biexciton and exciton signatures in transient photoluminescence decays. Although the technique is particularly sensitive due to enhanced biexciton radiative rates relative to the exciton, kradBX > 2 kradX, we find no evidence for CM in CdSe and CdTe NCs up to photon energies E > 3 Eg, well above previously reported relative energy thresholds.Comment: 9 pages, 6 figure

Influence of Flow Rate on Leachability

The leaching potential of coal fly ash is often approximated with laboratory-based methods that expose columns of compacted material to synthetic precipitation. While this procedure can simulate aspects of the field condition, it remains difficult to replicate site-specific thermodynamic and kinetic constraints on geochemical processes. This article explores one aspect that contributes to the field/laboratory disparity, namely, the influence of flow rate and intermittency. Seven column-based leaching experiments were conducted with the same ash but with different flow rates and intermittency (i.e., infiltration pulsing), and results were evaluated in terms of aqueous sodium, calcium, and chromium concentrations in the effluent. Flow rates ranged by three orders of magnitude, encompassing advection- and diffusion-dominated conditions as determined by Peclet number calculations. With few exceptions, the results revealed diminishing leachate concentrations with continued flushing, consistent with a declining source model. Notwithstanding differences in effluent concentration as a function of pore volume, general mass release followed similar patterns that likely reflected solubility control. Higher liquid-to-solid ratios revealed potentially nonequilibrium behavior at the highest flow rate (2400 mL/day) during intermittent flow conditions for chromium and calcium, and to a modest extent for sodium. The primary conclusion from this work is that for the constituents and ash tested, there was relatively little effect of flow rate or intermittency on leachability patterns

Carrier multiplication yields in PbS and PbSe nanocrystals measured by transient photoluminescence

We report here an assessment of carrier multiplication (CM) yields in PbSe and PbS nanocrystals (NCs) by a quantitative analysis of biexciton and exciton dynamics in transient photoluminescence decays. Interest in CM, the generation of more than one electron and hole in a semiconductor after absorption of one photon, has renewed in recent years because of reports suggesting greatly increased efficiencies in nanocrystalline materials compared to the bulk form, in which CM was otherwise too weak to be of consequence in photovoltaic energy conversion devices. In our PbSe and PbS NC samples, however, we estimate using transient photoluminescence that at most 0.25 additional e-h pairs are generated per photon even at energies hv > 5Eg, instead of the much higher values reported in the literature. We argue by comparing NC CM estimates and reported bulk values on an absolute energy basis, which we justify as appropriate on physical grounds, that the data reported thus far are inconclusive with respect to the importance of nanoscale-specific phenomena in the CM process.Comment: 10 pages, 7 figure

Optimization of a High–Speed Deployment Slider–Crank Mechanism: A Design Charts Approach

Mechanical and aerospace applications often require that mechanisms deploy in a quick stable and reliable way. The objective of this study is to implement a general optimization procedure to perform a first stage conceptual design of HSD mechanisms, focusing on both kinematics and dynamics. In particular, the authors will focus on the development of design charts. In the very first part of the work, a parametric lumped-mass system will be modeled in order to reduce the number of parameters for the synthesis phase. A correlation will be established between geometry, inertia and initial position to guarantee the maximum value of acceleration during deployment of the deployable arm by means of the principle of virtual work. In the second part of this work, the influence of important factors such as friction and joint clearance on the overall dynamics of the system will be investigated. Finally, a coupled dynamic and structural analysis of the helical spring, that actuates the mechanism, will be carried out in order to achieve optimal performance. The developed charts will also take into account the space limitation requirement, that are often needed for both aerospace and mechanical applications. A final example will summarize all the points covered by this research effort. Results will be validated using the commercial software ABAQUS.</jats:p

Gender Inequality, Bargaining, and Pay in Care Services in the U.S.

The authors argue that paid providers of care services in the U.S. (in health, education, and social service industries) are less able than providers of business services to capture value-added or to extract rents because limited consumer sovereignty, incomplete information regarding quality, and large positive externalities reduce their relative market power. In addition, many care jobs enforce normative responsibility for others and require specific skills that limit cross industry mobility. Analysis of Current Population Survey data for 2014-2019 reveals significant pay penalties in care services relative to business services, controlling for factors such as gender, education, occupation, and public/private employment. Women’s concentration in care services explains a significant proportion of the gender wage gap and raises the possibility of significant potential benefits from industry-level bargaining strategies

Predictions for Electromagnetic Counterparts to Neutron Star Mergers Discovered during LIGO-Virgo-KAGRA Observing Runs 4 and 5

We present a comprehensive, configurable open-source framework for estimating the rate of electromagnetic detection of kilonovae (KNe) associated with gravitational wave detections of binary neutron star (BNS) mergers. We simulate the current LIGO-Virgo-KAGRA (LVK) observing run (O4) using up-to-date sensitivity and up-time values as well as the next observing run (O5) using predicted sensitivities. We find the number of discoverable kilonovae during LVK O4 to be ${ 1}_{- 1}^{+ 4}$ or ${ 2 }_{- 2 }^{+ 3 }$, (at 90% confidence) depending on the distribution of NS masses in coalescing binaries, with the number increasing by an order of magnitude during O5 to ${ 19 }_{- 11 }^{+ 24 }$. Regardless of mass model, we predict at most five detectable KNe (at 95% confidence) in O4. We also produce optical and near-infrared light curves that correspond to the physical properties of each merging system. We have collated important information for allocating observing resources and directing search and follow-up observations including distributions of peak magnitudes in several broad bands and timescales for which specific facilities can detect each KN. The framework is easily adaptable, and new simulations can quickly be produced as input information such as merger rates and NS mass distributions are refined. Finally, we compare our suite of simulations to the thus-far completed portion of O4 (as of October 14, 2023), finding a median number of discoverable KNe of 0 and a 95-percentile upper limit of 2, consistent with no detection so far in O4.Comment: 16 pages, 13 figures, MNRAS: Accepted 2023 November 25. Received 2023 November 16; in original form 2023 October 2

Sub-percent Photometry: Faint DA White Dwarf Spectophotometric Standards for Astrophysical Observatories

We have established a network of 19 faint (16.5 mag $< V <$19 mag) northern and equatorial DA white dwarfs as spectrophotometric standards for present and future wide-field observatories. Our analysis infers SED models for the stars that are tied to the three CALSPEC primary standards. Our SED models are consistent with panchromatic Hubble Space Telescope ($HST$) photometry to better than 1%. The excellent agreement between observations and models validates the use of non-local-thermodynamic-equilibrium (NLTE) DA white dwarf atmospheres extinguished by interstellar dust as accurate spectrophotometric references. Our standards are accessible from both hemispheres and suitable for ground and space-based observatories covering the ultraviolet to the near infrared. The high-precision of these faint sources make our network of standards ideally suited for any experiment that has very stringent requirements on flux calibration, such as studies of dark energy using the Large Synoptic Survey Telescope (LSST) and the Wide-Field Infrared Survey Telescope ($WFIRST$).Comment: 46 pages, 23 figures, 8 tables, accepted for publication in ApJ