Evaluación de la técnica de tomografía eléctrica para la estimación de propiedades fisioquímicas de residuos mineros

El objetivo principal del trabajo es estudiar la idoneidad de la técnica de “tomografía eléctrica” como herramienta de evaluación de las propiedades fisicoquímicas de residuos mineros. Desde el punto de vista práctico se trata de averiguar si existe o no influencia entre dichas propiedades y la resistividad eléctrica en este tipo de residuos. Para ello será necesario llevar a cabo la caracterización geoquímica del depósito minero, a través de análisis de laboratorio de las muestras de residuo tomadas. Esto permitirá, a su vez, establecer el grado de contaminación del depósito. Debemos evaluar también el efecto de la humedad en la resolución de la tomografía eléctrica (en adelante, TE) y, por último, estudiar la correlación entre las variables geoquímicas y geofísicas.Escuela de Ingeniería de Caminos y MinasUniversidad Politécnica de Cartagen

Use of multivariable and redundancy analysis to assess the behavior of metals and arsenic in urban soil and road dust affected by metallic mining as a base for risk assessment

The vicinity of abandoned mining ponds to populated areas may suppose a high environmental and health risk being necessary evaluate unreclaimend ponds as source of metal(loid)s. In order to evaluate the behaviour of metals and arsenic from tailing ponds and their effects in urban areas, 10 mine wastes samples, 10 urban soil and 10 urban road dust samples were collected from two mining districts (La Unión and Mazarrón, SE Spain). Physicochemical properties and total, available and water-soluble concentration of metals (Cd, Co, Cr, Cu, Fe, Ni, Mn, Pb, Zn) and As were analyzed. Results suggest enrichment in Fe, Mn, Pb and Zn of urban soil and road dust in both studied towns. Multivariable analysis indicated that Cd, Mn, Pb and Zn in La Unión urban soil, and As, Cd, Cu, Pb and Zn in soil and Fe in road dust of Mazarrón come from mining districts. In addition, redundancy analysis showed that mobility of metal(loid)s related to mining sources were more influenced by their total concentration, while metals with a lithogeny origin were more affected by physicochemical properties.The financial support to conduct this study was provided by the Fundación Séneca of 235 Comunidad Autónoma de Murcia-Spain (15380/PI/10)

Assessment of metals behaviour in industrial soil using sequential extraction, multivariable analysis and a geostatistical approach

The main objectives of this studywere to evaluate the degree of Pb, Cu, Zn, Cd, Cr and Ni pollution using pollution indexes and geostatistical approach, and to assess metals dynamic using sequential extraction procedure and multivariable statistical analysis in surface soils and soil profiles froman industrial complex as a base for a correct management in order to avoid health and environmental problems. Results showed that the industrial activity increases both Pb (103 mgkg−1), Zn (526 mgkg−1) and Cu (39 mgkg−1) concentrations and salinity in soil. Pollution indexes showed that industrial soils were moderately contaminated by Zn, Pb, Cu, Cr and Ni as well as a moderate ecological risk was reported. Two main areas were identified: southeast area with the highest metal concentrations, and northwest areawith the lowest levels. Chemical speciation of metals showed that the residual phase was the dominant phase for all metals. However, Pb and Zn were highly associated to the reducible phase (25–30% and 35–40% respectively) and a significant concentration was associated to carbonates (5% for both metals). In contrast, Cu, Cr and Ni were mainly bound to the residual phase (N80% for all metals) with low concentrations retained to reducible phase, and very low concentrations bound to the most labile phases. Cd was the most mobile metal with high concentration associated to exchangeable (5%) and carbonates (15–20%) phases. Therefore, Pb, Zn and Cd represent the greatest risk for human health and the environment

Electrical resistivity tomography (ERT) and geochemical analysis dataset to delimit subsurface affected areas by livestock pig slurry ponds

The electrical resistivity tomography (ERT) technique was employed with the support of geochemical analyses to delimit the affected surface area by slurry pig ponds. Data were taken in three selected slurry ponds located in Fuente Álamo municipality, Murcia region (SE Spain), to obtain electrical resistivity value-based 2D sections and 3D blocks. All ERT-based survey data were obtained in September 2020 using a SuperSting R8 resistivity meter from Advanced Geosciences Inc. and using the dipole-dipole array consisting of a total of twenty-eight electrodes. The soil samples were taken from drilling core sampling by boreholes at each slurry pond, and physical-chemical analyses of soil samples were obtained using standard laboratory testing methods. Electrical resistivity values and physical-chemical analysis data obtained from soil samples were contrasted, whose comparison showed a correlation between profiles-based electrical resistivity, laboratory-based electrical conductivity (EC) data, and nitrate (N-NO3-) content from soil samples. The statistical analysis was run by SPSS Statistics v.23 software (IBM, Neconductivity York, NY, USA) to establish the non-parametric Spearman correlation. The dataset establishes a reliable methodology and provides insight and information to delimit the affected subsurface area by pig slurry. Data contained within this publication are presented concurrently with Capa-Camacho et al. 2022 [1].This work was supported by the research grant 21583/FPI/21. Fundación Séneca. Región de Murcia (Spain), and the Sustainable Use, Management, and Reclamation of Soil and Water research group

Environmental impact assessment of industrial activities on heavy metals distribution in street dust and soil

Street dust and soil are important materials for evaluating the contaminants level in industrial areas. Detailed size-resolved distribution of metal(loid)s in street dusts and soils influenced by industrial activities has rarely been investigated. This study was carried out to understand how industrialization might affect the size distribution of metal(loid)s concentration and contamination level in the street dust and soil from Murcia, southern Spain. An industrial and a natural areas were selected and surface soil and street dust samples were taken. They were fractionated into eleven size classes and total concentrations of Pb, Zn, Cu, Cd, Cr, Ni, As and Fe were determined in both the bulk samples and their fractions. Enrichment factor, geoaccumulation index, and mass loading of different heavy metal(loids) were calculated. The results indicated that the street dust from natural and industrial areas had almost the same particle size distribution, both containing higher percentage of coarse-sized particles than the soil. Industrialization seems to have only slightly affected the concentration of most elements studied in the soil. In contrast, the concentrations of the heavy elements in bulk industrial dust samples and all their size fractions were extremely higher than those from the natural area. This means that the industrial activities only affected the size dependency of the concentration (contamination level) of certain elements (Pb, Zn, Cu, Cd, and Cr) in the street dust, but not in the soil.Este artículo fue financiado por las universidades Isfahan University of Technology y Shahrood University of Technology (Irán) a través de las estancias de los profesores Khademi y Abbaspour, así como por la Fundación Séneca de la Comunidad Autónoma de la Región de Murcia, con el proyecto de referencia 15380/PI/10

Electrical resistivity tomography as a support tool for physicochemical properties assessment of near-surface waste materials in a mining tailing Pond (El Gorguel, SE Spain)

The legacy of the mining industry has left a large number of tailing ponds in the Cartagena–La Unión mining district exposed to water and wind erosion, which causes serious environmental and health problems and requires remediation. Before applying any remediation technique, an intensive sampling of the materials infilling the pond is required to determine the geochemistry of the pond, which will condition the remediation process. However, sampling the large number of tailing ponds that compose the district could be expensive. Thus, the main objective of this study is to evaluate the usefulness of electrical resistivity tomography (ERT) as a non-invasive tool to provide an image of spatial subsurface resistivity distribution and its relation to the physicochemical composition of near-surface mine wastes. To achieve this objective, three short ERT profiles were conducted, and 12 samples in each profile were collected at different depths for its geochemical characterization. Several non-linear regression models were fitted to predict physicochemical properties and metal concentrations from electrical resistivity measures. As a result, a high resistivity area was depicted in the ERT profiles G2 and G3, while the low resistivity ERT profile G1 was also obtained in accordance with the site’s surficial characteristics. Relationships among low resistivity values and high salinity, clay content, high metal concentrations, and mobility were established. Specifically, calibrated models were obtained for electrical conductivity, particle sizes of 0.02–50 µm and 50–2000 µm, total Zn and Cd concentration, and bioavailable Ni, Cd, and Fe. The ERT technique was shown to be a useful tool for the approximation of the location and distribution of the highest ranges of fine particle sizes, moisture, and, to a lesser extent, metal accumulation in the near-surface waste materials

Distribution of metal(loid)s in particle size fraction in urban soil and street dust: influence of population density

Assessment of street dust is an invaluable approach for monitoring atmospheric pollution. Little information is available on the size distribution of contaminants in street dusts and urban soils and it is not known how the population density would influence them. This research was carried out to assess the size distribution of trace metal(loid)s in street dust and urban soil, and to understand how population density might influence the size-resolved concentration of metal(loid)s. Three urban areas with a high (HD), medium (MD) and low population density (LD) and a natural area (NA) were selected, and urban soil and street dust sampled. They were fractionated into 8 size fractions: 2000-850, 850-180, 180-106, 106-50, 50-20, 20-10, 10-2, and < 2 µm. The concentration of Pb, Zn, Cu, Cd, Cr, Ni, As, and Fe was determined and enrichment factor and grain size fraction loadings were computed. The results indicated that the concentration of Pb, Zn, Cu, Cd, Cr were highly size dependent, particularly for particles < 100 µm, especially for street dust. Low concentrations of Ni and As in street dust and urban soil were size and population density independent. Higher size dependency of the metals concentration and the higher degree of elemental enrichment in the street dust fractions than the urban soils indicate higher contribution of human induced pollution to the dust. Findings also confirm the inevitability of size fractionation when soils or dusts are environmentally assessed, particularly in moderately to highly polluted areas. Otherwise, higher concentrations of certain pollutants in fine-sized particles might be overlooked leading to inappropriate decisions for environmental remediation.Este artículo fue financiado por las universidades Isfahan University of Technology y Shahrood University of Technology (Irán) a través de las estancias de los profesores Khademi y Abbaspour, así como por la Fundación Séneca de la Comunidad Autónoma de la Región de Murcia, con el proyecto de referencia 15380/PI/10

Effect of land use and soil properties in the feasibility of two sequential extraction procedures for metals fractionation

Several sequential extraction procedures are widely applied for metals chemical fractionation in the literature. However, their limitations to be used in different soils and metals have not been discussed in detail. This study compares two of the most commonly used extraction methods for metals chemical fractionation: Tessier and BCR. The objectives were to i) assess the differences between concentrations of metals extracted in each fraction by both Tessier and BCR procedures; ii) elucidate if soil properties affected the extraction ability of each fraction from both procedures; and iii) evaluate how land use contributes to different chemical metal distribution. Results indicated that both methods provide similar results when were applied to the same soil, since non-significant differences were found in metal concentrations between both methods at each fraction. Conversely, when we compared among land uses, significant differences were found in the metal concentration between both methods, especially between agricultural/urban/industrial against forest soil. Redundancy analysis showed that in carbonate- rich soils, BCR extraction method could cover up the real concentration of exchangeable metals with those bound to the carbonate phase, being the Tessier method the most suitable one for this kind of soils. Therefore, although sequential extraction is a useful tool to understand the distribution of metals in soil, the method used must be selected according to the land use and specific soil characteristics, taking into account at least, soil carbonate content

Phytoremediation of mine tailings with Atriplex halimus and organic/inorganic amendments: A five-year field case study

Mine tailings have adverse chemical and physical conditions, including high concentrations of metals and salts, low organic matter content, and unbalanced rates of nutrients which limit the development of vegetation. A large scale field experiment was conducted to reclaim a tailing pond by triggering the growth of native species by spontaneous colonization by tilling (TL) the tailing pond surface and using marble waste (CaCO3; MW), pig slurry (PS) and their combination (MW+PS) as soil amendments. Soil physicochemical properties and water and DTPA extractable metal concentrations of bulk and rhizosphere soils were analyzed after five year from the application of the treatments. In addition, plants of Atriplex halimus from each treatment were collected and metals in roots, leaves and stems analyzed. Before amendments application, the studied pond showed a neutral pH, high salinity and a moderate organic carbon content. After five years, the pH value was significantly increased only in MW plot. The results showed significant increases of DTPA-extractable Zn in MW and MW+PS plots, Pb in all treatments except MW plot, Cd only in PS plot, and Cu only in MW+PS plot. A. halimus was the most dominant species, growing spontaneously in all plots, with lower vegetation cover in CT and MW plots, 6% and 2% respectively. Application of MW increased leaf Pb accumulation by 2.5-fold and Cd by 55 %, when compared to the CT. The high initial salinity and probable substitution of metals by Ca2+ on exchangeable surfaces of soil particles may be the reasons for higher uptake of metals in MW plot when compared to the other plots. Although this plant is widely utilized in contaminated sites for phytostabilization purposes, it may absorb and translocate high concentrations of metals to the aboveground tissues in saline contaminated sites

Nitrogen assessment in amended mining soils sown with Coronilla juncea and piptatherum miliaceum

Metalliferous mining activities generate a large amount of waste. This waste usually has high concentrations of pollutants such as metal(oid)s associated with the extractive processes, which, if not properly treated and reclaimed, put the ecosystem and the population at risk. One of the most used techniques for mine waste reclamation is aided phytostabilization, which is based on the use of plants that immobilize metals in the soil/roots aided by the use of amendments to improve the soil properties to favor plant growth. Although amendments increase nutrients and improve the soil properties, the concentration of these nutrients—especially N, the most limiting plant nutrient—decreases over time. Thus, this study focused on the evaluation of the relationship between different combinations of amendments (compost, biochar, zeolite and limestone) and plant growth (we introduced Coronilla juncea and Piptatherum miliaceum) on the evolution of soil N over time as well as the influence of C. juncea on soil N fixation. The results showed that the addition of amendments improved the soil characteristics in all plots favoring the growth of C. juncea and P. miliaceum. The compost provided higher concentrations of total N, nitrites, nitrates and ammonium due to the nature of this amendment and the biochar was less in measure. The limestone helped to elevate the pH and the zeolite controlled the exchangeable ions. Soils from C. juncea showed higher concentrations of N forms, suggesting that this legume contributes to the enrichment of soil N, likely due to biological fixation. Hence, the combinations limestone-zeolite-compost and limestone-zeolite-compost-biochar were the most suitable treatments for improving the soil fertility and favored plant growth. In addition, C. juncea seems to be a good candidate for reclaiming mining environments.This work was supported by Fundación Séneca (Agency of Science and Technology of the Region of Murcia, Spain) (grant number 20947/PI/18)