986 research outputs found
Effect of Sr substitution on superconductivity in Hg2(Ba1-ySry)2YCu2O8-d (part2): bond valence sum approach of the hole distribution
The effects of Sr substitution on superconductivity, and more particulary the
changes induced in the hole doping mechanism, were investigated in
Hg2(Ba1-ySry)2YCu2O8-d by a "bond valence sum" analysis with Sr content from y
= 0.0 to y = 1.0. A comparison with CuBa2YCu2O7-d and Cu2Ba2YCu2O8 systems
suggests a possible explanation of the Tc enhancement from 0 K for y = 0.0 to
42 K for y = 1.0. The charge distribution among atoms of the unit cell was
determined from the refined structure, for y = 0.0 to 1.0. It shows a charge
transfer to the superconducting CuO2 plane via two doping channels pi(1) and
pi(2), i.e. through O2(apical)-Cu and Ba/Sr-O1 bonds respectively.Comment: 13 pages, 5 figures, accepted for publication in Journal of Physics:
Condensed Matte
The Fourth Positive System of Carbon Monoxide in the Hubble Space Telescope Spectra of Comets
The rich structure of the Fourth Positive System (A-X) of carbon monoxide
accounts for many of the spectral features seen in long slit HST-STIS
observations of comets 153P/Ikeya-Zhang, C/2001 Q4 (NEAT), and C/2000 WM1
(LINEAR), as well as in the HST-GHRS spectrum of comet C/1996 B2 Hyakutake. A
detailed CO fluorescence model is developed to derive the CO abundances in
these comets by simultaneously fitting all of the observed A-X bands. The model
includes the latest values for the oscillator strengths and state parameters,
and accounts for optical depth effects due to line overlap and self-absorption.
The model fits yield radial profiles of CO column density that are consistent
with a predominantly native source for all the comets observed by STIS. The
derived CO abundances relative to water in these comets span a wide range, from
0.44% for C/2000 WM1 (LINEAR), 7.2% for 153P/Ikeya-Zhang, 8.8% for C/2001 Q4
(NEAT) to 20.9% for C/1996 B2 (Hyakutake). The subtraction of the CO spectral
features using this model leads to the first identification of a molecular
hydrogen line pumped by solar HI Lyman-beta longward of 1200A in the spectrum
of comet 153P/Ikeya-Zhang. (Abridged)Comment: 12 pages, 11 figures, ApJ accepte
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