Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu₃(μ₃‑OH)(μ-pz)₃]²⁺ (pz = pyrazolate) and Succinate Anion

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(μ₃-OH)­(μ-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu­(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu­(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added

Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu₃(μ₃‑OH)(μ-pz)₃]²⁺ (pz = pyrazolate) and Succinate Anion

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(μ₃-OH)­(μ-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu­(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu­(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added

Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu₃(μ₃‑OH)(μ-pz)₃]²⁺ (pz = pyrazolate) and Succinate Anion

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(μ₃-OH)­(μ-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu­(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu­(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added

Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu₃(μ₃‑OH)(μ-pz)₃]²⁺ (pz = pyrazolate) and Succinate Anion

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(μ₃-OH)­(μ-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu­(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu­(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added

Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu₃(μ₃‑OH)(μ-pz)₃]²⁺ (pz = pyrazolate) and Succinate Anion

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(μ₃-OH)­(μ-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu­(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu­(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added