2-Ethyl-5-nitro­aniline

The mol­ecule of the title compound, C8H10N2O2, is nearly planar [maximum deviation of 0.163 (3) Å for one of the O atoms of the NO2 group]. In the crystal structure, weak inter­molecular N—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into chains, forming R 2 2(10) ring motifs

7-Chloro-5-(2-ethoxy­phen­yl)-1-methyl-3-propyl-2,6-dihydro-1H-pyrazolo[4,3-d]pyrimidine

In the title compound, C17H21ClN4O, the benzene ring is oriented at dihedral angles of 1.59 (3) and 1.27 (3)° with respect to the pyrimidine and pyrazole rings, while the dihedral angle between the pyrimidine and pyrazole rings is 0.83 (3)°. An intra­molecular N—H⋯O hydrogen bond results in the formation of a planar (r.m.s. deviation 0.004 Å) six-membered ring

Quantum Criticality from in-situ Density Imaging

We perform large-scale Quantum Monte Carlo (QMC) simulations for strongly interacting bosons in a 2D optical lattice trap, and confirm an excellent agreement with the benchmarking in-situ density measurements by the Chicago group [1]. We further present a general finite temperature phase diagram both for the uniform and the trapped systems, and demonstrate how the universal scaling properties near the superfluid(SF)-to-Mott insulator(MI) transition can be observed by analysing the in-situ density profile. The characteristic temperature to find such quantum criticality is estimated to be of the order of the single-particle bandwidth, which should be achievable in the present or near future experiments. Finally, we examine the validity regime of the local fluctuation-dissipation theorem (FDT), which can be a used as a thermometry in the strongly interacting regime.Comment: 4 page

Poly[bis­[chlorido­cop­per(I)]-μ4-1,4-bis­[1-(3-pyridylmeth­yl)-1H-benzimid­azol-2-yl]butane]

The title CuI coordination polymer, [Cu2Cl2(C30H28N6)]n, was obtained by reaction of CuCl2·2H2O and 1,4-bis­[1-(3-pyridyl­meth­yl)-1H-benzimidazol-2-yl]butane. Each CuI cation is three-coordinated by a ClN2 donor set. The anion acts as a tetra­dentate ligand, linking CuI centres into a polymeric chain

Psychosocial Determinants of Insomnia in Adolescents: Roles of Mental Health, Behavioral Health, and Social Environment

The theoretical explanation of human problems is derived from the complex interplay of psychological, social, economic, political, and physical factors. Aims: This study examined the roles of behavioral health (i.e., alcohol abuse and suicidality) and social environment (i.e., family support, school connectedness, and favorable neighborhood) and mental health [i.e., depression, anxiety, and attention deficit hyperactivity disorder (ADHD)] in predicting insomnia in adolescents in an ecological perspective. Methods: Approximately 6445 high school students in Taiwan were administered an anonymous self-report survey. Hierarchical multiple regression was performed to examine how multidimensional social environment, behavioral health, and mental health factors were associated with insomnia in adolescents. Results: The prevalence rate of insomnia in the sample was 30%. The results indicated that alcohol abuse (β = 0.04), suicidality (β = 0.06), depression (β = 0.29), anxiety (β = 0.14), and ADHD (β = 0.11) were positively associated with insomnia (p \u3c 0.001), whereas family support (β = −0.06), school connectedness (β = −0.05), and favorable neighborhood (β = −0.10) were negatively associated with insomnia (p \u3c 0.001). Sex did not predict insomnia, but age was positively associated with insomnia (β = 0.09, p \u3c 0.001). Among all predictors of insomnia in the study, mental health factors, especially depression, play a major role on insomnia among adolescents, and is as much important as social environment factors. Conclusion: This study demonstrated how both psychosocial variables (social environment and behavioral health) and psychological symptoms were associated with insomnia in adolescents when the demographic variables (sex and age) were controlled and provided valuable information and evidence for clinicians, social workers, and health professionals who provide support to adolescents with insomnia. Applying an ecological approach in practice can aid in understanding at individual, family, school, and community levels and in identifying the strengths and weaknesses of their interactions with each other. Implications: This perspective enables practitioners in effectively treating problems and addressing the needs of the various levels, including the individual, family, school, and the broader community. Thus, prevention and intervention of insomnia in adolescents should focus on multidimensional risk and protective factors, including mental health, behavioral health, and social environment, in the context of an ecological system

Silver Metallization of Polyimide Surfaces Using EnvironmentallyFriendly Reducing Agents

Two environmentally friendly reducing agents, ascorbic acid and glucose, were employed to fabricate Ag-thin-film-coated polyimide(PI) films. Ascorbic acid is an acidic reducing agent, whereas glucose is an alkaline reducing agent. Both of these reducing agentsare capable of reducing Ag+ ions doped in poly(amic acid) (PAA) formed by hydrolysis of a PI surface. Only glucose can producea continuous and dense Ag thin film on a PAA surface. Granular and discontinuous Ag thin films were obtained when ascorbic acidwas employed as a reducing agent. This difference in reactivity is attributed to the pH values of these reducing solutions

Counting by weighing:know your numbers with confidence

Counting by weighing is often more efficient than counting manually, which is time consuming and prone to human errors, especially when the number of items (e.g. plant seeds, printed labels or coins) is large. Papers in the statistical literature have focused on how to count, by weighing, a random number of items that is close to a prespecified number in some sense. The paper considers the new problem, arising from a consultation with a company, of making inference about the number of 1p coins in a bag with known weight for infinitely many bags, by using the estimated distribution of coin weight from one calibration data set only. Specifically, a lower confidence bound has been constructed on the number of 1p coins for each of infinitely many future bags of 1p coins, as required by the company. As the same calibration data set is used repeatedly in the construction of all these lower confidence bounds, the interpretation of coverage frequency of the lower confidence bounds that is proposed is different from that of a usual confidence set

Statistical calibration and exact one-sided simultaneous tolerance intervals for polynomial regression

Statistical calibration using linear regression is a useful statistical tool having many applications. Calibration for infinitely many future y-values requires the construction of simultaneous tolerance intervals (STI’s). As calibration often involves only two variables x and y and polynomial regression is probably the most frequently used model for relating y with x, construction of STI’s for polynomial regression plays a key role in statistical calibration for infinitely many future y-values. The only exact STI’s published in the statistical literature are provided by Mee et al. (1991) and Odeh and Mee (1990). But they are for a multiple linear regression model, in which the covariates are assumed to have no functional relationships. When applied to polynomial regression, the resultant STI’s are conservative. In this paper, one-sided exact STI’s have been constructed for a polynomial regression model over any given interval. The available computer program allows the exact methods developed in this paper to be implemented easily. Real examples are given for illustration