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    Temperature Dependences of Conductivity and Magnetoconductivity of Multiwall Carbon Nanotubes Annealed at Different Temperatures

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    ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½Ρ‹ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π½Ρ‹Π΅ зависимости проводимости (Π² Π΄ΠΈΠ°ΠΏΠ°Π·ΠΎΠ½Π΅ 4.2-300 K) ΠΈ ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎ- ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ (Π² полях Π΄ΠΎ 10 ΠΊΠ“ ΠΏΡ€ΠΈ 4.2 K) многослойных ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним внСшним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 8-10 ΠΈ 20-22 Π½ΠΌ, ΠΎΡ‚ΠΎΠΆΠΆΠ΅Π½Π½Ρ‹Ρ… ΠΏΡ€ΠΈ Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Ρ… Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π°Ρ… (1600, 2200, 2600, 2800β—¦C). Показано, Ρ‡Ρ‚ΠΎ Π·Π°Π²ΠΈΡΠΈΠΌΠΎΡΡ‚ΡŒ проводимости для Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 20-22 Π½ΠΌ Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π½Π° для ΠΊΠ²Π°Π½Ρ‚ΠΎΠ²Ρ‹Ρ… ΠΏΠΎΠΏΡ€Π°Π²ΠΎΠΊ ΠΊ проводимости Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΡ… элСктронов Π² Π΄Π²ΡƒΠΌΠ΅Ρ€Π½Ρ‹Ρ… ΠΏΡ€ΠΎΠ²ΠΎΠ΄Π½ΠΈΠΊΠ°Ρ… с Π»ΠΎΠΊΠ°Π»ΡŒΠ½Ρ‹ΠΌ бСспорядком. Для Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 8- 10 Π½ΠΌ ΠΈΠΌΠ΅Π΅Ρ‚ мСсто одномСрная прыТковая ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ с ΠΏΠ΅Ρ€Π΅ΠΌΠ΅Π½Π½ΠΎΠΉ Π΄Π»ΠΈΠ½ΠΎΠΉ ΠΏΡ€Ρ‹ΠΆΠΊΠ°. Показано, Ρ‡Ρ‚ΠΎ ΠΏΡ€ΠΈ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π½ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ΅ многослойных ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ измСняСтся Π²ΠΊΠ»Π°Π΄ ΠΊΠ²Π°Π½Ρ‚ΠΎΠ²Ρ‹Ρ… ΠΏΠΎΠΏΡ€Π°Π²ΠΎΠΊ Π² ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ, Π° Ρ‚Π°ΠΊΠΆΠ΅ ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€Ρ‹ ΠΏΡ€Ρ‹ΠΆΠΊΠΎΠ²ΠΎΠΉ проводимости, Ρ‡Ρ‚ΠΎ ΠΎΡ‚ΠΆΠΈΠ³ ΠΎΠ±Ρ€Π°Π·Ρ†ΠΎΠ² влияСт Π½Π° ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ. ΠœΠ½ΠΎΠ³ΠΎΡΠ»ΠΎΠΉΠ½Ρ‹Π΅ ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Π΅ Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΊΠΈ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 20-22 Π½ΠΌ ΠΈΠΌΠ΅ΡŽΡ‚ ΠΏΠΎΠ»ΠΎΠΆΠΈΡ‚Π΅Π»ΡŒΠ½ΡƒΡŽ ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ.Temperature (in range 4.2-300 K) and magnetic field (in fields up to 10 kG at 4.2 K) dependences of the conductivity of two sets of multiwall carbon nanotubes with different average diameters (8-10 nm and 20-22 nm) heated at various temperatures (1600, 2200, 2600, 2800β—¦C) were investigated. Temperature dependences for nanotubes with average diameter 20-22 nm is typical for quantum corrections to conduc- tivity of the systems with interaction electrons in two dimensional conductors with local disorder. For nanotubes with average diameter 8-10 nm temperature dependences corresponds to one-dimensional variable range hopping conductivity (VRHC). The variation of annealing temperature of MWNTs influence on the contribution of corrections to conductivity and parameters of VRHC. The magnetoconductivity of MWNTs also depends on the annealing temperature and is less than that of highly oriented pyrographite. Annealed MWNTs with average diameter 20-22 nm has a positive magnetoconductivity

    Temperature Dependences of Conductivity and Magnetoconductivity of Multiwall Carbon Nanotubes Annealed at Different Temperatures

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    ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½Ρ‹ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π½Ρ‹Π΅ зависимости проводимости (Π² Π΄ΠΈΠ°ΠΏΠ°Π·ΠΎΠ½Π΅ 4.2-300 K) ΠΈ ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎ- ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ (Π² полях Π΄ΠΎ 10 ΠΊΠ“ ΠΏΡ€ΠΈ 4.2 K) многослойных ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним внСшним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 8-10 ΠΈ 20-22 Π½ΠΌ, ΠΎΡ‚ΠΎΠΆΠΆΠ΅Π½Π½Ρ‹Ρ… ΠΏΡ€ΠΈ Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Ρ… Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π°Ρ… (1600, 2200, 2600, 2800β—¦C). Показано, Ρ‡Ρ‚ΠΎ Π·Π°Π²ΠΈΡΠΈΠΌΠΎΡΡ‚ΡŒ проводимости для Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 20-22 Π½ΠΌ Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π½Π° для ΠΊΠ²Π°Π½Ρ‚ΠΎΠ²Ρ‹Ρ… ΠΏΠΎΠΏΡ€Π°Π²ΠΎΠΊ ΠΊ проводимости Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΡ… элСктронов Π² Π΄Π²ΡƒΠΌΠ΅Ρ€Π½Ρ‹Ρ… ΠΏΡ€ΠΎΠ²ΠΎΠ΄Π½ΠΈΠΊΠ°Ρ… с Π»ΠΎΠΊΠ°Π»ΡŒΠ½Ρ‹ΠΌ бСспорядком. Для Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 8- 10 Π½ΠΌ ΠΈΠΌΠ΅Π΅Ρ‚ мСсто одномСрная прыТковая ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ с ΠΏΠ΅Ρ€Π΅ΠΌΠ΅Π½Π½ΠΎΠΉ Π΄Π»ΠΈΠ½ΠΎΠΉ ΠΏΡ€Ρ‹ΠΆΠΊΠ°. Показано, Ρ‡Ρ‚ΠΎ ΠΏΡ€ΠΈ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π½ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ΅ многослойных ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Ρ… Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΎΠΊ измСняСтся Π²ΠΊΠ»Π°Π΄ ΠΊΠ²Π°Π½Ρ‚ΠΎΠ²Ρ‹Ρ… ΠΏΠΎΠΏΡ€Π°Π²ΠΎΠΊ Π² ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ, Π° Ρ‚Π°ΠΊΠΆΠ΅ ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€Ρ‹ ΠΏΡ€Ρ‹ΠΆΠΊΠΎΠ²ΠΎΠΉ проводимости, Ρ‡Ρ‚ΠΎ ΠΎΡ‚ΠΆΠΈΠ³ ΠΎΠ±Ρ€Π°Π·Ρ†ΠΎΠ² влияСт Π½Π° ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ. ΠœΠ½ΠΎΠ³ΠΎΡΠ»ΠΎΠΉΠ½Ρ‹Π΅ ΡƒΠ³Π»Π΅Ρ€ΠΎΠ΄Π½Ρ‹Π΅ Π½Π°Π½ΠΎΡ‚Ρ€ΡƒΠ±ΠΊΠΈ со срСдним Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€ΠΎΠΌ 20-22 Π½ΠΌ ΠΈΠΌΠ΅ΡŽΡ‚ ΠΏΠΎΠ»ΠΎΠΆΠΈΡ‚Π΅Π»ΡŒΠ½ΡƒΡŽ ΠΌΠ°Π³Π½Π΅Ρ‚ΠΎΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ.Temperature (in range 4.2-300 K) and magnetic field (in fields up to 10 kG at 4.2 K) dependences of the conductivity of two sets of multiwall carbon nanotubes with different average diameters (8-10 nm and 20-22 nm) heated at various temperatures (1600, 2200, 2600, 2800β—¦C) were investigated. Temperature dependences for nanotubes with average diameter 20-22 nm is typical for quantum corrections to conduc- tivity of the systems with interaction electrons in two dimensional conductors with local disorder. For nanotubes with average diameter 8-10 nm temperature dependences corresponds to one-dimensional variable range hopping conductivity (VRHC). The variation of annealing temperature of MWNTs influence on the contribution of corrections to conductivity and parameters of VRHC. The magnetoconductivity of MWNTs also depends on the annealing temperature and is less than that of highly oriented pyrographite. Annealed MWNTs with average diameter 20-22 nm has a positive magnetoconductivity
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