Engineering vibrationally-assisted energy transfer in a trapped-ion quantum simulator

Many important chemical and biochemical processes in the condensed phase are notoriously difficult to simulate numerically. Often this difficulty arises from the complexity of simulating dynamics resulting from coupling to structured, mesoscopic baths, for which no separation of time scales exists and statistical treatments fail. A prime example of such a process is vibrationally assisted charge or energy transfer. A quantum simulator, capable of implementing a realistic model of the system of interest, could provide insight into these processes in regimes where numerical treatments fail. We take a first step towards modeling such transfer processes using an ion trap quantum simulator. By implementing a minimal model, we observe vibrationally assisted energy transport between the electronic states of a donor and an acceptor ion augmented by coupling the donor ion to its vibration. We tune our simulator into several parameter regimes and, in particular, investigate the transfer dynamics in the nonperturbative regime often found in biochemical situations

Quantum Sensing of Intermittent Stochastic Signals

Realistic quantum sensors face a trade-off between the number of sensors measured in parallel and the control and readout fidelity ($F$) across the ensemble. We investigate how the number of sensors and fidelity affect sensitivity to continuous and intermittent signals. For continuous signals, we find that increasing the number of sensors by $1/F^2$ for $F<1$ always recovers the sensitivity achieved when $F=1$. However, when the signal is intermittent, more sensors are needed to recover the sensitivity achievable with one perfect quantum sensor. We also demonstrate the importance of near-unity control fidelity and readout at the quantum projection noise limit by estimating the frequency components of a stochastic, intermittent signal with a single trapped ion sensor. Quantum sensing has historically focused on large ensembles of sensors operated far from the standard quantum limit. The results presented in this manuscript show that this is insufficient for quantum sensing of intermittent signals and re-emphasizes the importance of the unique scaling of quantum projection noise near an eigenstate.Comment: 5 pages, 4 figure