2 research outputs found
Streaming Potential Revisited: The Influence of Convection on the Surface Conductivity
Electrokinetic
phenomena play an important role in the electrical
characterization of surfaces. In terms of planar or porous substrates,
streaming potential and/or streaming current measurements can be used
to determine the zeta potential of the substrates in contact with
aqueous electrolytes. In this work, we perform electrical impedance
spectroscopy measurements to infer the electrical resistance in a
microchannel with the same conditions as for a streaming potential
experiment. Novel correlations are derived to relate the streaming
current and streaming potential to the Reynolds number of the channel
flow. Our results not only quantify the influence of surface conductivity,
and here especially the contribution of the stagnant layer, but also
reveal that channel resistance and therefore zeta potential are influenced
by the flow in the case of low ionic strengths. We conclude that convection
can have a significant impact on the electrical double layer configuration
which is reflected by changes in the surfaces conductivity
Zeta Potential of Poly(methyl methacrylate) (PMMA) in Contact with Aqueous Electrolyte–Surfactant Solutions
The
addition of surfactants can considerably impact the electrical
characteristics of an interface, and the zeta potential measurement
is the standard method for its characterization. In this article,
a comprehensive study of the zeta potential of polyÂ(methyl methacrylate)
(PMMA) in contact with aqueous solutions containing an anionic, a
cationic, or a zwitterionic surfactant at different pH and ionic strength
values is conducted. Electrophoretic mobilities are inferred from
electrophoretic light scattering measurements of the particulate PMMA.
These values can be converted into zeta potentials using permittivity
and viscosity measurements of the continuous phase. Different behaviors
are observed for each surfactant type, which can be explained with
the various adsorption mechanisms on PMMA. For the anionic surfactant,
the absolute zeta potential value below the critical micelle concentration
(CMC) increases with the concentration, while it becomes rather constant
around the CMC. At concentrations above the CMC, the absolute zeta
potential increases again. We propose that hydrophobic-based adsorption
and, at higher concentrations, the competing micellization process
drive this behavior. The addition of cationic surfactant results in
an isoelectric point below the CMC where the negative surface charge
is neutralized by a layer of adsorbed cationic surfactant. At concentrations
near the CMC, the positive zeta potential is rather constant. In this
case, we propose that electrostatic interactions combined with hydrophobic
adsorption are responsible for the observed behavior. The zeta potential
in the presence of zwitterionic surfactant is influenced by the adsorption,
because of hydrophobic interactions between the surfactant tail and
the PMMA surface. However, there is less influence, compared to the
ionic surfactants. For all three surfactant types, the zeta potential
changes to more-negative or less-positive values for alkaline pH values,
because of hydroxide adsorption. An increase of the ionic strength
decreases the absolute value of the zeta potential, because of the
shielding effects