2 research outputs found
Nano-Structured Bio-Inorganic Hybrid Material for High Performing Oxygen Reduction Catalyst
In this study, we demonstrate a non-Pt
nanostructured bioinorganic hybrid (BIH) catalyst for catalytic oxygen
reduction in alkaline media. This catalyst was synthesized through
biomaterial hemin, nanostructured Ag–Co alloy, and graphene
nano platelets (GNP) by heat-treatment and ultrasonically processing.
This hybrid catalyst has the advantages of the combined features of
these bio and inorganic materials. A 10-fold improvement in catalytic
activity (at 0.8 V vs RHE) is achieved in comparison of pure Ag nanoparticles
(20–40 nm). The hybrid catalyst reaches 80% activity (at 0.8
V vs RHE) of the state-of-the-art catalyst (containing 40% Pt and
60% active carbon). Comparable catalytic stability for the hybrid
catalyst with the Pt catalyst is observed by chronoamperometric experiment.
The hybrid catalyst catalyzes 4-electron oxygen reduction to produce
water with fast kinetic rate. The rate constant obtained from the
hybrid catalyst (at 0.6 V vs RHE) is 4 times higher than that of pure
Ag/GNP catalyst. A catalytic model is proposed to explain the oxygen
reduction reaction at the BIH catalyst
Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions
Hydroxyapatite
(HAP, Ca<sub>10</sub>(PO<sub>4</sub>)<sub>6</sub>(OH)<sub>2</sub>)
has a hexagonal prismatic structure that exposes
two crystalline surfaces: prism-faceted a- and basal-faceted c-surfaces.
In this work, the predominant exposure of c-surface was controlled,
and its influences in methane oxidation reactions (combustion and
oxidative coupling over HAP and lead-substituted HAP (Pb-HAP), respectively)
were studied. The c-surface exposure was realized by crystal orientation
in HAP-based catalyst film, which was created by an electrochemical
deposition of HAP seeds on a titanium substrate, followed by hydrothermal
crystallization and peeling off of the crystalline films from the
substrate. In comparison to a-surface that is prevalently exposed
in unoriented HAP-based catalysts, the c-surface (i.e., (002) crystalline
plane) of HAP-based catalysts exhibited up to 47-fold enhancement
in areal rate in both reactions. The distinct catalytic activity between
these two crystalline surfaces is attributed to the preferential formation
of oxide ions and vacancies on c-surfaces. The oxide ions and vacancies
in turns function as actives sites for promoting methane activation
and complete oxidation into CO<sub>2</sub>. Density functional theory
calculations confirmed the close relationship between different catalytic
activities in c-surface of oriented and a-surface of unoriented HAP
through the tendency of vacancy formation. Without the presence of
vacancies, the methyl or methylene group after methane activation
forms ethane or ethylene via coupling. The present study explored
the effects of HAP crystal orientation in methane oxidation reactions,
which revealed distinct catalytic behaviors of crystal surfaces in
HAP-based materials