2,034 research outputs found
Direct observations of nucleation in a nondilute multicomponent alloy
The chemical pathways leading to gamma-prime(L1_2)-nucleation from nondilute
Ni-5.2 Al-14.2 Cr at.%, gamma(f.c.c.), at 873 K are followed with radial
distribution functions and isoconcentration surface analyses of direct-space
atom-probe tomographic images. Although Cr atoms initially are randomly
distributed, a distribution of congruent Ni3Al short-range order domains (SRO),
=0.6 nm, results from Al diffusion during quenching. Domain site occupancy
develops as their number density increases leading to Al-rich phase separation
by gamma-prime-nucleation, =0.75 nm, after SRO occurs.Comment: 5 pages, 4 figure
Effects of solute concentrations on kinetic pathways in Ni-Al-Cr alloys
The kinetic pathways resulting from the formation of coherent L12-ordered
y'-precipitates in the g-matrix (f.c.c.) of Ni-7.5 Al-8.5 Cr at.% and Ni-5.2
Al-14.2 Cr at.% alloys, aged at 873 K, are investigated by atom-probe
tomography (APT) over a range of aging times from 1/6 to 1024 hours; these
alloys have approximately the same volume fraction of the y'-precipitate phase.
Quantification of the phase decomposition within the framework of classical
nucleation theory reveals that the y-matrix solid-solution solute
supersaturations of both alloys provide the chemical driving force, which acts
as the primary determinant of the nucleation behavior. In the coarsening
regime, the temporal evolution of the y'-precipitate average radii and the
y-matrix supersaturations follow the predictions of classical coarsening
models, while the temporal evolution of the y'-precipitate number densities of
both alloys do not. APT results are compared to equilibrium calculations of the
pertinent solvus lines determined by employing both Thermo-Calc and
Grand-Canonical Monte Carlo simulation.Comment: Submitted to Acta Materialia, June, 200
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Atomic and Electronic Structure and Chemistry of Ceramic/Metal Interfaces. Final Report
Materials containing ceramic and metal phases play a significant role in modern materials technology
TEMPORAL EVOLUTION OF SUB-NANOMETER COMPOSITIONAL PROFILES ACROSS THE GAMMA/GAMMA' INTERFACE IN A MODEL Ni-Al-Cr SUPERALLOY
Early-stage phase separation in a Ni-5.2 Al-14.2 Cr at.% superalloy, isothermally decomposing at 873 K, is investigated with atom-probe tomography. Sub-nanometer scale compositional profiles across the gamma/gamma'(L12) interfaces demonstrate that both the gamma-matrix and the gamma'-precipitate compositions evolve with time. Observed chemical gradients of Al depletion and Cr enrichment adjacent to the gamma'-precipitates are transient, consistent with well-established model predictions for diffusion-limited growth, and mark the first detailed observation of this phenomenon. Furthermore, it is shown that Cr atoms are kinetically trapped in the growing precipitates
Compositional Pathways and Capillary Effects during Early-stage Isothermal Precipitation in a Nondilute Ni-Al-Cr Alloy
For a Ni-5.2 Al-14.2 Cr at.% alloy with moderate solute supersaturations, the compositional pathways, as measured with atom-probe tomography, during early to later stage y'(LI2)-precipitation (R = 0.45-10 nm), aged at 873 K, are discussed in light of a multi-component coarsening model. Employing nondilute thermodynamics, detailed model analyses during quasistationary coarsening of the experimental data establish that the y/y' interfacial free-energy is 22- 23+/-7 mJ/sq m. Additionally, solute diffusivities are significantly slower than model estimates. Strong quantitative evidence indicates that an observed y'-supersaturation of Al results from the Gibbs-Thomson effect, providing the first experimental verification of this phenomenon. The Gibbs-Thomson relationship, for a ternary system, as well as differences in measured phase equilibria with CALPHAD assessments, are considered in great detail
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