7,561 research outputs found

    Control of Electrophilicity in Aliphatic Friedel-Crafts Reactions

    Get PDF

    A three dimensional model of the Venusian thermosphere with superrotation

    Get PDF
    An improved three dimensional spectral model of the thermosphere of Venus is described. The model solves the Navier-Stokes equations and includes nonlinear effects for an arbitrary number of atmospheric species. A two dimensional axisymmetric model of the superrotation of the thermosphere is also presented. This model addresses the Pioneer-Venus mission finding, which suggested the thermospheric rotation rate to be much higher than that of the planet as seen from the asymmetric distribution of hydrogen and helium. Both models include the effects of an anisotropic eddy diffusion that is consistent with atmospheric mixing length theory

    Untangling the Conceptual Isssues Raised in Reydon and Scholz’s Critique of Organizational Ecology and Darwinian Populations

    Get PDF
    Reydon and Scholz raise doubts about the Darwinian status of organizational ecology by arguing that Darwinian principles are not applicable to organizational populations. Although their critique of organizational ecology’s typological essentialism is correct, they go on to reject the Darwinian status of organizational populations. This paper claims that the distinction between replicators and interactors, raised in modern philosophy of biology but not discussed by Reydon and Scholz, points the way forward for organizational ecologists. It is possible to conceptualise evolving Darwinian populations providing the inheritance mechanism is appropriately specified. By this approach, adaptation and selection are no longer dichotomised, and the evolutionary significance of knowledge transmission is highlightedPeer reviewe

    Amorphous thin film growth: theory compared with experiment

    Full text link
    Experimental results on amorphous ZrAlCu thin film growth and the dynamics of the surface morphology as predicted from a minimal nonlinear stochastic deposition equation are analysed and compared. Key points of this study are (i) an estimation procedure for coefficients entering into the growth equation and (ii) a detailed analysis and interpretation of the time evolution of the correlation length and the surface roughness. The results corroborate the usefulness of the deposition equation as a tool for studying amorphous growth processes.Comment: 7 pages including 5 figure

    The effect of Wilson line moduli on CP-violation by soft supersymmetry breaking terms

    Full text link
    The CP-violating phases in the soft supersymmetry-breaking sector in orbifold compactifications with a continuous Wilson line are investigated. In this case the modular symmetry is the Siegel modular group Sp(4,Z)Sp(4,Z) of genus two. In particular, we study the case that the hidden sector non-perturbative superpotential is determined by the Igusa cusp form C12{\cal C}_{12} of modular weight 12. The effect of large non-perturbative corrections to the dilaton K\"ahler potential on the resulting CP-violating phases is also investigated.Comment: LaTeX file, 12 pages plus 7 figures, to appear in Phys.Lett.

    Phonon anomalies and charge dynamics in Fe_{1-x}Cu_{x}Cr_{2}S_{4} single crystals

    Get PDF
    A detailed investigation of phonon excitations and charge carrier dynamics in single crystals of Fe_{1-x}Cu_{x}Cr_{2}S_{4} (x = 0, 0.2, 0.4, 0.5) has been performed by using infrared spectroscopy. In FeCr_{2}S_{4} the phonon eigenmodes are strongly affected by the onset of magnetic order. Despite enhanced screening effects, a continuous evolution of the phonon excitations can be observed in the doped compounds with x = 0.2 (metallic) and x = 0.4, 0.5 (bad metals), but the effect of magnetic ordering on the phonons is strongly reduced compared to x = 0. The Drude-like charge-carrier contribution to the optical conductivity in the doped samples indicates that the colossal magneto-resistance effect results from the suppression of spin-disorder scattering.Comment: 8 pages, 6 figure

    eingesetzt wird. A. nutzt dazu die Boolesche Logik (Algebra) mit den Operatoren AND, OR und NOT. Die logischen Operatoren ergeben folgende Mengen: A AND B

    Get PDF
    N2- Drucker, die ein Verfahren zum schnellen und kostengünstigen Erstellen von dreidimensionalen physikalischen Modellen (Prototypen) nutzen. Sie verwenden Pulvermaterialien, die sich durch Einspritzen eines Bindemittels verfestigen. 3D-D. verarbeiten CAD-Daten und sind für das „rapid prototyping “ inzwischen für unter $ 5.000 zu erwerben

    Spin-orbiton and quantum criticality in FeSc2S4

    Get PDF
    In FeSc2S4 spin-orbital exchange competes with strong spin-orbit coupling, suppressing long-range spin and orbital order and, hence, this material represents one of the rare examples of a spin-orbital liquid ground state. Moreover, it is close to a quantum-critical point separating the ordered and disordered regimes. Using THz and FIR spectroscopy we study low-lying excitations in FeSc2S4 and provide clear evidence for a spin-orbiton, an excitation of strongly entangled spins and orbitals. It becomes particularly well pronounced upon cooling, when advancing deep into the quantum-critical regime. Moreover, indications of an underlying structureless excitation continuum are found, a possible signature of quantum criticality.Comment: 11 pages, 11 figures (including 4 pages and 5 figures in Supplemental Material). Revised version according to suggestions of referees. Phys. Rev. B (in press

    Optical conductivity in multiferroic GaV4_4S8_8 and GeV4_4S8_8: Phonons and electronic transitions

    Get PDF
    We report on optical spectroscopy on the lacunar spinels GaV4_4S8_8 and GeV4_4S8_8 in the spectral range from 100 to 23000 cm1^{-1} and for temperatures from 5 to 300 K. These multiferroic spinel systems reveal Jahn-Teller driven ferroelectricity and complex magnetic order at low temperatures. We study the infrared-active phonon modes and the low-lying electronic excitations in the cubic high-temperature phase, as well as in the orbitally and in the magnetically ordered low-temperature phases. We compare the phonon modes in these two compounds, which undergo different symmetry-lowering Jahn-Teller transitions into ferroelectric and orbitally ordered phases, and exhibit different magnetic ground states. We follow the splitting of the phonon modes at the structural phase transition and detect additional splittings at the onset of antiferromagnetic order in GeV4_4S8_8. We observe electronic transitions within the dd-derived bands of the V4_4 clusters and document a significant influence of the structural and magnetic phase transitions on the narrow electronic band gaps.Comment: 12 pages, 10 figure
    corecore