3 research outputs found
Tuning the Fermi Level and the Kinetics of Surface States of TiO<sub>2</sub> Nanorods by Means of Ammonia Treatments
Ammonia-induced
reduction treatment of titanium dioxide rutile
nanorods has been performed, where the treatment triggered a synergistic
surface modification of titania electrodes that enhanced its overall
photoelectrochemical performance, besides introducing a new absorption
band in the 420ā480 nm range. A physical model has been proposed
to reveal the role of each fundamental interfacial property on the
observed behavior. On the one hand, by tuning the Fermi level position,
charge separation was optimized by adjusting the depletion region
width to maximize the potential drop inside titanium dioxide and also
filling the surface states, which in turn decreased electronāhole
recombination. On the other hand, by increasing the density of surface
holes traps (identified as surface hydroxyl groups), the average hole
lifetime was extended, depicting a more efficient hole transfer to
electrolyte species. The proposed model could serve as a rationale
for controlled interfacial adjustment of nanostructured photoelectrodes
tailoring them for the required application
Highly Specific and Wide Range NO<sub>2</sub> Sensor with Color Readout
We
present a simple and inexpensive method to implement a Griess-Saltzman-type
reaction that combines the advantages of the liquid phase method (high
specificity and fast response time) with the benefits of a solid implementation
(easy to handle). We demonstrate that the measurements can be carried
out using conventional RGB sensors; circumventing all the limitations
around the measurement of the samples with spectrometers. We also
present a method to optimize the measurement protocol and target a
specific range of NO<sub>2</sub> concentrations. We demonstrate that
it is possible to measure the concentration of NO<sub>2</sub> from
50 ppb to 300 ppm with high specificity and without modifying the
Griess-Saltzman reagent
Band Engineered Epitaxial 3D GaN-InGaN CoreāShell Rod Arrays as an Advanced Photoanode for Visible-Light-Driven Water Splitting
3D single-crystalline, well-aligned GaN-InGaN rod arrays are fabricated by selective area growth (SAG) metalāorganic vapor phase epitaxy (MOVPE) for visible-light water splitting. Epitaxial InGaN layer grows successfully on 3D GaN rods to minimize defects within the GaN-InGaN heterojunctions. The indium concentration (In ā¼ 0.30 Ā± 0.04) is rather homogeneous in InGaN shells along the radial and longitudinal directions. The growing strategy allows us to tune the band gap of the InGaN layer in order to match the visible absorption with the solar spectrum as well as to align the semiconductor bands close to the water redox potentials to achieve high efficiency. The relation between structure, surface, and photoelectrochemical property of GaN-InGaN is explored by transmission electron microscopy (TEM), electron energy loss spectroscopy (EELS), Auger electron spectroscopy (AES), currentāvoltage, and open circuit potential (OCP) measurements. The epitaxial GaN-InGaN interface, pseudomorphic InGaN thin films, homogeneous and suitable indium concentration and defined surface orientation are properties demanded for systematic study and efficient photoanodes based on III-nitride heterojunctions