A Fourier transform infrared trace gas and isotope analyser for atmospheric applications

Concern in recent decades about human impacts on Earth's climate has led to the need for improved and expanded measurement capabilities of greenhouse gases in the atmosphere. In this paper we describe in detail an in situ trace gas analyser based on Fourier Transform Infrared (FTIR) spectroscopy that is capable of simultaneous and continuous measurements of carbon dioxide (CO<sub>2</sub>), methane (CH<sub>4</sub>), carbon monoxide (CO), nitrous oxide (N<sub>2</sub>O) and <sup>13</sup>C in CO<sub>2</sub> in air with high precision. High accuracy is established by reference to measurements of standard reference gases. Stable water isotopes can also be measured in undried airstreams. The analyser is automated and allows unattended operation with minimal operator intervention. Precision and accuracy meet and exceed the compatibility targets set by the World Meteorological Organisation – Global Atmosphere Watch for baseline measurements in the unpolluted troposphere for all species except <sup>13</sup>C in CO<sub>2</sub>. <br><br> The analyser is mobile and well suited to fixed sites, tower measurements, mobile platforms and campaign-based measurements. The isotopic specificity of the optically-based technique and analysis allows its application in isotopic tracer experiments, for example in tracing variations of <sup>13</sup>C in CO<sub>2</sub> and <sup>15</sup>N in N<sub>2</sub>O. We review a number of applications illustrating use of the analyser in clean air monitoring, micrometeorological flux and tower measurements, mobile measurements on a train, and soil flux chamber measurements

Measurement of direct photon emission in K+→π+π0γK^+ \to \pi^+ \pi^0 \gamma decay using stopped positive kaons

The radiative decay $K^+ \to \pi^+ \pi^0 \gamma$ ($K_{\pi 2 \gamma}$) has been measured with stopped positive kaons. A $K_{\pi 2 \gamma}$ sample containing 4k events was analyzed, and the $K_{\pi 2 \gamma}$ branching ratio of the direct photon emission process was determined to be $[6.1\pm2.5({\rm stat})\pm1.9({\rm syst})]\times 10^{-6}$. No interference pattern with internal bremsstrahlung was observed.Comment: 12 pages, 6 figures, 2 tables, to be published in Phys. Lett.

Contributions of order O(mquark2){\cal O}(m_{\rm quark}^2) to Kℓ3K_{\ell 3} form factors and unitarity of the CKM matrix

The form factors for the $K_{\ell 3}$ semileptonic decay are computed to order $O(p^4)$ in generalized chiral perturbation theory. The main difference with the standard $O(p^4)$ expressions consists in contributions quadratic in quark masses, which are described by a single divergence-free low-energy constant, $A_3$. A new simultaneous analysis is presented for the CKM matrix element $V_{us}$, the ratio $F_K/F_{\pi}$, $K_{\ell 3}$ decay rates and the scalar form factor slope $\lambda_0$. This framework easily accommodates the precise value for $V_{ud}$ deduced from superallowed nuclear $\beta$-decays

pi-pi scattering in a QCD based model field theory

A model field theory, in which the interaction between quarks is mediated by dressed vector boson exchange, is used to analyse the pionic sector of QCD. It is shown that this model, which incorporates dynamical chiral symmetry breaking, asymptotic freedom and quark confinement, allows one to calculate $f_\pi$, $m_\pi$, $r_\pi$ and the partial wave amplitudes in $\pi$-$\pi$ scattering and obtain good agreement with the experimental data, with the latter being well described up to energies \mbox{$E\simeq 700$ MeV}.Comment: 23 Pages, 4 figures in PostScript format, PHY-7512-TH-93, REVTEX Available via anonymous ftp in /pub: login anonymou get pipi93.tex Fig1.ps Fig2.ps Fig3.ps Fig4.p

The Breathing Mode in Extended Skyrme Model

We study an extended Skyrme model which includes fourth and sixth-order terms. We explore some static properties like the $\Delta$-nucleon mass splitting and investigate the Skyrmion breathing mode in the framework of the linear response theory. We find that the monopole response function has a pronounced peak located at $\sim$ 400 MeV, which we identify to the Roper resonance $N(1440)$. As compared to the standard one, the extended Skyrme model provides a more accurate description of baryon properties.Comment: 12 pages of plain Latex and 3 figures (available from the authors), preprint IPNO/TH 93-0

A global fit of ππ\pi\pi and πK\pi K elastic scattering in ChPT with dispersion relations

We apply the one-loop results of the $SU(3)_L\times SU(3)_R$ ChPT suplemented with the inverse amplitude method to fit the available experimental data on $\pi\pi$ and $\pi K$ scattering. With esentially only three parameters we describe accurately data corresponding to six different channels, namely $(I,J)=(0,0), (2,0), (1,1), (1/2,0), (3/2,0)$ and $(1/2,1)$. In addition we reproduce the first resonances of the $(1,1)$ and $(1/2,1)$ channel with the right mass corresponding to the $\rho$ and the $K^*(892)$ particles.Comment: 19 pages, 5 figures available on request, FT/UCM/10/9

πK\pi K Scattering in Three Flavour ChPT

We present the scattering lengths for the $\pi K$ processes in the three flavour Chiral Perturbation Theory (ChPT) framework at next-to-next-to-leading order (NNLO). The calculation has been performed analytically but we only include analytical results for the dependence on the low-energy constants (LECs) at NNLO due to the size of the expressions. These results, together with resonance estimates of the NNLO LECs are used to obtain constraints on the Zweig rule suppressed LECs at NLO, $L_4^r$ and $L_6^r$. Contrary to expectations from NLO order calculations we find them to be compatible with zero. We do a preliminary study of combining the results from $\pi\pi$ scattering, $\pi K$ scattering and the scalar form-factors and find only a marginal compatibility with all experimental/dispersive input data.Comment: 23 page

Isospin breaking corrections to low-energy pi-K scattering

We evaluate the matrix elements for the processes pi^0 K^0 -> pi^0 K^0 and pi^- K^+ -> pi^0 K^0 in the presence of isospin breaking terms at leading and next-to-leading order. As a direct application the releveant combination of the S-wave scattering lengths involved in the pion-kaon atom lifetime is determined. We discuss the sensitivity of the results with respect to the input parameters.Comment: 33 pages, plain latex, 2 figure

Chiral symmetry and the pion gas virial expansion

In this work we study the thermodynamic properties of the pion gas starting from the realistic elastic scattering phase-shifts obtained from Chiral Perturbation Theory and using the virial expansion. In particular we study the state equation and the behavior of the quark condensate as a function of the temperature and the density.Comment: 16 Pages, 12 figure

Final State Interactions and Khuri-Treiman Equations in η→3π\eta\to 3\pi decays

Using extended Khuri-Treiman equations, we evaluate the final state interactions due to two-pion rescatterings to the decays $\eta\to \pi^0 \pi^+ \pi^-$ and $\eta\to \pi^0 \pi^0 \pi^0$. As subtraction to the dispersion relation we take the one-loop chiral perturbation theory result of Gasser and Leutwyler. The calculated corrections are moderate and amount to about $14\%$ in the amplitude at the center of the decay region. A careful analysis of the errors inherent to our approach is given. As a consequence, the experimental rate of the decay can only be reproduced if the double quark mass ratio $Q^{-2}\equiv\frac{m_{d}-m_{u}} {m_{s}-{\hat m}} \cdot\frac{m_{d}+m_{u}}{m_{s}+{\hat m}}$ is increased from the usual value of $1/(24.1)^2$ to $1/(22.4 \pm 0.9)^2$. We have also calculated the ratio of the rates of the two decays and various Dalitz Plot parameters. In particular, the linear slope $a$ in the charged decay is different from the one-loop value and agrees better with experiment.Comment: 55 pages, 4 Postscript figure