4 research outputs found
Volumetric, Viscometric, and Refractive Index Behavior of 7‑Hydroxy-4-methylcoumarin in Aqueous Ethanol or 1‑Propanol Solutions in the Temperature Range of (293.15 to 313.15) K
Densities
and viscosities of the pseudo binary system 7-hydroxy-4-methylcoumarin
+ (ethanol or 1-propanol) + water at temperatures of (293.15, 298.15,
303.15, 308.15, and 313.15) K and refractive indices of this system
at <i>T</i> = 298.15 K have been measured as a function
of the molality of 7-hydroxy-4-methylcoumarin. The density data have
been used to compute the apparent molar volume and limiting partial
molar volume. The viscosity <i>B</i>-coefficients and variation
of <i>B</i> with temperature have been calculated from the
viscosity data according to the Jones–Dole equation. Molar
refractions of the investigated system have been obtained from the
refractive index data. These parameters and their variation tendencies
have been expounded in terms of the interactions between solutes and
solvents. The results have shown that 7-hydroxy-4-methylcoumarin plays
a structure-making role in the given solution
Solvent and pH Dependences of Mixing Enthalpies of <i>N</i>‑Glycylglycine with Protocatechuic Acid
Protocatechuic
acid (PA) is a natural phenolic compound which has
been proven to have chemopreventive property against chemically induced
carcinogenesis. The mixing enthalpies of PA with <i>N</i>-glycylglycine in sodium phosphate and potassium phosphate buffer
solutions with different pH values have been investigated by mixing-flow
isothermal microcalorimetry at <i>T</i> = 298.15 K. The
heterotactic enthalpic interaction coefficients (<i>h</i><sub><i>xy</i></sub>) in the pH range of phosphate buffer
solution from 3.0 to 8.0 have been calculated according to the McMillan–Mayer
theory. Trends of the enthalpic pairwise interaction coefficients
(<i>h</i><sub><i>xy</i></sub>) with increasing
pH in both phosphate buffer solutions were obtained. The solvent and
pH dependence of the <i>h</i><sub><i>xy</i></sub> were discussed in terms of molecular interactions between solvated
solute molecules
Thermodynamic Difference between Protocatechualdehyde and <i>p</i>‑Hydroxybenzaldehyde in Aqueous Sodium Chloride Solutions
The
enthalpies of dilution of protocatechualdehyde and <i>p</i>-hydroxybenzaldehyde in the aqueous sodium chloride solutions
were measured by using a mixing-flow microcalorimeter at 298.15 K.
Densities of the ternary homogeneous systems at different temperatures
(293.15, 298.15, 303.15, 308.15, and 313.15 K) were also measured
with a quartz vibrating-tube densimeter. The homogeneous enthalpic
interaction coefficients (<i>h</i><sub>2</sub>, <i>h</i><sub>3</sub>, and <i>h</i><sub>4</sub>) were
calculated according to the excess enthalpy concept based on the calorimetric
data. The apparent molar volumes (<i>V</i><sub>Ï•</sub>) and standard partial molar volumes (<i>V</i><sub>Ï•</sub><sup>0</sup>) of the
investigated system were computed from their density data. The variation
trends in <i>h</i><sub>2</sub> and <i>V</i><sub>Ï•</sub><sup>0</sup> with increasing
salt molality were obtained and discussed in terms of the (solute
+ solute) and (solute + solvent) interactions. The experimental results
showed that the molecular structures of protocatechualdehyde and <i>p</i>-hydroxybenzaldehyde, especially the number of hydroxyl
groups, have evident influence on their thermodynamic properties.
The thermodynamic data obtained in this work may be helpful for exploring
the structure–function relationship of protocatechualdehyde
and <i>p</i>-hydroxybenzaldehyde
Additional file 1: Figures S1–S6. of Facile Fabrication of Bi2WO6/Ag2S Heterostructure with Enhanced Visible-Light-Driven Photocatalytic Performances
The EDS, BET surface area, and Zeta potential analysis for the as-formed heterostructures, the XRD pattern of Ag2S, and the temporal evolution of Rh B absorption spectra over Bi2WO6/Ag2S heterostructure at different pH values. Figure S1. Elemental mapping and EDX spectra of the Bi2WO6/Ag2S heterostructure. Figure S2. EDS spectra of the composite photocatalysts Bi2WO6/Ag2S. Figure S3. Nitrogen adsorption-desorption isotherms and the pore size distribution curve (inset) of sample (a) Bi2WO6 and (b) Bi2WO6/Ag2S. Figure S4. XRD pattern of Ag2S. Figure S5. Zeta potential for a suspension containing 1 g L of sample Bi2WO6/Ag2S in the presence of KCl (10−3 M) at different pH values. Figure S6. The temporal evolution of Rh B absorption spectra over Bi2WO6/Ag2S heterostructure at different pH values