Toward an electrical power utility for space exploration

Plans for space exploration depend on today's technology programs addressing the novel requirements of space-based enterprise. The requirements for electrical power will be formidable: megawatts in magnitude, reliability for multi-year missions and the flexibility to adapt to needs unanticipated at design time. The reasons for considering the power management and distribution in the various systems from a total mission perspective, rather than simply extrapolating current spacecraft design practice, are discussed. A utility approach to electric power being developed at the Lewis Research Center is described. It integrates requirements from a broad selection of current development programs with studies in which both space and terrestrial technologies are conceptually applied to exploration mission scenarios

Spacecraft 2000: The challenge of the future

Considerable opportunity exists to improve the systems, subsystems, components, etc., included in the space station bus, the non-payload portion of the spacecraft. The steps followed to date, the challenges being faced by industry, and the progress toward establishing a new NASA initiative which will identify the technologies required to build spacecraft of the 21st century and which will implement the technology development/validation programs necessary are described

Spacecraft 2000 program overview

The goals are to identify the critical need and technologies for spacecraft of the 21st century, and to recommend technology development and validation programs and possible government/industrial roles and partnerships. The objectives of the workshop are to increase awareness and exchange ideas among participants, highlight the spacecraft as a focal point for technology, and facilitate industry-government coordination

Operational environments for electrical power wiring on NASA space systems

Electrical wiring systems are used extensively on NASA space systems for power management and distribution, control and command, and data transmission. The reliability of these systems when exposed to the harsh environments of space is very critical to mission success and crew safety. Failures have been reported both on the ground and in flight due to arc tracking in the wiring harnesses, made possible by insulation degradation. This report was written as part of a NASA Office of Safety and Mission Assurance (Code Q) program to identify and characterize wiring systems in terms of their potential use in aerospace vehicles. The goal of the program is to provide the information and guidance needed to develop and qualify reliable, safe, lightweight wiring systems, which are resistant to arc tracking and suitable for use in space power applications. This report identifies the environments in which NASA spacecraft will operate, and determines the specific NASA testing requirements. A summary of related test programs is also given in this report. This data will be valuable to spacecraft designers in determining the best wiring constructions for the various NASA applications

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO_2 Fixation

Two major energy-related problems confront the world in the next 50 years. First, increased worldwide competition for gradually depleting fossil fuel reserves (derived from past photosynthesis) will lead to higher costs, both monetarily and politically. Second, atmospheric CO_2 levels are at their highest recorded level since records began. Further increases are predicted to produce large and uncontrollable impacts on the world climate. These projected impacts extend beyond climate to ocean acidification, because the ocean is a major sink for atmospheric CO2.1 Providing a future energy supply that is secure and CO_2-neutral will require switching to nonfossil energy sources such as wind, solar, nuclear, and geothermal energy and developing methods for transforming the energy produced by these new sources into forms that can be stored, transported, and used upon demand

Accuracy of Rapid Tests Used for Analysis of Advanced Onsite Wastewater Treatment System Effluent

Rapid tests provide an inexpensive, desirable alternative to standard laboratory analyses for testing advanced onsite wastewater treatment system (OWTS) effluent in the field. Despite their potential utility, their accuracy for analysis of effluent from advanced OWTS has not been assessed. We evaluated the accuracy of an initial suite of rapid tests commonly used to analyze wastewater (test strips for ammonium, pH, nitrate, and alkalinity; pH pocket meter; titration kit for dissolved oxygen (DO)) by comparing values obtained in the field to values obtained using standard laboratory methods. We tested final effluent from three different advanced nitrogen removal OWTS technologies sampled monthly for 7 months at 42 different sites within the greater Narragansett Bay watershed in Rhode Island, USA. Significant differences between values obtained using field and standard methods were found only for nitrate and pH test strips when the data were analyzed using ANOVA on ranks. However, regression analysis indicated that all test strip-based rapid methods and the DO titration kit produced values that deviated significantly from correspondence with standard analyses. When effluent samples were analyzed in the laboratory (to minimize sources of variability) using the same rapid tests, significant differences between rapid tests and standard analysis disappeared for all the tests. Evaluation of a suite of alternative rapid tests for ammonium, nitrate, pH, and alkalinity indicated that test kits for NH4+ and multi-analysis test strips for pH provide accurate results in the field. Our results indicate that the accuracy of rapid tests needs to be evaluated under field conditions before they are used to assess effluent from advanced N-removing OWTS

Palladium(II) agostic complex : exchange of Aryl–Pd and Alkyl–Pd bonds

Cyclopalladation of 2-tbutyl-6-(4-fluorophenyl)pyridine with palladium acetate cleanly gives cyclometalated complex 3 with an aryl–Pd bond. Replacement of the acetates by chloride gives the monomeric species 4 with a crystal structure confirming the presence of an agostic interaction from the alkyl group. Reaction of 3 with Na(acac) initially gives the monomeric acac complex 5 which maintains the aryl–Pd bond. Complex 5 shows fluxional behavior of the acac group, and this provides a pathway for its isomerization to complex 6 which has an alkyl–Pd bond; complex 6 was characterized crystallographically. Reaction of agostic 4 with triphenylphosphine gives an initial complex that maintains the aryl–Pd bond, but this complex isomerizes to crystallographically characterized 8 which has an alkyl–Pd bond