982 research outputs found
Noord-Frankrijk en (West-) Vlaanderen: partners voor de toekomst, grensoverschreidende samenwerking: stand van zaken en krachtlijnen voor een beleidsvisie
Kwantificeren van recente veranderingen in status van amfibieën en hun biotopen in het landelijk gebied: evaluatie en niet-technische samenvatting
Commensurate and Incommensurate Vortex States in Superconductors with Periodic Pinning Arrays
As a function of applied field, we find a rich variety of ordered and
partially-ordered vortex lattice configurations in systems with square or
triangular arrays of pinning sites. We present formulas that predict the
matching fields at which commensurate vortex configurations occur and the
vortex lattice orientation with respect to the pinning lattice. Our results are
in excellent agreement with recent imaging experiments on square pinning arrays
[K. Harada et al., Science 274, 1167 (1996)].Comment: 9 pages, 3 figures. Accepted to Physical Review
Solution-processable thienoisoindigo-based molecular donors for organic solar cells with high open-circuit voltage
Two acetylene-bridged Donor–Acceptor–Donor (D-A-D) type small pi-conjugated molecules involving triphenylamine or N-phenylcarbazole as donor blocks (D) and thienoisoindigo as the acceptor unit (A) were synthesized and characterized by UV–Vis absorption and cyclic voltammetry. These donor materials were mixed with [6,6]-phenyl-C61-butyric acid methyl ester to prepare bulk heterojunction solar cells by simple solution processing. Due to their low-lying highest occupied molecular orbital energy levels, high open-circuit voltages up to 0.99 V were measured. The triphenylamine end-capped derivative led to the best power conversion efficiency of ca 2.20%, which ranks among the highest reported value for thienoisoindigo-based materials
Characterization of immune response to neurofilament light in experimental autoimmune encephalomyelitis
PMCID: PMC3856490This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.PMCID: PMC385649
Analysis of cyt0kine gene expression in stimulated T cells of small children by semi-quantitative PCR
Only limited amounts of peripheral blood samples can be obtained from small children. Therefore, a polymerase chain reaction (PCR) aided analysis of cytokine gene expression by PBMC or T cells is a valuable tool. We present a combination of procedures to obtain an accurate estimation of the expression of the cytokines IL-4 and IFN-γ. This can be performed on T cells purified from blood samples of up to 5 ml in volume from children aged 0–4 years with allergic asthma and atopic dermatitis. This procedure includes multiple sampling of PCR products to determine the linear phase of the PCR; inter-experiment correction using a helper T-cell clone, expressing both IL-4 and IFN-γ; interpatient correction by comparing the expression of a housekeeping gene (HPRT); and finally the development of specific software to analyse densitometric data obtained by scanning photographs of agarose gels, separating PCR products. In this way it is possible to study cytokine gene expression from a very small amount of material
Doped ordered mesoporous carbons as novel, selective electrocatalysts for the reduction of nitrobenzene to aniline
Ordered mesoporous carbons (OMCs) doped with nitrogen, phosphorus or boron were synthesised through a two-step nanocasting method and studied as electrocatalysts for the reduction of nitrobenzene to aniline in a half-cell setup. The nature of the dopant played a crucial role in the electrocatalytic performance of the doped OMCs, which was monitored by LSV with a rotating disk electrode setup. The incorporation of boron generated the electrocatalysts with the highest kinetic current density, whereas the incorporation of phosphorus led to the lowest overpotential. Doping with nitrogen led to intermediate behaviour in terms of onset potential and kinetic current density, but provided the highest selectivity towards aniline, thus resulting in the most promising electrocatalyst developed in this study. Density functional theory calculations allowed explaining the observed difference in the onset potentials between the various doped OMCs, and indicated that both graphiticN and pyrdinic N can generate active sites in the N-doped electrocatalyst. A chronoamperometric experiment over N-doped OMC performed at -0.75 V vs. Fc/Fc(+) in an acidic environment, resulted in a conversion of 61% with an overall selectivity of 87% to aniline. These are the highest activity and selectivity ever reported for an electrocatalyst for the reduction of nitrobenzene to aniline, making N-doped OMC a promising candidate for the electrochemical cogeneration of this industrially relevant product and electricity in a fuel cell setup
Multiply quantized vortices in trapped Bose-Einstein condensates
Vortex configurations in rotating Bose-Einstein condensed gases trapped in
power-law and anharmonic potentials are studied. When the confining potential
is steeper than harmonic in the plane perpendicular to the axis of rotation,
vortices with quantum numbers larger than one are energetically favorable if
the interaction is weak enough. Features of the wave function for small and
intermediate rotation frequencies are investigated numerically.Comment: 9 pages, 6 figures. Revised and extended article following referee
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