73 research outputs found
Infrared Multiple Photon Dissociation Action Spectroscopy and Theoretical Studies of Triethyl Phosphate Complexes: Effects of Protonation and Sodium Cationization on Structure
Deamidation Reactions of Asparagine- and Glutamine-Containing Dipeptides Investigated by Ion Spectroscopy
On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions
Thermodynamics and Mechanism of Protonated Cysteine Decomposition: A Guided Ion Beam and Computational Study
Reactions of Th(+) + H2, D2, and HD Studied by Guided Ion Beam Tandem Mass Spectrometry and Quantum Chemical Calculations.
Kinetic energy dependent reactions of Th(+) with H2, D2, and HD were studied using a guided ion beam tandem mass spectrometer. Formation of ThH(+) and ThD(+) is endothermic in all cases with similar thresholds. Branching ratio results for the reaction with HD indicate that Th(+) reacts via a statistical mechanism, similar to Hf(+). The kinetic energy dependent cross sections for formation of ThH(+) and ThD(+) were evaluated to determine a 0 K bond dissociation energy (BDE) of D0(Th(+)-H) = 2.45 ± 0.07 eV. This value is in good agreement with a previous result obtained from analysis of the Th(+) + CH4 reaction. D0(Th(+)-H) is observed to be larger than its transition metal congeners, TiH(+), ZrH(+), and HfH(+), believed to be a result of lanthanide contraction. The reactions with H2 were also explored using quantum chemical calculations that include a semiempirical estimation and explicit calculation of spin-orbit contributions. These calculations agree nicely and indicate that ThH(+) most likely has a (3)Δ1 ground level with a low-lying (1)Σ(+) excited state. Theory also provides the reaction potential energy surfaces and BDEs that are in reasonable agreement with experiment
Activation of carbon dioxide by a terminal uranium-nitrogen bond in the gas-phase: a demonstration of the principle of microscopic reversibility.
Activation of CO2 is demonstrated by its spontaneous dissociative reaction with the gas-phase anion complex NUOCl2(-), which can be considered as NUO(+) coordinated by two chloride anion ligands. This reaction was previously predicted by density functional theory to occur exothermically, without barriers above the reactant energy. The present results demonstrate the validity of the prediction of microscopic reversibility, and provide a rare case of spontaneous dissociative addition of CO2 to a gas-phase complex. The activation of CO2 by NUOCl2(-) proceeds by conversion of a U[triple bond, length as m-dash]N bond to a U[double bond, length as m-dash]O bond and creation of an isocyanate ligand to yield the complex UO2(NCO)Cl2(-), in which uranyl, UO2(2+), is coordinated by one isocyanate and two chloride anion ligands. This activation of CO2 by a uranium(vi) nitride complex is distinctive from previous reports of oxidative insertion of CO2 into lower oxidation state U(iii) or U(iv) solid complexes, during which both C-O bonds remain intact. This unusual observation of spontaneous addition and activation of CO2 by NUOCl2(-) is a result of the high oxophilicity of uranium. If the computed Gibbs free energy of the reaction pathway, rather than the energy, is considered, there are barriers above the reactant asymptotes such that the observed reaction should not proceed under thermal conditions. This result provides a demonstration that energy rather than Gibbs free energy determines reactivity under low-pressure bimolecular conditions
Kinetic Energy Dependence of Competitive Spin-Allowed and Spin-Forbidden Reactions: V<sup>+</sup> + CS<sub>2</sub>
Recommended from our members
Reactions of U+ with H2, D2, and HD Studied by Guided Ion Beam Tandem Mass Spectrometry and Theory.
The kinetic energy-dependent reactions of the atomic actinide uranium cation (U+) with H2, D2, and HD were examined by guided ion beam tandem mass spectrometry. An average 0 K bond dissociation energy of D0(U+ - H) = 2.48 ± 0.06 eV is obtained by analysis of the endothermic product ion cross sections. Quantum chemistry calculations were performed for comparison with experimental thermochemistry, including high-level CASSCF-CASPT2-RASSI calculations of the spin-orbit corrections. CCSD(T) and the CASSCF levels show excellent agreement with experiment, whereas B3LYP and PBE0 slightly overestimate and the M06 approach badly underestimates the bond energy for UH+. Theory was also used to investigate the electronic structures of the reaction intermediates and potential energy surfaces. The experimental product branching ratio for the reaction of U+ with HD indicates that these reactions occur primarily via a direct reaction mechanism, despite the presence of a deep-well for UH2+ formation according to theory. The reactivity and hydride bond energy for U+ are compared with those for transition metal, lanthanide, and actinide cations, and periodic trends are discussed. These comparisons suggest that the 5f electrons on uranium are largely core and uninvolved in the reactive chemistry
- …