Simultaneous removal of organic and nitrogenous compounds in mature landfill leachate by a hybrid electro-oxidation-dialysis (EOD) system

Electrochemical process has been widely applied to eliminate recalcitrant contaminants (i.e., organic and nitrogenous compounds) in landfill leachate. This study aimed to evaluate the performance of a hybrid electro-oxidation-dialysis (EOD) system to minimize organic and nitrogenous compounds through a synergistic process of electrochemical oxidation (EO) and electrodialysis (ED) as well as the dissolved organic matter was characterized in terms of fluorescent component and molecular weight distribution. The EOD was carried out using boron-doped diamond (BDD) and Pt alternately. The results have shown that pH adjustment to acidic conditions is beneficial to EO. At optimal pH (pH 4), BDD-based EO is superior to remove COD and NH4+ up to around 56% and 64%, respectively. During EOD process, the lower current density at 20.83 mA cm–2 is preferred for the recovery of nitrogenous ions (i.e., NH4+ and NO3-), especially for BDD-EOD. In addition, the dominant humic acid-like (HAL) and soluble microbial products-like (SMPL) substances in the mature leachate are mostly degraded to smaller molecules from 105 Da to 103 Da in both EOD processes. Overall, BDD-EOD favors indirect oxidation and has a higher energy consumption efficiency than Pt-EOD induced by direct oxidation for simultaneous removal of organic and nitrogenous compounds. BDD-EOD requires a lower total operation cost around $2.33/m3 compared to Pt-EOD. It is concluded that hybrid BDD-EOD process is technically feasible as a powerful pre-treatment approach to mature landfill leachate for refractory organics degradation and nitrogenous nutrients recovery.</p