3 research outputs found
Additional file 1 of Modified nano magnetic Fe2O3-MgO as a high active multifunctional heterogeneous catalyst for environmentally beneficial carbon–carbon synthesis
Additional file 1: Supplementary Material 1
Superparamagnetic Fe(OH)<sub>3</sub>@Fe<sub>3</sub>O<sub>4</sub> Nanoparticles: An Efficient and Recoverable Catalyst for Tandem Oxidative Amidation of Alcohols with Amine Hydrochloride Salts
Magnetic FeÂ(OH)<sub>3</sub>@Fe<sub>3</sub>O<sub>4</sub> nanoparticles
were successfully prepared and characterized. This magnetic nanocomposite
was employed as an efficient, reusable, and environmentally benign
heterogeneous catalyst for the direct amidation of alcohols with amine
hydrochloride salts. Several derivatives of primary, secondary and
tertiary amides were synthesized in moderate to good yields in the
presence of this catalytic system. The catalyst was successfully recycled
and reused up to six times without significant loss of its catalytic
activity
Modifying Effect of Imidazolium-Based Ionic Liquids on Surface Activity and Self-Assembled Nanostructures of Sodium Dodecyl Sulfate
The
effect of four cationic ionic liquids (ILs), 1-butyl-3-methylimidazolium
chloride (BMImCl), 1-butyl-3-methylimidazolium bromide (BMImBr), 1-hexyl-3-methylimidazolium
chloride (HMImCl), and 1-hexyl-3-methyl-imidazolium bromide (HMImBr)
on surface activity and micellization of an anionic surfactant, sodium
dodecyl sulfate (SDS), is studied. The thermodynamic data on micellization
and surface adsorption are obtained from tensiometry and conductometry.
The applicability of UV–visible spectroscopy to study of SDS/IL
systems is also investigated using Crystal Violet as the probe. Cyclic
voltammetry, dynamic light scattering, and TEM imaging are employed
to investigate the size and morphology of aggregates. According to
the findings, addition of butyl-chained ILs to aqueous SDS results
in only a slight gradual increase in average aggregate size whereas
the size of SDS assemblies are dramatically increased upon addition
of hexyl-chained ILs. It is proposed that BMIm<sup>+</sup> cations
of the IL undergo Coulombic attractive interactions with anionic headgroups
adsorbed at the micellar surface in aqueous SDS whereas HMIm<sup>+</sup> interact through hydrophobic chain–chain attractions as well.
Thus, mixed micellization results in formation of vesicles. A micellar
phase change from vesicles to micelles takes place at higher [SDS]/[IL]
ratios. All of these processes are successfully tracked by the employed
techniques