Primary gas thermometry by means of laser-absorption spectroscopy: Determination of the Boltzmann constant

We report on a new optical implementation of primary gas thermometry based on laser absorption spectrometry in the near infrared. The method consists in retrieving the Doppler broadening from highly accurate observations of the line shape of the R(12) $\nu_{1} + 2 \nu_{2}^{\phantom{1}0} + \nu_{3}$ transition in CO$_{2}$ gas at thermodynamic equilibrium. Doppler width measurements as a function of gas temperature, ranging between the triple point of water and the gallium melting point, allowed for a spectroscopic determination of the Boltzmann constant with a relative accuracy of $\sim1.6\times10^{-4}$.Comment: Submitted to Physical Review Letter

Evaluation of Mater Bi and Polylactic Acid as materials for biodegradable innovative mini-radiosondes to track small scale fluctuations within clouds

Turbulence plays an important part in determining the chemical and physical processes, on both the micro- and macro-scales, whereby clouds are formed and behave. However, exactly how these are linked together and how turbulence impacts each of these processes is not yet fully understood. This is partly due to a lack of in-situ small scale fluctuation measurements due to a limitation in the available technology. It is in this context that the radiosondes, for which the material characterisation is presented in this paper, are being developed to generate a Lagrangian set of data which can be used to improve the ever-expanding knowledge of atmospheric processes and, in particular, the understanding of the interaction between turbulence and micro-physical phenomenologies inside clouds (www.complete-h2020network.eu). Specifically, the materials developed for the balloons are discussed in further detail within this paper. Mater Bi and polylactic acid are the two common biodegradable thermoplastics that were used initially to make the balloons. To tailor their properties, the balloons were then coated with carnauba wax blended with either pine resin or SiO2 nanoparticles. The properties such as hydrophobicity, toughness, elasticity and helium gas permeability are investigated and improved in order to keep the density of the radiosondes as constant as possible for a couple of hours. This will allow them to float inside and outside clouds on an isopycnic surface, to measure various properties such as velocity, temperature, pressure and humidity by means of solid state sensors and to transmit them to receivers on Earth. Tests have been made under a rigorous metrological approach comparing the 6 new materials with two reference balloon materials, latex and mylar. It was found that Mater Bi with the two carnauba wax coatings is the most suited though its roughness and water vapour permeability should be improved