44 research outputs found

    电致发光成像技术在硅太阳能电池隐性缺陷检测中的应用

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    论述了一种利用硅太阳能电池在一定偏压下的电致发光(Electrolum inescence,EL)成像来检测硅太阳能电池隐性缺陷的方法。硅太阳能电池的EL波长范围为850~1200 nm。正向偏压下的EL光强反映了少数载流子的浓度及其扩散长度,而反向偏压下的EL区和发光强度对应于电池的缺陷区域和缺陷密度。用硅CCD相机对硅太阳能电池的EL快速成像,然后根据EL成像的明暗强度可检测出电池的隐性缺陷。由于内在缺陷处EL强度比外在缺陷处受温度的影响更敏感,所以可利用电池缺陷处EL强度随温度变化的差异来辨别缺陷的类型

    High purity trigonal selenium nanorods growth via laser ablation under controlled temperature

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    通讯作者地址: Xie, ZX (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R ChinaBy utilizing laser ablation, high purity trigonal selenium nanorods with different size have been synthesized from selenium powders. The high purity of the nanorods is attributed to freestanding growth process without catalyst or template. Its morphologies depend on both substrate temperature and reaction time. By controlling the experimental conditions, selenium nanorods with lateral dimensions in different range can be synthesized ranging from 20 nm to several hundred nanometers in width, and up to 10 mum in lengths. (C) 2002 Elsevier Science B.V. All rights reserved

    Low temperature solvothermal synthesis of crumpled carbon nanosheets

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    通讯作者地址: Xie, ZX (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Siming Nanlu 422, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 电子邮件地址: [email protected] carbon nanosheets have been successfully synthesized via a catalyst-free solvothermal route at very low temperatures (60-100 degreesC), using tetrachloromethane as the carbon source and potassium as the reductant. The X-ray powder diffraction pattern indicates that the products are hexagonal graphite. Transmission and scanning electron microscopy show that the thickness of crumpled carbon nanosheets ranges from 3 to 8 nm. Raman spectroscopy supports the existence of graphitized carbon at the nanoscale. BET experiments show that carbon nanosheets have a large surface area. Compared with previous methods to prepare graphite nanosheets, such a low reaction temperature has attractive advantages

    Controllable growth of In(OH)(3) nanorods with rod-in-rod structure in a surfactant solution

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    通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Dept Chem, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Dept Chem, Xiamen 361005, Peoples R ChinaThe In(OH)(3) nanorods (25-55 nm in diameter and 120-200 nm in length) bearing parallel subunit nanorods (diameters ranging from 8 to 10 nm) were synthesized by controlling hydrolysis of indium nitrate in the presence of hexamethylene tetraamine and cetyltrimethylammonium bromide. (C) 2003 Elsevier B.V. All rights reserved

    Rational Design and Fabrication of ZnO Nanotubes from Nanowire Templates in a Microwave Plasma System

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    通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R ChinaA nanowire-nanocable-nanotube scheme was designed for fabricating tubular ZnO in a microwave plasma system. Depending on optimal reaction conditions, diameters (from submicrometer to nanometer) and wall thicknesses of the tubular ZnOs can be controlled in the process. Data from morphology analyses, X-ray diffraction, photoluminescence spectra and Raman spectroscopy of the as-prepared ZnO nanotubes support the validity of the proposed three-step route for the fabrication of tubular ZnO

    Starlike nanostructures of polyoxometalates K-3[PMo12O40].nH(2)O synthesized and assembled by an inverse microemulsion method

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    通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R ChinaIn a nonionic inverse microemulsion system, surfactant (C12-18EO9)/cyclohexane/water, heteropolyanions [PMo12O40](3-) react with K+ to form K-3[PMo12O40].nH(2)O nanorods and assemble as three-dimensional starlike nanostructures

    Two I-h-symmetry-breaking C-60 isomers stabilized by chlorination

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    通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 电子邮件地址: [email protected] abiding surprise in fullerene science is that I-h-symmetric buckminsterfullerene C-60 (ref. 1) (I-h-C-60 or C-#1,812(60), the nomenclature specified by symmetry or by Fowler's spiral algorithm(2)) remains the sole C-60 species experimentally available. Setting it apart from the other 1,811 topological isomers (isobuckminsterfullerenes) is its exclusive conformity with the isolated-pentagon rule(3), which states that stable fullerenes have isolated pentagons. Although gas-phase existence of isobuckminsterfullerenes has long been suspected(4-7), synthetic efforts have yet to yield successful results. Here, we report the realization of two isobuckminsterfullerenes by means of chlorination of the respective C-2v-and C-s-symmetric C-60 cages. These chlorinated species, (C60Cl8)-C-#1,809(1) and (C60Cl12)-C-#1,804(2), were isolated in experimentally useful yields. Structural characterization by crystallography unambiguously established the unique pentagon-pentagon ring fusions. These distinct structural features are directly responsible for the regioselectivity observed in subsequent substitution of chlorines, and also render these unprecedented derivatives of C60 isomers important for resolving the long-standing puzzle of fullerene formation by the Stone-Wales transformation scheme(8-11).NNSF of China,20525103 ,20531050 ,20721001 , 20571062 ,20425312 973 Program 2007CB81530

    兰州重离子研究装置(HIRFL)的辐射防护

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    本文介绍了兰州重离子研究装置(HIRFL)的辐射防护概况。分五个部分:(1)装置概况;(2)辐射发射率;(3)辐射屏蔽;(4)感生放射性及其对环境的影响;(5)区域监测及安全系统
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