Surface Plasmon Coupled Emission for Polymer Films

表面等离子体耦合发射荧光（SPCE）是利用激发态的荧光团和金属表面等离子体的耦合近场作用而建立起来的一种新型的表面增强荧光技术，具有角度定向性、波长分辨性、距离依赖性、信号偏振性和背景抑制作用等多种独特的光学特性，在化学分析、生物传感、细胞成像等领域中显现出广阔的应用前景。聚合物刷已经成为一种典型的软物质界面材料，由于其化学组成与空间构型的不同，对pH值、温度、溶剂、光和离子等多种环境刺激会产生响应，促使表面形貌、厚度或润湿性发生变化。将聚合物刷受刺激后产生的厚度变化特性与SPCE的距离依赖性相结合，可以制备各种用途的传感器。Kretschmann（KR）模式SPCE荧光的研究利用尚少。本文在...Surface plasmon coupled emission (SPCE) technique, based on the near-field interaction between fluorophores and surface plasmons on metal surfaces, has attracted increasing attention in sensor technology, bioanalysis, and cell imaging as it displays unique optical properties like strongly directional emission, unique polarization, wavelength resolution, thickness dependence and background suppress...学位：理学博士院系专业：化学化工学院_化学生物学学号：2052009015330

Adsorptive Stripping Voltammetry in a Flow-through Thin Layer Cell for the Determination of Chloramphenicol in Fish Meats

论文研制了一种半流动薄层电解池，该电解池采用玻碳为工作电极，对玻碳电极表面活化过程和活化后的玻碳电极对氯霉素的吸附作用进行了研究，建立了半流动薄层吸附伏安法，并成功地将该方法用于鱼肉氯霉素残留的快速检测。本论文共分四章。第一章分别介绍了薄层电化学和吸附伏安法的原理、特点、应用以及氯霉素的各种检测方法，提出本文研究半流动薄层吸附伏安法并将其用于鱼肉中氯霉素残留快速检测的技术路线和创新意义。第二章介绍了所研制的半流动薄层电解池，利用该电解池对氯霉素在更宽电位范围（相对于汞电极）内的电化学行为进行了初步探讨，并研究了薄层池的结构（电极面积、薄层厚度）对氯霉素伏安行为的影响。第三章分为两节：第一节考察...A flow-through thin layer cell is designed and fabricated. A rapid and sensitive method, based on the adsorptive accumulation of chloramphenicol at the electrochemically pretreated glassy carbon electrode in the above mentioned thin layer cell, for determination of chloramphenicol residues in fish meats has been developed. Chapter one presents a brief overview of thin layer electrochemistry, ad...学位：理学硕士院系专业：化学化工学院化学系_分析化学学号：20012500

如何精准做好化学教学实验室的建设

主要介绍了厦门大学化学国家级实验教学示范中心在实验室细化建设方面的具体做法,如实验室的给排水、供配电、通风等系统工程和实验家具的精准设计和精准施工,以期更好地为国内高校化学教学实验室的细化设计和细化建设提供适应面广、操作性强的可借鉴经验。2016年度教育部“基础学科拔尖学生培养试验计划”研究课题;;2017年福建省本科高校教育教学改革研究项目(FBJG20170295);;2017年度厦门大学教学改革研究项目(JG20170204);;国家基础科学人才培养基金项目(J1310024

Application of "6S" in the Management of Basic Chemistry Teaching Laboratory

主要介绍“6S管理”在厦门大学基础化学教学实验室内部细化管理过程中的应用实践与效果,特别是实验环境、物品定位管理、试剂管理、仪器管理等方面的具体做法,为高校化学教学实验室的建设和有效管理提供适应面广、操作性强的可借鉴经验。2016年度教育部“基础学科拔尖学生培养试验计划”研究课题;福建省高等学校教学改革研究项目(JAS14634);国家基础科学人才培养基金项目(J1310024

基础化学教学实验室试剂和仪器的科学细化管理

介绍了厦门大学化学国家级实验教学示范中心基础化学实验(一)实验室在试剂和仪器科学细化管理方面的一些具体做法,如试剂的排序存放、计划补充、优化使用及仪器的\"五防\"和\"三位一体\"管理模式。通过对试剂、仪器一系列规范、有序、科学的细化管理,节约了试剂用量,减少了废物排放量,保证了干净整洁的实验环境;培养了学生良好的实验习惯,保证了仪器的正常运行及获得准确的实验数据,并提高了仪器的使用寿命,为实验教学的顺利开展提供了有力的保障。希望能为国内高校化学教学实验室相关方面管理提供可借鉴的经验。2016年度教育部“基础学科拔尖学生培养试验计划”研究课题;;\n2017年福建省本科高校教育教学改革研究项目(FBJG20170295);;\n2017年度厦门大学教学改革研究项目(JG20170204);;\n国家基础科学人才培养基金项目(J1310024

科学做好基础化学实验的细化准备

科学做好基础化学实验的细化准备,为实验教学提供更高效的服务,是实验室建设与管理内涵建设的内容之一。本文介绍了厦门大学化学国家级实验教学示范中心无机及化学分析实验教学准备工作的一些具体做法和经验,以期为高校基础化学实验的准备工作提供适用的参考与借鉴。2016年度教育部“基础学科拔尖学生培养试验计划”研究课题;;2017年福建省本科高校教育教学改革研究项目(FBJG20170295);;2017年度厦门大学教学改革研究项目(JG20170204);;国家基础科学人才培养基金项目(J1310024

Combustion Oxidation Coupled to Ion Chromatography to Determine Chlorine and Sulfur Content in Methanol and Charcoal Using I~-/I_3~- Solution as the Absorbent

提出采用燃烧氧化偶联离子色谱法测定甲醇、碳黑中的氯和硫的含量。方法通过在管式炉中燃烧将甲醇、碳黑中的氯及硫转化为Cl2、HCl,SO2,SO3等气态物质。选用I-/I3-溶液作为燃烧产物的吸收剂。I-/I3-溶液既作氧化剂又作还原剂,将Cl2、HCl转化为Cl-,将SO2、SO3转化为SO42-。用离子色谱法测量吸收剂中Cl-和SO42-的含量进而推算甲醇、碳黑中氯和硫的含量。实验结果表明,该方法简单、准确、灵敏。氯和硫的检出限分别为9.71μg/g和1.64μg/g。A new method has been developed to determine chlorine and sulfur content in methanol and charcoal by using combustion oxidation coupled to ion chromatography.Through combustion oxidation,the chlorine and sulfur in methand or charcoal was converted to chlorine and chlorine hydride,and sulfur dioxide respectively.Using I~-/I~-_3 solution as the absorbent,they were converted to chloride and sulfate ions,respectively.These ions were then determined directly by ion chromatography.The difference between the developed method and the others is that this method use cheap and convenient porcelain boat and the tubal stove was used as a reactive device,and efficient and stable I~(-)/I~-_(3)solution as the absorbent.The method is economic,simple,accurate and sensitive.The detection limit of the method is 9.71×10~(-6) μg/g for Cl and 1.64×10~(-6) μg/g for S.福建省重大科技项目(No.2003Y010

Effect of Surface Processing on The Performance of Low-cost Multi-crystalline Silicon Solar Cells

通过沉积SInX薄膜和H2退火表面处理工艺对低成本多晶硅太阳电池进行了处理,对表面处理前后的电池效率进行了对比测试,详细地研究了这两种表面处理工艺对电池的短路电流、开路电压、填充因子和转换效率的影响。实验发现,沉积了SInX薄膜的低成本多晶硅太阳电池的效率在原有基础上提高了1.8%左右;而经过H2退火后的电池效率则出现了效率衰减。与此同时,对成本相对高的太阳能级多晶硅电池也进行了H2退火,与低成本多晶硅电池相比,其效率增加明显,与低成本太阳电池呈现了相反的现象。最后分析了两种表面处理工艺对电池性能造成影响的原因。Two surface processing methods,which includes depositing SiNxthin film on the cells and annealing the cells in H2,were carried out on low-cost multi-crystalline silicon solar cells.The efficiency of the solar cells was tested before and after the surface processing.And the effects of the two surface processing methods on the short-circuit current,open-circuit voltage, fill factor and efficiency were carried out in this paper.The results show that the efficiency of the low-cost solar cells is improved by 1.8%after depositing SiNxthin film on the cells,but after H2 annealing,the efficiency is degraded.And high-cost solar-graded multi-crystalline silicon solar cells are also annealed in H2 atmosphere,but its efficiency increases,which shows different tendency compared to low-cost multi-crystalline silicon solar cells.Finally the factors resulting in different effects by the two methods are analyzed and discussed.福建省自然科学基金项目(2012J05122); 福建省教育厅B类项目(JB11147

Detection of Glucose by Enzyme-Ion Chromatography

应用酶反应催化性能高,反应选择性好以及离子色谱法快速、灵敏、准确的特点,率先提出酶 离子色谱法检测葡萄糖的新方法.在含葡萄糖样品溶液中加入一定量的葡萄糖氧化酶(GOD),在葡萄糖氧化酶的催化下,被测葡萄糖被氧化产生H2O2,生成的H2O2与加入的NO-3用离子色谱定性和定量测定.因为被2进一步反应,生成的NO-测的葡萄糖与生成的NO-3的浓度计算出葡萄糖的含量.测定葡萄糖的线性范围3存在定量关系,从而可以由NO-在5～100mg/L,测定了市售葡萄糖和蜂蜜中葡萄糖的含量,回收率分别为94%和94.5%.It is well known that enzyme reactions usually proceed with good efficiency and good selectivity. Ion chromatography is rapid, sensitive and precise. The two excellent methods were combined to make a enzymeion chromatography to determine glucose. Glucose was oxidized with the catalysis of glucose oxidase to produce hydrogen peroxid, which could oxidize added nitrite into nitrate. Then nitrate was determinated by ion chromatography. According to the peak height change of nitrate caused by glucose, glucose could be quantitatively determined with the linear range of its concentration in 5～100 mg/L. The method was applied to analysis glucose in two food samples, with 94 and 94.5 recovery percent respectively

Effect of dissolved phosphorus on alkaline phosphatase activity in marine microalgae

在实验室批量培养条件下，测定了海洋微藻培养体系中碱性磷酸酶活力（APA）和各形态溶解磷的动态变化，分析了二者之间的关系.结果表明，在批量培养过程中，APA的动态变化呈“S“形曲线，各形态溶解磷在其变化过程中所起的调控作用不同，介质中溶解无机磷和小分子溶解有机磷的浓度是激发APA发生变化的主要调控因子，大分子溶解有机磷的浓度对APA的作用不明显，但APA的增大可加速微藻利用大分子溶解有机磷的速率.微藻的种类和丰度不影响APA的动态变化形式及其调控机理.It was thought that phosphorus licited the primary productivity in lake while nitrogen in ocean, but recent studies showed that phosphorus limited the phytoplankton growth in the specific coastal waters, results also indicated that Phytoplankton could utilize dissolved organic phosphorus (DOP) and alkaline phosphatase (AP) played an important role in the utilization of DOP.However, the variation and controlling mechanism of AP are still poorly understood.The present study focused on the effects of different species of dissolved phosphorus on the variation of AP in algal batch culture.The results showed that vacation of airline phosphatase activity (APA) was closed to "S" curve, different spotes of dissolved phosphorus had different effects on APA.The concentrations of dissolved inorganic phosphorus and small moleculal dissolved organic phosphorus had a sighficant effect on APA, while the concentration of large molecular dissolved organic phosphorus (LDOP) has little effect on APA, but the increasing of APA could accelerate the decomposing of LDOP in the medium.Results also showed that algae species and abundance had little effect on APA.国家自然科学基金!4920606