An investigation of the beneficial effects of adding carbon nanotubes to standard injection grout

Mortar grouting is often used in masonry constructions to mitigate structural decay and repair damage by filling cracks and voids, resulting in an improvement in mechanical properties. This paper presents an original experimental investigation on grout with added carbon nanotubes (CNTs). The samples were prepared with different percentages of CNTs, up to 1.2 wt% with respect to the binder, and underwent three‐point bending tests in crack mouth opening displacement mode and compressive tests. The results showed that very small additions (up to 0.12 wt% of CNTs) increased not only flexural and compressive strengths (+73% and 35%, respectively, in comparison with plain mortar) but also fracture energy (+80%). These results can be explained on the basis of a reduction in porosity, as evidenced by mercury intrusion porosimetry, as well as by a crack bridging mechanism and by the probable formation of nucleation sites for hydration products, as observed through scanning electron microscopy

Nanostructured Metal Oxide Semiconductors towards Greenhouse Gas Detection

Climate change and global warming are two huge current threats due to continuous anthropogenic emissions of greenhouse gases (GHGs) in the Earth’s atmosphere. Accurate measurements and reliable quantifications of GHG emissions in air are thus of primary importance to the study of climate change and for taking mitigation actions. Therefore, the detection of GHGs should be the first step when trying to reduce their concentration in the environment. Throughout recent decades, nanostructured metal oxide semiconductors have been found to be reliable and accurate for the detection of many different toxic gases in air. Thus, the aim of this article is to present a comprehensive review of the development of various metal oxide semiconductors, as well as to discuss their strong and weak points for GHG detection

Damage Management of Concrete Structures with Engineered Cementitious Materials and Natural Fibers: A Review of Potential Uses

The importance of the safety and sustainability of structures has attracted more attention to the development of smart materials. The presence of small cracks (<300 µm in width) in concrete is approximately inevitable. These cracks surely damage the functionality of structures, increase their degradation, and decrease their sustainability and service life. Self-sensing cement-based materials have been widely assessed in recent decades. Engineers can apply piezoresistivity for structural health monitoring that provides timely monitoring of structures, such as damage detection and reliability analysis, which consequently guarantees the service life with low maintenance costs. However, concrete piezoresistivity is limited to compressive stress sensing due to the brittleness of concrete. In contrast, engineered cementitious composites (ECC) present excellent tensile ductility and deformation capabilities, making them able to sense tensile stress/strain. Therefore, in this paper, first, the ability of ECC to partly replace transverse reinforcements and enhance the joint shear resistance, the energy absorption capacity, and the cracking response of concrete structures in seismic areas is reviewed. Then, the potential use of natural fibers and cellulose nanofibers in cementitious materials is investigated. Moreover, steel and carbon fibers and carbon black, carbon nanotubes, and graphene, all added as conductive fillers, are also presented. Finally, among the conductive carbonaceous materials, biochar, the solid residue of biomass waste pyrolysis, was recently investigated to improve the mechanical properties, internal curing, and CO2 capture of concrete and for the preparation of self-sensing ECC

Experimental investigation on the ability of macro-encapsulated polyurethane to resist cyclic damaging actions in self-repaired cement-based elements

The use of polymer precursors as repairing agents in capsule-based self-healing systems has been extensively studied in recent years. In particular, the effectiveness of macro-encapsulated polyurethane in restoring both watertightness and mechanical properties has been demonstrated at the laboratory level, and the experimental methods to test the effectiveness have been validated following pre-standard procedures. However, the use of macro-capsules containing polyurethane precursors for field applications has not been sufficiently implemented yet. For these systems to become appealing to the construction industry, it is essential to further characterize the self-healing effect in terms of stability in time, namely, to investigate the behavior of the self-healing system when subjected to recurring actions that can affect structures in time, after cracking and subsequent self-repairing. The goal of this study was to characterize the ability of commercial polyurethane foams to withstand cyclic flexural actions and repeated temperature variations after release from cementitious macro-capsules embedded in mortar specimens. The specimens were tested immediately after pre-cracking and self-repairing to characterize the initial sealing efficiency through a water-flow test. The same test was repeated at prescribed time intervals to analyze the evolution of the sealing efficiency with the applied mechanical and thermal stresses. The results showed that the proposed system has good stability against the selected damaging actions and confirmed the potential of encapsulated polyurethane for self-healing applications

Carbon-based materials for humidity sensing: a short review

Humidity sensors are widespread in many industrial applications, ranging from environmental and meteorological monitoring, soil water content determination in agriculture, air conditioning systems, food quality monitoring, and medical equipment to many other fields. Thus, an accurate and reliable measurement of water content in dierent environments and materials is of paramount importance. Due to their rich surface chemistry and structure designability, carbon materials have become interesting in humidity sensing. In addition, they can be easily miniaturized and applied in flexible electronics. Therefore, this short review aims at providing a survey of recent research dealing with carbonaceous materials used as capacitive and resistive humidity sensors. This work collects some successful examples of devices based on carbon nanotubes, graphene, carbon black, carbon fibers, carbon soot, and more recently, biochar produced from agricultural wastes. The pros and cons of the dierent sensors are also discussed in the present review

Sustainable Public Procurement in the Building Construction Sector

Considering that in the E.U. public procurement in the construction sector is highly represented, the Directive 2014/24/EU is implemented for harmonizing procurement processes across European countries. The Directive is transposed in Italy, through the Sustainable Public Procurement (SPP) national action plan, for supporting public procurement and public–private partnership (PPP) interventions. SPP is founded on two pillars: according to an economic viewpoint, the financial efficiency is the key aspect to verify, and, according to a sustainability viewpoint, externalities are a key element in the environmental evaluation, despite the fact that their monetary quantification into the global cost calculation is quite complex. Thus, this work aims to explore a methodology for the joint evaluation of economic–environmental sustainability of project options, in the tender evaluation phase of the SPP. The methodology is based on the life cycle costing (LCC) and CO2 emissions joint assessment, including criteria weighting and uncertainty components. Two alternative technologies—a timber and an aluminum window frame—are assumed as a case for a simulation, implemented with the software “Smart SPP LCC-CO2 Tool” (developed through the research “Smart SPP—Innovation through sustainable procurement”, supported by Intelligent Energy Europe). The simulation demonstrates that the methodology is a fast and effective modality for selecting alternative options, introducing sustainability in the decision-making process. The work is a contribution to the growing literature on the topic, and for giving support to subjects (public authorities and private operators) involved in public procurement processes/PPP interventions

New Concepts for Next Generation of High Performance Concretes

AbstractWith the development of high-speed railway, long span bridges and high-rise buildings, new concretes need to increase strength and toughness. Adding fibers to concrete matrix has been long recognized as a way to enhance the energy absorption capacity and crack resistance of the plain concrete. In recent years, particular attention has been paid to the distribution of fibers: very small and well dispersed fibers may control the microcracks in the matrix from the very beginning of their opening and particularly high deformability of the composite may be obtained [3–5]. Carbon nanotubes (CNTs) used as reinforcing fibers has been also explored [6–8], the functional effect of their addition in a concrete equals to the one obtained with the addition of fibers. CNTs also provide a better ductility and an increase of the fracture energy. However, agglomeration and the relative high price seem to limit their application in cement based composite materials [14]. In this work, the potential beneficial effects of carbon micro/nanoparticles addition to cement pastes for improving the mechanical properties of the resulting composites has been investigated [15]. Pyrolyzed polyethylene beads (CNBs) and coconuts shells (Cocos nucifera, CCNs) were produced at Politecnico di Torino and characterized by Raman spectroscopy, thermogravimetry and scanning electron microscopy (SEM). When added to cement paste, up to 0.08 wt%, both materials were effective in increasing the cement matrix compressive strength and toughness. From SEM observations it is evident that the presence of these small particles disturb the propagation of microcracks, which has to deviate from its trajectory and has to follow the carbon nano/micro-particles contour. This mechanism increases strongly the fracture surface during the test performed by imposing the monotonic increment of crack opening. Crack and crack pinning are the mechanisms which can explain the increase of toughness in the composite samples

Sol–Gel Synthesis of Iron-Doped Sepiolite as a Novel Humidity-Sensing Material

Nowadays, humidity sensors are attracting a great deal of attention, and there are many studies focusing on enhancing their performances. Nevertheless, their fabrication through facile methods at reasonable cost is a significant factor. In this article, a new magnesium silicate nanopowder was successfully synthesized using a simple and low-cost sol–gel method. Subsequently, modified sepiolite was achieved by the substitution of iron ions in the synthesized nanopowders. The specimens were then characterized by X-ray diffraction, field emission–scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric–differential thermal analysis, infrared spectroscopy, and nitrogen adsorption. Furthermore, humidity sensors were manufactured by screen printing the prepared powders on alumina substrates with interdigitated Pt electrodes. The results showed that the fabricated sensors with modified sepiolite exhibited interesting characteristics for humidity detection