The influence of droplet size on line tension

Within the effective interfacial Hamiltonian approach we evaluate the excess line free energy associated with cylinder-shaped droplets sessile on a stripe-like chemical inhomogeneity of a planar substrate. In the case of short-range intermolecular forces the droplet morphology and the corresponding expression for the line tension - which includes the inhomogeneity finite width effects - are derived and discussed as functions of temperature and increasing width. The width-dependent contributions to the line tension change their structure at the stripe wetting temperature T_W1: for T<T_W1 they decay exponentially while for T>T_W1 the decay is algebraic. In addition, a geometric construction of the corresponding contact angle is carried out and its implications are discussed

Bogoliubov correction to the mean-field dynamics of interacting bosons

We consider the dynamics of a large quantum system of $N$ identical bosons in 3D interacting via a two-body potential of the form $N^{3\beta-1} w(N^\beta(x-y))$. For fixed $0\leq \beta <1/3$ and large $N$, we obtain a norm approximation to the many-body evolution in the $N$-particle Hilbert space. The leading order behaviour of the dynamics is determined by Hartree theory while the second order is given by Bogoliubov theory.Comment: Final version, to appear in ATM

Lateral critical Casimir force in 2D Ising strip with inhomogeneous walls

We analyze the lateral critical Casimir force acting between two planar, chemically inhomogeneous walls confining an infinite 2D Ising strip of width $M$. The inhomogeneity of each of the walls has size $N_1$; they are shifted by the distance $L$ along the strip. Using the exact diagonalization of the transfer matrix, we calculate the lateral critical Casimir force and discuss its properties, in particular its scaling close to the 2D bulk critical point, as a function of temperature, surface magnetic field, and the geometric parameters $M$, $N_1$, $L$. We determine the magnetization profiles which display the formation of the bridge joining the inhomogeneities on the walls and establish the relation between the characteristic properties of the lateral Casimir force and magnetization morphologies. We check numerically that breaking of the bridge is related to the inflection point of the lateral force.Comment: 5 pages, 6 figure

Lateral critical Casimir force in two-dimensional inhomogeneous Ising strip. Exact results

We consider two-dimensional Ising strip bounded by two planar, inhomogeneous walls. The inhomogeneity of each wall is modeled by a magnetic field acting on surface spins. It is equal to $+h_1$ except for a group of $N_1$ sites where it is equal to $-h_1$. The inhomogeneities of the upper and lower wall are shifted with respect to each other by a lateral distance $L$. Using exact diagonalization of the transfer matrix, we study both the lateral and normal critical Casimir forces as well as magnetization profiles for a wide range of temperatures and system parameters. The lateral critical Casimir force tends to reduce the shift between the inhomogeneities, and the excess normal force is attractive. Upon increasing the shift $L$ we observe, depending on the temperature, three different scenarios of breaking of the capillary bridge of negative magnetization connecting the inhomogeneities of the walls across the strip. As long as there exists a capillary bridge in the system, the magnitude of the excess total critical Casimir force is almost constant, with its direction depending on $L$. By investigating the bridge morphologies we have found a relation between the point at which the bridge breaks and the inflection point of the force. We provide a simple argument that some of the properties reported here should also hold for a whole range of different models of the strip with the same type of inhomogeneity

Formation of capillary bridges in AFM-like geometry

We discuss the phase diagram of fluid confined in AFM-like geometry. It combines the properties of capillary condensation and complete filling of a wedge.Comment: 9 pages, 7 figure

Calculation of the critical temperature of a dilute Bose gas in the Bogoliubov approximation

Following an earlier calculation in 3D, we calculate the 2D critical temperature of a dilute, translation-invariant Bose gas using a variational formulation of the Bogoliubov approximation introduced by Critchley and Solomon in 1976. This provides the first analytical calculation of the Kosterlitz-Thouless transition temperature that includes the constant in the logarithm.Comment: Published version, 7 pages, 2 figure

Diagonalization of bosonic quadratic Hamiltonians by Bogoliubov transformations

We provide general conditions for which bosonic quadratic Hamiltonians on Fock spaces can be diagonalized by Bogoliubov transformations. Our results cover the case when quantum systems have infinite degrees of freedom and the associated one-body kinetic and paring operators are unbounded. Our sufficient conditions are optimal in the sense that they become necessary when the relevant one-body operators commute.Comment: Revised version to appear in Journal of Functional Analysi