360 research outputs found

    Evolutionary gaming approach for decision making of Tier-3 Internet service provider networks migration to SoDIP6 networks

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    This is the peer reviewed version of the following article: Dawadi, BR, Rawat, DB, Joshi, SR, Manzoni, P. Evolutionary gaming approach for decision making of Tier-3 Internet service provider networks migration to SoDIP6 networks. Int J Commun Syst. 2020; 33:e4399, which has been published in final form at https://doi.org/10.1002/dac.4399. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.[EN] With the increasing number of Internet of Things (IoT) devices, current networking world is suffering in terms of management and operations with lack of IPv4 addresses leading to issues like network address translation (NAT) proliferation, security and quality of services. Software-defined networking (SDN) and Internet Protocol version 6 (IPv6) are the new networking paradigms evolved to address related issues of legacy IPv4 networking. To adapt with global competitive environment and avoid all existing issues in legacy networking system, network service providers have to migrate their networks into IPv6 and SDN-enabled networks. But immediate transformations of existing network are not viable due to several factors like higher cost of migration, lack of technical human resources, lack of standards and protocols during transitions, and many more. In this paper, we present the migration analysis for proper decision making of network transition in terms of customer demand, traffic engineering, and organizational strength with operation expenditure for network migration using evolutionary gaming approach. Joint migration to SDN-enabled IPv6 network from game theoretic perspective is modeled and is validated using numerical results obtained from simulations. Our empirical analysis shows the evolutionary process of network migration while different internal and external factors in the organization affect the overall migration. Evolutionary game in migration planning is supportive in decision making for service providers to develop suitable strategy for their network migration. The proposed approach for migration decision making is mostly applicable to fairly sustained service providers who lack economics, regulation/policy, and resources strengths.ERASMUS+, Grant/Award Number: KA107; UGC-NP, Grant/Award Number: FRG-074/75-Engg-01; NTNU-EnPE-MSESSD; US National Science Foundation, Grant/Award Numbers: CNS 1650831, HRD 1828811; NASTDawadi, BR.; Rawat, DB.; Joshi, SR.; Manzoni, P. (2020). Evolutionary gaming approach for decision making of Tier-3 Internet service provider networks migration to SoDIP6 networks. 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    DESIGN AND SYNTHESIS OF CHELATING COMPOUNDS AND SOLID-SUPPORTED CHELATORS FOR METAL DEPLETED SOLUTIONS

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    Metals are essential to life, yet they can be toxic for biological systems when present in excessive amounts. The major source of metal overload in humans is diet; and in some cases, intravenous feeding. Thus the removal of toxic metal ions from contaminated clinical products such as total parenteral nutrition (TPN) solutions, and drinking and waste water is extremely important. The use of chelating resins, which are polymeric solids containing covalently immobilized chelating compounds, for the selective removal of metal ions from contaminated solutions has been conceptualized long ago. Herein, the design and synthesis of metal specific chelating compounds and chelating resins will be presented, along with the application of these materials to remove toxic metals from aqueous solutions. Solution phase hydroxamate based chelating compounds have been synthesized for the selective binding of trivalent metals such as iron and aluminum in the presence of divalent metals such as calcium. Iron complexation behavior of these solution phase chelating compounds has been studied by UV-Vis Spectrophotometric methods. These hydroxamate chelators have potential applications as chelating agents in the treatment of iron and aluminum overload. A set of the strongly binding chelators have been immobilized on solid support via various linkages. These solid supported chelators have been employed to selectively remove aluminum from contaminated TPN components such as a solution of calcium gluconate. Our resins are able to remove more than 90% of aluminum from commercial calcium gluconate solutions. This technology of employing hydroxamate functionalized resins for the removal of aluminum from calcium gluconate solution will be available in hospitals soon and will greatly benefit premature neonates who receive TPN solutions for life support. Additionally, citramide functionalized chelating resins have been prepared for the removal of trivalent metals from contaminated solutions at low pH, and dithiolate based chelating resins were prepared for the removal of high priority environmental metal toxins such as lead, cadmium, mercury, and arsenic. Overall, this dissertation embodies the design, synthesis, and metal binding studies of novel chelators and chelating resins and the applications of these resins for the selective removal of metal ions from contaminated solutions
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