2,789 research outputs found

    Self-Diffusion and Collective Diffusion of Charged colloids Studied by Dynamic Light Scattering

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    A microemulsion of decane droplets stabilized by a non-ionic surfactant film is progressively charged by substitution of a non-ionic surfactant molecule by a cationic surfactant. We check that the microemulsion droplets remain identical within the explored range of volume fraction (0.02 to 0.18) and of the number of charge per droplets (0 to 40) . We probe the dynamics of these microemulsions by dynamic light scattering. Despite the similar structure of the uncharged and charged microemulsions the dynamics are very different . In the neutral microemulsion the fluctuations of polarization relax, as is well known, via the collective diffusion of the droplets. In the charged microemulsions, two modes of relaxation are observed. The fast one is ascribed classically to the collective diffusion of the charged droplets coupled to the diffusion of the counterions. The slow one has, to our knowledge, not been observed previously neither in similar microemulsions nor in charged spherical colloids. We show that the slow mode is also diffusive and suggest that its possible origine is the relaxation of local charge fluctuations via local exchange of droplets bearing different number of charges . The diffusion coefficient associated with this mode is then the self diffusion coefficient of the droplets

    Analysis by the Two-Fluids Model of the Dynamical Behavior of a Viscoelastic Fluid Probed by Dynamic Light Scattering

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    The dynamic properties of a model transient network have been studied by dynamic light scattering. The network is formed by microemulsion droplets linked by telechelic polymers (modified hydrophilic polymers with two grafted hydrophobic stickers). We compare the properties of two networks that are similar but for the residence time of the hydrophobic stickers in the droplets. The results are interpreted according to the so-called two-fluids model, which was initially developed for semidilute polymer solutions and which we extend here to any Maxwellian viscoelastic medium characterized by its elastic modulus and terminal time as measured by rheology. This model is found to describe consistently and quantitatively the experimental observations.Comment: novembre 200

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    Waking Up

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    Shell

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    Swollen Micelles Plus Hydrophobically Modified Hydrosoluble Polymers in Aqueous Solutions: Decoration Versus Bridging. a Small Angle Neutron Scattering Study

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    In this paper we examine the effective interactions introduced between the droplets of an oil in water microemulsion upon progressive addition of hydrophobically modified water soluble poly(ethylene oxide)-PEO using essentially small angle neutron scattering. To discuss the relative importance of decoration and bridging of the droplets we compare analogous samples with addition of a PEO grafted at both extremities with hydrophobic C12H 25 chains (PEO-2m) or addition of a PEO grafted at one extremity only with a C12H 25 chain (PEO-m). PEO-m or PEO-2m adsorb onto the droplets via their hydrophobic extremities and the droplets are found to retain their form and size upon addition of up to 40 hydrophobic C12H 25 chains per droplet. When the volume fraction of droplets is less than about 10%, the effective interactions introduced by PEO-m or PEO-2m are found to be very different: PEO-m introduces a repulsive interaction while PEO-2m introduces an effective attractive interaction. This attractive interaction leads to an associative phase separation in the range of low volume fraction when a sufficient amount of PEO-2m is added

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