Understanding of Relation Structures of Graphical Models by Lower Secondary Students

A learning path has been developed on system dynamical graphical modelling, integrated into the Dutch lower secondary physics curriculum. As part of the developmental research for this learning path, students’ understanding of the relation structures shown in the diagrams of graphical system dynamics based models has been investigated. One of our main findings is that only some students understand these structures correctly. Reality-based interpretation of the diagrams can conceal an incorrect understanding of diagram structures. As a result, students seemingly have no problems interpreting the diagrams until they are asked to construct a graphical model. Misconceptions have been identified that are the consequence of the fact that the equations are not clearly communicated by the diagrams or because the icons used in the diagrams mislead novice modellers. Suggestions are made for improvements

Interfacial Electronic Charge Transfer and Density of States in Short Period Cu/Cr Multilayers

Nanometer period metallic multilayers are ideal structures to investigate electronic phenomena at interfaces between metal films since interfacial atoms comprise a large atomic fraction of the samples. The Cu/Cr binary pair is especially suited to study the interfaces in metals since these elements are mutually insoluble, thus eliminating mixing effects and compound formation and the lattice mismatch is very small. This allows the fabrication of high structural quality Cu/Cr multilayers that have a structure which can be approximated in calculations based on idealized atomic arrangements. The electronic structure of the Cu and the Cr layers in several samples of thin Cu/Cr multilayers were studied using x-ray absorption spectroscopy (XAS). Total electron yield was measured and used to study the white lines at the Cu L{sub 2} and L{sub 3} absorption edges. The white lines at the Cu absorption edges are strongly related to the unoccupied d-orbitals and are used to calculate the amount of charge transfer between the Cr and Cu atoms in interfaces. Analysis of the Cu white lines show a charge transfer of 0.026 electrons/interfacial Cu atom to the interfacial Cr atoms. In the Cu XAS spectra we also observe a van Hove singularity between the L{sub 2} and L{sub 3} absorption edges as expected from the structural analysis. The absorption spectra are compared to partial density of states obtained from a full-potential linear muffin-tin orbital calculation. The calculations support the presence of charge transfer and indicate that it is localized to the first two interfacial layers in both Cu and Cr

Final Report: Biological and Synthetic Nanostructures Controlled at the Atomistic Level

Nanotechnology holds great promise for many application fields, ranging from the semiconductor industry to medical research and national security. Novel, nanostructured materials are the fundamental building blocks upon which all these future nanotechnologies will be based. In this Strategic Initiative (SI) we conducted a combined theoretical and experimental investigation of the modeling, synthesis, characterization, and design techniques which are required to fabricate semiconducting and metallic nanostructures with enhanced properties. We focused on developing capabilities that have broad applicability to a wide range of materials and can be applied both to nanomaterials that are currently being developed for nanotechnology applications and also to new, yet to be discovered, nanomaterials. During this 3 year SI project we have made excellent scientific progress in each of the components of this project. We have developed first-principles techniques for modeling the structural, electronic, optical, and transport properties of materials at the nanoscale. For the first time, we have simulated nanomaterials both in vacuum and in aqueous solution. These simulation capabilities harness the worldleading computational resources available at LLNL to model, at the quantum mechanical level, systems containing hundreds of atoms and thousands of electrons. Significant advances in the density functional and quantum Monte Carlo techniques employed in this project were developed to enable these techniques to scale up to simulating realistic size nanostructured materials. We have developed the first successful techniques for chemically synthesizing crystalline silicon and germanium nanoparticles and nanowires. We grew the first macroscopic, faceted superlattice crystals from these nanoparticles. We have also advanced our capabilities to synthesize semiconductor nanoparticles using physical vapor deposition techniques so that we are now able to control of the size, shape and surface structure of these nanoparticles. We have made advances in characterizing the surface of nanoparticles using x-ray absorption experiments. Throughout this SI a number of long-term, strategic external collaborations have been established. These collaborations have resulted in 30 joint publications, strategic hires of postdocs and graduate students from these groups into groups at LLNL and the submission of joint research grants. We have developed collaborations on the theory and modeling of nanomaterials with the groups of Profs. Ceder and Marzari (MIT), Crespi (Penn State), Freeman (Northwestern), Grossman and Lester (UC Berkeley), Mitas (North Carolina State), and Needs (Cambridge). We are collaborating with Dr. Alivisatos's group in the Molecular Foundry at Lawrence Berkeley Laboratory on the fabrication, characterization and modeling of inorganic nanomaterials. We are working with Prof. Majumdar's group at UC Berkeley on the characterization of nanomaterials. We are working with the molecular diamond group at Chevron-Texaco who has developed a process for extracting mono-disperse samples of nano-scale diamonds from crude oil. We are collaborating with Dr. Chen at UCSF to develop CdSe nanoparticle-biolabels. As a result of the outstanding scientific achievements and the long-term collaborations developed during this strategic initiative we have been extremely successful in obtaining external funding to continue and grow this research activity at the LLNL. We have received two DARPA grants to support the further development of our computational modeling techniques and to develop carbon nanotube based molecular separation devices. We have received two new Office of Science BES grants to support our nanomaterials modeling and synthesis projects. We have received funding from the NA22 office of DOE to develop the materials modeling capabilities begun in this SI for modeling detector materials. We have received funding from Intel Corporation to apply the modeling techniques developed in this initiative to examine silicon nanowires fabricated on computer chips. We are also pursuing several additional sources of funding from BES, the DHS, and NIH to support the continuation of the research programs developed in this SI. The remainder of this report and the attached publications describe the background to this SI research project and the details of the scientific achievements that have been made

HeMIS: Hetero-Modal Image Segmentation

We introduce a deep learning image segmentation framework that is extremely robust to missing imaging modalities. Instead of attempting to impute or synthesize missing data, the proposed approach learns, for each modality, an embedding of the input image into a single latent vector space for which arithmetic operations (such as taking the mean) are well defined. Points in that space, which are averaged over modalities available at inference time, can then be further processed to yield the desired segmentation. As such, any combinatorial subset of available modalities can be provided as input, without having to learn a combinatorial number of imputation models. Evaluated on two neurological MRI datasets (brain tumors and MS lesions), the approach yields state-of-the-art segmentation results when provided with all modalities; moreover, its performance degrades remarkably gracefully when modalities are removed, significantly more so than alternative mean-filling or other synthesis approaches.Comment: Accepted as an oral presentation at MICCAI 201

Access to aidable residual hearing in adult candidates for cochlear implantation in the UK

Guidance from the National Institute for Health and Care Excellence (NICE) permits candidates to receive a cochlear implant provided they only hear sounds louder than 90 dB HL at 2 and 4 kHz. In some patients, their level of residual hearing may be sufficient to warrant the use of a hearing aid in their non-implanted ear. A survey of unilaterally-implanted adults indicated that those implanted since the publication of NICE guidance were almost seven times more likely to use a hearing aid than those implanted prior to this. If contralateral hearing aid use provides additional benefits over implant use alone, it may be appropriate to consider the capacity to use residual hearing following implantation when determining candidacy

Fluvial or aeolian? Unravelling the origin of the silty clayey sediment cover of terraces in the Hanzhong Basin (Qinling Mountains, central China)

This study is focused on a silty clayey sedimentary sequence on a terrace in the intramontane Hanzhong Basin, located in the Qinling Mountains (QLM), central China. Traditionally, the QLM are considered to have blocked dust transport from northwest to southeast China. However, in recent years, geo-archaeological studies have documented loess-palaeosol sequences at numerous locations in and surrounding the QLM. In the loess deposits overlying the terraces of the Hanjiang River in the Hanzhong-, Ankang- and Yunxian basins, abundant artefacts, flakes, stone tools (e.g., scrapers and choppers) and cores are commonly found. The loess deposits have been deposited with lower sedimentation rates, and they are finer grained and more intensely weathered compared to the loess deposits on the Central Loess Plateau (CLP). The loess deposits overly coarse sandy and gravely fluvial deposits (terraces). Silty fluvial deposits are situated in between them. Discrimination between these two types of deposits could prove difficult because both deposits are fine grained (silt and clay) and can have similar grain size distribution characteristics. This is, however, crucial for palaeo-environmental interpretations during hominin occupation, understanding fluvial morphodynamics, and for pedostratigraphic correlation with the typical loess-palaeosol sequences on the CLP. The aim of this research is to determine and characterize the transition of the fluvial to aeolian depositional environment in a fine grained sequence, based on field observations, organic matter and carbonate content, grain size and shape analyses, mineral content (mica's) and end-member modelling of the grain size dataset. In addition, terrestrial cosmogenic nuclides (TCN) burial dating is used to determine the age of the basal, coarse grained fluvial deposits. The determined age, 0.6 ± 0.14 Ma, allows for a chronological correlation of the deposits to the loess-palaeosol sequence on the CLP independent from the pedostratigraphic correlation. This age also gives insight in terrace abandonment and the fluvial morphodynamics of the Hanjiang River. The result indicates a clear distinction between sediments deposited in a fluvial environment and those formed in an aeolian depositional environment. However, the aeolian (loess) deposits show some atypical characteristics. For example, the end-member model results show a coarsening in the five palaeosol layers. This is in contrast with the fine grained nature of palaeosols on the CLP. The coarsening observed in the studied palaeosol layers is interpreted as the result of local surface runoff processes, eroding fine sediment and/or depositing relatively coarse material during interglacial periods. Because of the known depth of the fluvial-aeolian transition and the absolute age of the TCN burial dated terrace deposits, pedostratigraphic correlation of the palaeosol layers with the Central Loess Plateau is possible. The oldest palaeosol is correlated with S5 (0.625–0.503 Ma). The transition from a fluvial to aeolian environment takes place in L6, between 0.625 and 0.693 Ma. This is consistent with the TCN age of 0.6 ± 0.14 Ma. This age also marks the abandonment of the terrace caused by incision of the Hanjiang River, which is possibly related to an uplift phase of the QLM

Effects of carbon on ion-implantation-induced disorder in GaN

Wurtzite GaN films bombarded with 40keV C ions to high doses (5×10¹⁷ and 1×10¹⁸cm⁻²) are studied by a combination of Rutherford backscattering/channeling spectrometry, transmission electron microscopy, and soft x-ray absorption spectroscopy. Results show that, contrary to other ion species, implanted C forms nitrilelike carbon-nitride bonds (—C≡N) and suppresses ion-beam-induced material decomposition involving the formation and agglomeration of ≳5-nm-large N₂ gas bubbles.Work at the ANU was supported by the ARC. The ALS is supported by the Director, Office of Science, Office of BES, Materials Sciences Division, of the U.S. DOE under Contract No. DE-AC03-76SF00098 at LBNL

Fluvial terrace formation and its impacts on early human settlement in the Hanzhong basin, Qinling Mountains, central China

The Qinling Mountains (QLM) form the climatic boundary between the temperate north and subtropical south of China. Many important Paleolithic archaeological sites located on fluvial terraces in this area have been reported in recent decades. Abundant artifacts have been excavated in silt layers overlying fluvial gravels and coarse sands. These silt layers have thus far been interpreted as aeolian deposits. However, in principle they could also represent (in part) fluvial (floodplain) deposits, especially near the base of fine-grained sequences. Reconstruction of fluvial terrace formation is crucial for the correct interpretation of the environment of hominin occupation. In this paper, two sediment sequences from two Paleolithic sites, located on different terrace levels of the Hanjiang River in the Hanzhong basin, are studied mainly using grain-size and grain-shape analyses. In addition, grain-size distributions have been unraveled by applying end-member modelling to distinguish different sedimentary environments. The results show that three different units can be discriminated in each section. The lower unit, consisting of gravelly sand mixed with fine silt, is interpreted as shallow-channel-fill sediment deposited during the start of the transition from a channel to a floodplain environment. The middle unit comprises a fine-grained, gradually fining-upward sequence, representative a floodplain environment. At its base, it reflects a high-energy floodplain situation; at its top, the sequence is interpreted as a low-energy floodplain environment with aeolian input (settling in static water). The third, uppermost unit consists of aeolian loess interbedded with paleosol(s) and sediments that are interpreted as the results of episodic surface runoff. The gradual transition between the 3 units and the gradual fining upward trend of the middle unit indicates that there is no considerable age gap (no hiatus) between the fluvial- and aeolian sedimentary environments. Stone artifacts have been found in all 3 units, with difference abundance, indicating that both the aeolian and floodplain depositional environments provided favorable living conditions. For the floodplain environment, the resources of water and raw materials (fluvial gravels) for tool making may have offered fundamental resources for hominin settlement