Study of Methanol to Formaldehyde Reaction in Fluidized Bed Reactor

Formaldehyde, as a valuable compound, has been widely used in chemical processes and is usually produced through the catalytic oxidization of methanol in a fixed bed reactor. In the present work, this reaction has been studied in a fluidized bed reactor. For this purpose, a stainless steel fluidized bed reactor , which has the capability of controlling the temperature and flow rate of the streams, has been employed. The effects of different operating variables on the performance of the above-mentioned reactor are studied. The results are compared with the two and three phase models

The Experimental Study on Effects of Height and Hold up on performance of Vertical Gas-Liquid Separator using Amin Contactor Tower

In present research, first the treatment of flow in designed vertical gas-liquid separator and Amin contactor tower at refinery in order to reduce of liquid percent was simulated. In order to simulation was used three dimension model with finite volume method numerically. Then separator and contactor tower has been modeled three dimensional and for droplet tracking in continuous phase has been used discrete phase model (DPM) with turbulence RNG k-Ɛ model. Also the gambit software is used for three dimension designs and fluent is used for solution governing equations of flow field. After simulation, the governing model of separator and contactor tower, fluid flow, the effect of growing of liquid droplet, droplet settling length (disengagement time) was studied. After analysis and compare behavior of flow in separator and tower, the results of simulation compared with experimental results at sweetening unit in Sarkhoun and Qeshm gas treating company that has 95% compatibility. The simulation results has shown that TOTAL method has more compatibility with relation to other methods so that one of effective parameters in improvement of separation process is growing of liquid droplets and separation factor depend on that, also more disengagement time causes increase hold up time and finally growing of liquid droplets. Additionally according to younger's comment gas-liquid separators can applied in horizontal or vertical status so that he founded if L/D be 1.7 to 3.6, the separators should be used vertically also Branan has proved that if L/D > 5, a horizontal separator should be used. The results of research are shown that in special conditions with L/D>6.5 can apply vertical separator. Finally experimental data has shown that the settling length can be 36 ft (11m) that separation works well and according to Schiman this length should be 0.75D or a minimum 12in (0.305 m) whereas Gerunda recommends a length equal to the diameter or a minimum of 3 ft (0.914 m) that present result is new recommendation

Nanohydroxyapatite Silicate-Based Cement Improves the Primary Stability of Dental Implants: An In Vitro Study

Objectives. Insufficient cortical bone volume when placing implants can lead to lack of primary stability. The use of cement as a bone fill material in bone defects around dental implant could result in better clinical outcome. HA has shown excellent biological properties in implant dentistry. The purpose of this study was to evaluate the effect of nanohydroxyapatite powder (Nano-HA) in combination with accelerated Portland cement (APC) on implant primary stability in surgically created circumferential bone defects in a bovine rib in vitro model. Materials and Methods. Sixteen bovine rib bones and thirty-six implants of same type and size (4 mm × 10 mm) were used. Implants were divided into six groups: no circumferential bone defect, defect and no grafting, bone chips grafting, Nano-HA grafting, APC grafting, and Nano-HA mixed to APC grafting (Nano-HA-APC). Circumferential defects around the implants were prepared. The implant stability quotient (ISQ) values were measured before and after the grafting. Results. APC exhibited the highest ISQ values. A significant increase of ISQ values following the grafting of Nano-HA-APC (18.08±5.82) and APC alone (9.50±4.12) was achieved. Increase of ISQ values after 72 hours was 24.16±5.01 and 17.58±4.89, respectively. Nano-HA grafting alone exhibited the least rise in ISQ values. Conclusions. Nanohydroxyapatite silicate-based cement could improve the primary stability of dental implants in circumferential bone defect around implants