12 research outputs found
Temperature responsive 4D liquid crystal microactuators fabricated by direct laser writing by two-photon polymerization
Over the past decade, progress in direct laser writing by two-photon polymerization (DLW-TPP) of stimuli-responsive materials has made considerable inroads into the realization of microactuators. With the focus on performing complex tasks such as walking, grasping, or delivering drugs, these actuators require a controlled preprogrammed actuation. Liquid crystalline microactuators enable such programmed movement when the mesogenic alignment can be successfully controlled. To date, this has necessitated low crosslink density networks, which are not readily conducive to the fabrication of 3D geometries. Herein, a liquid crystalline photoresist is reported, which results in a highly crosslinked network, that permits fabrication of 4D microactuators having a highly crosslinked network in which the molecular alignment is determined by the alignment layers in the cell construct. In addition to controllable deformation of the microactuators, they also display a characteristic and unique polarization color that can be used for both identification and reporting in real time, enabling their integration into sensing and anti-anticounterfeiting microdevices
Responsive Photonic Liquid Crystalline Flakes Produced by Ultrasonication
Responsive materials that alter their color in response to environmental changes can be used as optical sensors. Chiral nematic liquid crystals are photonic materials that selectively reflect specific wavelengths of light and have been made environmentally responsive. In this work, we demonstrate the use of ultrasonication of responsive cholesteric liquid crystal network films to form structurally colored flakes that demonstrate color changes when moved from an aqueous to dry environment and back again, suggesting a scalable technique to form quantities of responsive particles that could conceivably be embedded in permeable hosts to allow the optical detection of humidity or certain chemical species
4D Printing of Liquid Crystals: What’s Right for Me?
Recent years have seen major advances in the developments of both additive manufacturing concepts and responsive materials. When combined as 4D printing, the process can lead to functional materials and devices for use in health, energy generation, sensing, and soft robots. Among responsive materials, liquid crystals, which can deliver programmed, reversible, rapid responses in both air and underwater, are a prime contender for additive manufacturing, given their ease of use and adaptability to many different applications. In this paper, selected works are compared and analyzed to come to a didactical overview of the liquid crystal-additive manufacturing junction. Reading from front to back gives the reader a comprehensive understanding of the options and challenges in the field, while researchers already experienced in either liquid crystals or additive manufacturing are encouraged to scan through the text to see how they can incorporate additive manufacturing or liquid crystals into their own work. The educational text is closed with proposals for future research in this crossover field
Direct Ink Writing of a Light‐Responsive Underwater Liquid Crystal Actuator with Atypical Temperature‐Dependent Shape Changes
In recent years, light‐responsive liquid crystal (LC) polymers have been studied as promising materials for the fabrication of untethered soft actuators. The underwater behavior of these advanced materials has, however, been rarely investigated. This paper reports on the fabrication of light‐responsive amphibious LC‐actuators via direct ink writing (DIW). The actuators present two underwater deformation modes triggered by different stimuli. Temperature induces contraction/expansion and light induces bending/unbending. Unexpectedly, temperature can regulate the bending directionality, giving the material additional versatility to its deformation modes. These findings serve as a toolbox for the fabrication of light‐responsive actuators via DIW that operate in air and underwater
Direct Laser Writing of Four-Dimensional Structural Color Microactuators Using a Photonic Photoresist
With the advent of direct laser writing using two-photon polymerization, the generation of high-resolution three-dimensional microstructures has increased dramatically. However, the development of stimuli-responsive photoresists to create four-dimensional (4D) microstructures remains a challenge. Herein, we present a supramolecular cholesteric liquid crystalline photonic photoresist for the fabrication of 4D photonic microactuators, such as pillars, flowers, and butterflies, with submicron resolution. These micron-sized features display structural color and shape changes triggered by a variation of humidity or temperature. These findings serve as a roadmap for the design and creation of high-resolution 4D photonic microactuators
Light Tracking and Light Guiding Fiber Arrays by Adjusting the Location of Photoresponsive Azobenzene in Liquid Crystal Networks
The integration of light tracking and light guiding within fiber arrays is an intriguing challenge. In this study, an advanced drop casting/drawing method is applied to fabricate a fiber array capable of not only performing sunflower‐inspired light tracking, but also light guiding. The fiber arrays are constructed with various liquid crystal networks by adjusting the location of photoresponsive azobenzene moieties in the polymer network to understand the correlation between the extent of photoresponse and azobenzene location. Incorporating the azobenzene in the main chain oligomer renders these fibers with advanced photoresponse in both air and water. The fibers are able to track a light source and to guide the collected light, making these responsive actuator arrays potentially attractive for advanced photovoltaic and optical elements
An optical steam sterilization sensor based on a dual-responsive supramolecular cross-linked photonic polymer
An optical time–temperature steam sensor is presented based on the loss of structural color in a supramolecularly cross-linked cholesteric liquid crystal photonic coating. A gradual decrease in the selective reflection band is observed upon exposure to temperatures above 105 °C related to the cholesteric to isotropic transition temperature. The linear polymers with carboxylic acid side chains provide physical cross-linking through hydrogen bonding that allows a time–temperature-dependent order loss through the dynamic equilibrium between supramolecular dimer and free monomer states. Steam is accelerating the color loss, and autoclave experiments show that the photonic supramolecular polymer is applicable as a steam sterilization sensor for medical applications
3D test sample for the calibration and quality control of stimulated emission depletion (STED) and confocal microscopes
Multiple samples are required to monitor and optimize the quality and reliability of quantitative measurements of stimulated emission depletion (STED) and confocal microscopes. Here, we present a single sample to calibrate these microscopes, align their laser beams and measure their point spread function (PSF) in 3D. The sample is composed of a refractive index matched colloidal crystal of silica beads with fluorescent and gold cores. The microscopes can be calibrated in three dimensions using the periodicity of the crystal; the alignment of the laser beams can be checked using the reflection of the gold cores; and the PSF can be measured at multiple positions and depths using the fluorescent cores. It is demonstrated how this sample can be used to visualize and improve the quality of STED and confocal microscopy images. The sample is adjustable to meet the requirements of different NA objectives and microscopy techniques and additionally can be used to evaluate refractive index mismatches as a function of depth quantitativel