Observations of Toroidal Coupling for Low-N Alfven Modes in the Tca Tokamak

The antenna structure in the TCA tokamak is phased to excite preferentially Alfven waves with known toroidal and poloidal wave numbers. Surprisingly, the loading spectrum includes both discrete and continuum modes with poloidal wave numbers incompatible with the antenna phasing. These additional modes, which are important for our heating experiments, can be attributed to linear mode coupling induced by the toroidicity of the plasma column, when we take into account ion-cyclotron effects

Quantum dot containing nanocomposite thin films for phtoluminescent solar concentrators

Silicon oxide films containing CdS quantum dots have been deposited on glass substrates by a sol–gel dip-coating process. Hereby the CdS nanocrystals are grown during the thermal annealing step following the dip-coating procedure. Total hemispherical transmittance and reflectance measurements were carried out by means of a spectrophotometer coupled to an integrating sphere. For CdS-rich films, an absorption edge at photon energies in the vicinity of the band gap value of bulk CdS is observed. For lower CdS concentrations, the absorption edge shifts to higher photon energies, as expected for increasing quantum confinement. The samples show visible photoluminescence which is concentrated by total internal reflection and emitted at the edges of the substrate. The edge emission has been characterized by angle-dependent photoluminescent (PL) spectroscopy. Information on the lateral energy transport within the sample can be extracted from spectra obtained under spatial variation of the spot of excitation. The color of the photoluminescence can be tuned by varying the annealing temperature which governs crystal growth and thus the cluster size distribution. The characteristic features observed in the PL spectra clearly exhibit a blueshift for lower annealing temperatures, confirming the presence of quantum size effects. Advantages of the proposed concept of quantum dot containing coatings on glass panes for photoluminescent solar concentrators are the high potential for low-cost fabrication on the large scale and the suitability for architectural integration

Facade Integration of Solar Thermal Collectors:A Breakthrough?

One main barrier to the acceptability of façade use of solar thermal collectors is their black appearance and the visibility of piping or absorber irregularities through the glazing. To facilitate façade integration, a project was set up to develop selective filters reflecting only a small part of the solar spectrum in the visible range while letting the rest of the radiation heat the absorber. These filters were successfully produced and, combined with a diffusing glass treatment, have achieved the desired masking effect with minor impact on the collector efficiency (less than 10%). Glasses of various colours combined with several diffusing finishing (acid etching, structured glass etc…) can be produced that are able to hide the absorber. Such glazings will allow the use of the same product both in front of façade areas equipped with solar absorbers (as collector external glass) and in front of the non exposed areas (as façade cladding), opening the way to a broad variety of active façade designs. The active elements can then be positioned at will on the exposed areas, and their quantity determined only by thermal needs. By freeing the dimension of the façade area that can be clad with this glazing from the thermally needed surface for collectors, a major step to help architects use solar thermal on facades has been taken

Sol-gel deposition of nanostructured low refractive index materials on solar collector glazing

Nanoporous SiO2 and nanocomposite MgF2:SiO2 coatings have been deposited by sol gel dip-coating in a particle-free atmosphere. The refractive index of the prepared nanostructured thin films is determined from spectrophotometric data. In both cases, significantly lower values than for compact SiO2 have been achieved. Highly transparent samples have been produced in a single dip-coating step followed by simple thermal annealing in air. Broad spectral transmittance maxima are observed exceeding values of 98.5% (nanoporous SiO2) and 99.5% (quaternary Mg:F:Si:O films). MgF2:SiO2 nanocomposite thin films can be expected to exhibit a higher aging stability than porous SiO2 films with respect to pore-filling by hydrocarbons and are therefore a promising alternative as well for single-layered anti reflection coatings as for multilayered coulored coatings on solar collector glazing

Tetrabenzoporphyrin and -mono-, - Cis -di- and tetrabenzotriazaporphyrin derivatives: Electrochemical and spectroscopic implications of meso CH Group replacement with nitrogen

Nonperipherally hexyl-substituted metal-free tetrabenzoporphyrin (2H-TBP, 1a) tetrabenzomonoazaporphyrin (2H-TBMAP, 2a), tetrabenzo-cis-diazaporphyrin (2H-TBDAP, 3a), tetrabenzotriazaporphyrin (2H-TBTAP, 4a), and phthalocyanine (2H-Pc, 5a), as well as their copper complexes (1b-5b), were synthesized. As the number of meso nitrogen atoms increases from zero to four, Îmax of the Q-band absorption peak becomes red-shifted by almost 100 nm, and extinction coefficients increased at least threefold. Simultaneously the blue-shifted Soret (UV) band substantially decreased in intensity. These changes were related to the relative electron-density of each macrocycle expressed as the group electronegativity sum of all meso N and CH atom groups, âχR. X-ray photoelectron spectroscopy differentiated between the three different types of macrocyclic nitrogen atoms (the Ninner, (NH)inner, and Nmeso) in the metal-free complexes. Binding energies of the Nmeso and Ninner,Cu atoms in copper chelates could not be resolved. Copper insertion lowered especially the cathodic redox potentials, while all four observed redox processes occurred at larger potentials as the number of meso nitrogens increased. Computational chemical methods using density functional theory confirmed 1b to exhibit a Cu(II) reduction prior to ring-based reductions, while for 2b, Cu(II) reduction is the first reductive step only if the nonperipheral substituents are hydrogen. When they are methyl groups, it is the second reduction process; when they are ethyl, propyl, or hexyl, it becomes the third reductive process. Spectro-electrochemical measurements showed redox processes were associated with a substantial change in intensity of at least two main absorbances (the Q and Soret bands) in the UV spectra of these compounds

Sol-gel deposition and characterization of low refractive index nanocomposite Mg:F:Si:O thin films for solar and protective coatings

Coatings for thermal solar energy conversion have to be abrasion-resistant, stable at elevated temperatures, and often have to protect the substrate against corrosion. Due to the conditions of refractive index matching between the substrate and the ambient air, low refractive index materials are desired regarding a large variety of optical applications. Novel nanocomposite thin films based on the elements Mg, F, Si and O have been deposited by a sol-gel dip-coating process starting from trifluoroacetic acid, magnesium acetate and alcoxide precursors. Optical properties of this new material have been characterised by spectrophotometry and spectral ellipsometry, and show surprisingly low refractive index values. The experimental data obtained for varying chemical composition have been compared to the optical properties as predicted by Bruggeman and Ping-Sheng effective medium theories. Strong deviations from both theories are reported, suggesting modifications of the involved crystalline phases and/or formation of nanopores. Evidence for embedded crystalline nanoparticles has been found by Transmission Electron Microscopy (TEM). Compared to well known existing low refractive index materials such as porous SiO2 and MgF2, the quaternary Mg:F:Si:O thin films can be expected to show higher hardness and improved aging stability with respect to pore filling by hydrocarbons. The novel thin film material opens promising perspectives for new solar and protective coatings