209 research outputs found
Magnetic versus nonmagnetic doping effects on the magnetic ordering in the Haldane chain compound PbNi2V2O8
A study of an impurity driven phase-transition into a magnetically ordered
state in the spin-liquid Haldane chain compound PbNi2V2O8 is presented. Both,
macroscopic magnetization as well as 51V nuclear magnetic resonance (NMR)
measurements reveal that the spin nature of dopants has a crucial role in
determining the stability of the induced long-range magnetic order. In the case
of nonmagnetic (Mg2+) doping on Ni2+ spin sites (S=1) a metamagnetic transition
is observed in relatively low magnetic fields. On the other hand, the magnetic
order in magnetically (Co2+) doped compounds survives at much higher magnetic
fields and temperatures, which is attributed to a significant anisotropic
impurity-host magnetic interaction. The NMR measurements confirm the predicted
staggered nature of impurity-liberated spin degrees of freedom, which are
responsible for the magnetic ordering. In addition, differences in the
broadening of the NMR spectra and the increase of nuclear spin-lattice
relaxation in doped samples, indicate a diverse nature of electron spin
correlations in magnetically and nonmagnetically doped samples, which begin
developing at rather high temperatures with respect to the antiferromagnetic
phase transition.Comment: 10 pages, 7 figure
Dzyaloshinsky-Moriya interaction in vesignieite: A route to freezing in a quantum kagome antiferromagnet
We report an electron spin resonance investigation of the geometrically
frustrated spin-1/2 kagome antiferromagnet vesignieite,
BaCuVO(OH). Analysis of the line widths and line shifts
indicates the dominance of in-plane Dzyaloshinsky-Moriya anisotropy that is
proposed to suppress strongly quantum spin fluctuations and thus to promote
long-range ordering rather than a spin-liquid state. We also evidence an
enhanced spin-phonon contribution that might originate from a lattice
instability and discuss the origin of a low-temperature mismatch between
intrinsic and bulk susceptibility in terms of local inhomogeneity
Electron Spin Resonance of SrCu2(BO3)2 at High Magnetic Field
We calculate the electron spin resonance (ESR) spectra of the
quasi-two-dimensional dimer spin liquid SrCu2(BO3)2 as a function of magnetic
field B. Using the standard Lanczos method, we solve a Shastry-Sutherland
Hamiltonian with additional Dzyaloshinsky-Moriya (DM) terms which are crucial
to explain different qualitative aspects of the ESR spectra. In particular, a
nearest-neighbor DM interaction with a non-zero D_z component is required to
explain the low frequency ESR lines for B || c. This suggests that crystal
symmetry is lowered at low temperatures due to a structural phase transition.Comment: 4 pages, 4 b&w figure
Quantum Kagome antiferromagnet ZnCu3(OH)6Cl2
The frustration of antiferromagnetic interactions on the loosely connected
kagome lattice associated to the enhancement of quantum fluctuations for S=1/2
spins was acknowledged long ago as a keypoint to stabilize novel ground states
of magnetic matter. Only very recently, the model compound Herbersmithite,
ZnCu3(OH)6Cl2, a structurally perfect kagome antiferromagnet, could be
synthesized and enables a close comparison to theories. We review and classify
various experimental results obtained over the past years and underline some of
the pending issues.Comment: 23 pages, 16 figures, invited paper in J. Phys. Soc. Jpn, special
topics issue on "Novel States of Matter Induced by Frustration", to be
published in Jan. 201
Recovering Metallicity in A4C60: The Case of Monomeric Li4C60
The restoration of metallicity in the high-temperature, cubic phase of Li4C60
represents a remarkable feature for a member of the A4C60 family (A = alkali
metal), invariably found to be insulators. Structural and resonance technique
investigations on Li4C60 at T > 600 K, show that its fcc structure is
associated with a complete (4e) charge transfer to C60 and a sparsely populated
Fermi level. These findings not only emphasize the crucial role played by
lattice symmetry in fulleride transport properties, but also re-dimension the
role of Jahn-Teller effects in band structure determination. Moreover, they
suggest the present system as a potential precursor to a new class of
superconducting fullerides.Comment: 4 pages, 3 figure
Spin dynamics and disorder effects in the S=1/2 kagome Heisenberg spin liquid phase of kapellasite
We report Cl NMR, ESR, SR and specific heat measurements on the
frustrated kagom\'e magnet kapellasite,
CuZn(OH)Cl, where a gapless spin liquid phase is
stabilized by a set of competing exchange interactions. Our measurements
confirm the ferromagnetic character of the nearest-neighbour exchange
interaction and give an energy scale for the competing interactions K. The study of the temperature-dependent ESR lineshift reveals a
moderate symmetric exchange anisotropy term , with %. These
findings validate a posteriori the use of the Heisenberg
model to describe the magnetic properties of kapellasite [Bernu et al., Phys.
Rev. B 87, 155107 (2013)]. We further confirm that the main deviation from this
model is the severe random depletion of the magnetic kagom\'e lattice by 27%,
due to Cu/Zn site mixing, and specifically address the effect of this disorder
by Cl NMR, performed on an oriented polycrystalline sample.
Surprisingly, while being very sensitive to local structural deformations, our
NMR measurements demonstrate that the system remains homogeneous with a unique
spin susceptibility at high temperature, despite a variety of magnetic
environments. Unconventional spin dynamics is further revealed by NMR and
SR in the low-, correlated, spin liquid regime, where a broad
distribution of spin-lattice relaxation times is observed. We ascribe this to
the presence of local low-energy modes.Comment: 15 pages, 11 figures. To appear in Phys. Rev.
X-Band ESR Determination of Dzyaloshinsky-Moriya Interaction in 2D SrCu(BO) System
X-band ESR measurements on a single crystal of SrCu(BO) system in
a temperature range between 10 K and 580 K are presented. The temperature and
angular dependence of unusually broad ESR spectra can be explained by the
inclusion of antisymmetric Dzyaloshinsky-Moriya (DM) interaction, which yields
by far the largest contribution to the linewidth. However, the well-accepted
picture of only out-of-plane interdimer DM vectors is not sufficient for
explanation of the observed angular dependence. In order to account for the
experimental linewidth anisotropy we had to include sizable in-plane components
of interdimer as well as intradimer DM interaction in addition to the
out-of-plane interdimer one. The nearest-neighbor DM vectors lie perpendicular
to crystal anisotropy c-axis due to crystal symmetry. We also emphasize that
above the structural phase transition occurring at 395 K dynamical mechanism
should be present allowing for instantaneous DM interactions. Moreover, the
linewidth at an arbitrary temperature can be divided into two contributions;
namely, the first part arising from spin dynamics governed by the spin
Hamiltonian of the system and the second part due to significant spin-phonon
coupling. The nature of the latter mechanism is attributed to phonon-modulation
of the antisymmetric interaction, which is responsible for the observed linear
increase of the linewidth at high temperatures.Comment: 17 pages, 4 figures, submitted to PR
Multiferroic FeTeOBr: Alternating spin chains with frustrated interchain interactions
A combination of density functional theory calculations, many-body model
considerations, magnetization and electron spin resonance measurements shows
that the multiferroic FeTeOBr should be described as a system of
alternating antiferromagnetic chains with strong Fe-O-Te-O-Fe bridges
weakly coupled by two-dimensional frustrated interactions, rather than the
previously reported tetramer models. The peculiar temperature dependence of the
incommensurate magnetic vector can be explained in terms of interchain exchange
striction being responsible for the emergent net electric polarization.Comment: 7 pages, 6 figure
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