Compute-first optical detection for noise-resilient visual perception

In the context of visual perception, the optical signal from a scene is transferred into the electronic domain by detectors in the form of image data, which are then processed for the extraction of visual information. In noisy and weak-signal environments such as thermal imaging for night vision applications, however, the performance of neural computing tasks faces a significant bottleneck due to the inherent degradation of data quality upon noisy detection. Here, we propose a concept of optical signal processing before detection to address this issue. We demonstrate that spatially redistributing optical signals through a properly designed linear transformer can enhance the detection noise resilience of visual perception tasks, as benchmarked with the MNIST classification. Our idea is supported by a quantitative analysis detailing the relationship between signal concentration and noise robustness, as well as its practical implementation in an incoherent imaging system. This compute-first detection scheme can pave the way for advancing infrared machine vision technologies widely used for industrial and defense applications

Efficiency above the Shockley–Queisser Limit by Using Nanophotonic Effects To Create Multiple Effective Bandgaps With a Single Semiconductor

We present a pure photonic approach to overcome the Shockley–Queisser limit. A single material can show different effective bandgap, set by its absorption spectrum, which depends on its photonic structure. In a tandem cell configuration constructed from a single material, one can achieve two different effective bandgaps, thereby exceeding the Shockley–Queisser limit

Large-Scale Spinning of Silver Nanofibers as Flexible and Reliable Conductors

Conducting metal nanowires can be assembled into thin films for flexible electronics and optoelectronics applications including transparent electrodes, nanocircuits, and electronic skin, however, the junction resistances and low aspect ratios still limit its performance. Herein we report high-quality silver nanofibers (AgNFs) synthesized by a gas-assistant solution spinning method. Compared with traditional Ag nanowires that usually have lengths below 100 μm, AgNFs are infinitely long and can be easily assembled into large-scale 2D and 3D flexible conductors with fused junctions between nanofibers. The AgNF networks showed high transparency, low sheet resistance (e. g, 6 Ω sq^–1 at ∼97% transparency), and high flexibility as transparent electrodes, whereas the 3D AgNF sponge could be used as a deformable and robust 3D conductor

Hybrid Silicon Nanocone–Polymer Solar Cells

Recently, hybrid Si/organic solar cells have been studied for low-cost Si photovoltaic devices because the Schottky junction between the Si and organic material can be formed by solution processes at a low temperature. In this study, we demonstrate a hybrid solar cell composed of Si nanocones and conductive polymer. The optimal nanocone structure with an aspect ratio (height/diameter of a nanocone) less than two allowed for conformal polymer surface coverage via spin-coating while also providing both excellent antireflection and light trapping properties. The uniform heterojunction over the nanocones with enhanced light absorption resulted in a power conversion efficiency above 11%. Based on our simulation study, the optimal nanocone structures for a 10 μm thick Si solar cell can achieve a short-circuit current density, up to 39.1 mA/cm², which is very close to the theoretical limit. With very thin material and inexpensive processing, hybrid Si nanocone/polymer solar cells are promising as an economically viable alternative energy solution

Extraordinary Photoluminescence and Strong Temperature/Angle-Dependent Raman Responses in Few-Layer Phosphorene

Phosphorene is a new family member of two-dimensional materials. We observed strong and highly layer-dependent photoluminescence in few-layer phosphorene (two to five layers). The results confirmed the theoretical prediction that few-layer phosphorene has a direct and layer-sensitive band gap. We also demonstrated that few-layer phosphorene is more sensitive to temperature modulation than graphene and MoS₂ in Raman scattering. The anisotropic Raman response in few-layer phosphorene has enabled us to use an optical method to quickly determine the crystalline orientation without tunneling electron microscopy or scanning tunneling microscopy. Our results provide much needed experimental information about the band structures and exciton nature in few-layer phosphorene

Extreme Light Management in Mesoporous Wood Cellulose Paper for Optoelectronics

Wood fibers possess natural unique hierarchical and mesoporous structures that enable a variety of new applications beyond their traditional use. We dramatically modulate the propagation of light through random network of wood fibers. A highly transparent and clear paper with transmittance >90% and haze <1.0% applicable for high-definition displays is achieved. By altering the morphology of the same wood fibers that form the paper, highly transparent and hazy paper targeted for other applications such as solar cell and antiglare coating with transmittance >90% and haze >90% is also achieved. A thorough investigation of the relation between the mesoporous structure and the optical properties in transparent paper was conducted, including full-spectrum optical simulations. We demonstrate commercially competitive multitouch touch screen with clear paper as a replacement for plastic substrates, which shows excellent process compatibility and comparable device performance for commercial applications. Transparent cellulose paper with tunable optical properties is an emerging photonic material that will realize a range of much improved flexible electronics, photonics, and optoelectronics

Two-Dimensional Chalcogenide Nanoplates as Tunable Metamaterials via Chemical Intercalation

New plasmonic materials with tunable properties are in great need for nanophotonics and metamaterials applications. Here we present two-dimensional layered, metal chalcogenides as tunable metamaterials that feature both dielectric photonic and plasmonic modes across a wide spectral range from the infrared to ultraviolet. The anisotropic layered structure allows intercalation of organic molecules and metal atoms at the van der Waals gap of the host chalcogenide, presenting a chemical route to create heterostructures with molecular and atomic precision for photonic and plasmonic applications. This marks a departure from a lithographic method to create metamaterials. Monochromated electron energy-loss spectroscopy in a scanning transmission electron microscope was used to first establish the presence of the dielectric photonic and plasmonic modes in M₂E₃ (M = Bi, Sb; E = Se, Te) nanoplates and to observe marked changes in these modes after chemical intercalation. We show that these modal properties can also be tuned effectively by more conventional methods such as thickness control and alloy composition of the nanoplates

Two-Dimensional Chalcogenide Nanoplates as Tunable Metamaterials via Chemical Intercalation

New plasmonic materials with tunable properties are in great need for nanophotonics and metamaterials applications. Here we present two-dimensional layered, metal chalcogenides as tunable metamaterials that feature both dielectric photonic and plasmonic modes across a wide spectral range from the infrared to ultraviolet. The anisotropic layered structure allows intercalation of organic molecules and metal atoms at the van der Waals gap of the host chalcogenide, presenting a chemical route to create heterostructures with molecular and atomic precision for photonic and plasmonic applications. This marks a departure from a lithographic method to create metamaterials. Monochromated electron energy-loss spectroscopy in a scanning transmission electron microscope was used to first establish the presence of the dielectric photonic and plasmonic modes in M₂E₃ (M = Bi, Sb; E = Se, Te) nanoplates and to observe marked changes in these modes after chemical intercalation. We show that these modal properties can also be tuned effectively by more conventional methods such as thickness control and alloy composition of the nanoplates

Enhanced Performance of Ge Photodiodes <i>via</i> Monolithic Antireflection Texturing and α‑Ge Self-Passivation by Inverse Metal-Assisted Chemical Etching

Surface antireflection micro and nanostructures, normally formed by conventional reactive ion etching, offer advantages in photovoltaic and optoelectronic applications, including wider spectral wavelength ranges and acceptance angles. One challenge in incorporating these structures into devices is that optimal optical properties do not always translate into electrical performance due to surface damage, which significantly increases surface recombination. Here, we present a simple approach for fabricating antireflection structures, with self-passivated amorphous Ge (α-Ge) surfaces, on single crystalline Ge (c-Ge) surface using the inverse metal-assisted chemical etching technology (I-MacEtch). Vertical Schottky Ge photodiodes fabricated with surface structures involving arrays of pyramids or periodic nano-indentations show clear improvements not only in responsivity, due to enhanced optical absorption, but also in dark current. The dark current reduction is attributed to the Schottky barrier height increase and self-passivation effect of the i-MacEtch induced α-Ge layer formed on top of the c-Ge surface. The results demonstrated in this work show that MacEtch can be a viable technology for advanced light trapping and surface engineering in Ge and other semiconductor based optoelectronic devices