Observation of condensed phases of quasi-planar core-softened colloids

We experimentally study the condensed phases of repelling core-softened spheres in two dimensions. The dipolar pair repulsion between superparamagnetic spheres trapped in a thin cell is induced by a transverse magnetic field and softened by suitably adjusting the cell thickness. We scan a broad density range and we materialize a large part of the theoretically predicted phases in systems of core-softened particles, including expanded and close-packed hexagonal, square, chain-like, stripe/labyrinthine, and honeycomb phase. Further insight into their structure is provided by Monte Carlo simulations

Aggregates of two-dimensional vesicles: Rouleaux and sheets

Using both numerical and variational minimization of the bending and adhesion energy of two-dimensional lipid vesicles, we study their aggregation, and we find that the stable aggregates include an infinite number of vesicles and that they arrange either in a columnar or in a sheet-like structure. We calculate the stability diagram and we discuss the modes of transformation between the two types of aggregates, showing that they include disintegration as well as intercalation.Comment: 4 figure

Limiting shapes of confined lipid vesicles

We theoretically study the shapes of lipid vesicles confined to a spherical cavity, elaborating a framework based on the so-called limiting shapes constructed from geometrically simple structural elements such as double-membrane walls and edges. Partly inspired by numerical results, the proposed non-compartmentalized and compartmentalized limiting shapes are arranged in the bilayer-couple phase diagram which is then compared to its free-vesicle counterpart. We also compute the area-difference-elasticity phase diagram of the limiting shapes and we use it to interpret shape transitions experimentally observed in vesicles confined within another vesicle. The limiting-shape framework may be generalized to theoretically investigate the structure of certain cell organelles such as the mitochondrion

Soft Spheres Make More Mesophases

We use both mean-field methods and numerical simulation to study the phase diagram of classical particles interacting with a hard-core and repulsive, soft shoulder. Despite the purely repulsive interaction, this system displays a remarkable array of aggregate phases arising from the competition between the hard-core and shoulder length scales. In the limit of large shoulder width to core size, we argue that this phase diagram has a number of universal features, and classify the set of repulsive shoulders that lead to aggregation at high density. Surprisingly, the phase sequence and aggregate size adjusts so as to keep almost constant inter-aggregate separation.Comment: 4 pages, 2 included figure

Casimir Torques between Anisotropic Boundaries in Nematic Liquid Crystals

Fluctuation-induced interactions between anisotropic objects immersed in a nematic liquid crystal are shown to depend on the relative orientation of these objects. The resulting long-range ``Casimir'' torques are explicitely calculated for a simple geometry where elastic effects are absent. Our study generalizes previous discussions restricted to the case of isotropic walls, and leads to new proposals for experimental tests of Casimir forces and torques in nematics.Comment: 4 pages, 1 figur

Axially symmetric membranes with polar tethers

Axially symmetric equilibrium configurations of the conformally invariant Willmore energy are shown to satisfy an equation that is two orders lower in derivatives of the embedding functions than the equilibrium shape equation, not one as would be expected on the basis of axial symmetry. Modulo a translation along the axis, this equation involves a single free parameter c.If c\ne 0, a geometry with spherical topology will possess curvature singularities at its poles. The physical origin of the singularity is identified by examining the Noether charge associated with the translational invariance of the energy; it is consistent with an external axial force acting at the poles. A one-parameter family of exact solutions displaying a discocyte to stomatocyte transition is described.Comment: 13 pages, extended and revised version of Non-local sine-Gordon equation for the shape of axi-symmetric membrane

Interfaces in Diblocks: A Study of Miktoarm Star Copolymers

We study AB$_n$ miktoarm star block copolymers in the strong segregation limit, focussing on the role that the AB interface plays in determining the phase behavior. We develop an extension of the kinked-path approach which allows us to explore the energetic dependence on interfacial shape. We consider a one-parameter family of interfaces to study the columnar to lamellar transition in asymmetric stars. We compare with recent experimental results. We discuss the stability of the A15 lattice of sphere-like micelles in the context of interfacial energy minimization. We corroborate our theory by implementing a numerically exact self-consistent field theory to probe the phase diagram and the shape of the AB interface.Comment: 12 pages, 11 included figure

Soap Froths and Crystal Structures

We propose a physical mechanism to explain the crystal symmetries found in macromolecular and supramolecular micellar materials. We argue that the packing entropy of the hard micellar cores is frustrated by the entropic interaction of their brush-like coronas. The latter interaction is treated as a surface effect between neighboring Voronoi cells. The observed crystal structures correspond to the Kelvin and Weaire-Phelan minimal foams. We show that these structures are stable for reasonable areal entropy densities.Comment: 4 pages, RevTeX, 2 included eps figure