Anisotropic Rolling and Controlled Chirality of Nanocrystalline Diamond Nanomembranes toward Biomimetic Helical Frameworks

Future advances in materials will be aided by improved dimensional control in fabrication of 3D hierarchical structures. Self-rolling technology provides additional degrees of freedom in 3D design by enabling an arbitrary rolling direction with controllable curvature. Here, we demonstrate that deterministic helical structures with variable rolling directions can be formed through releasing a strained nanomembrane patterned in a “utility knife” shape. The asymmetry of the membrane shape provides anisotropic driving force generated by the disparity between the etching rates along different sides in this asymmetric shape. A transient finite element method (FEM) model of diagonal rolling is established to analyze the relationships among geometries, elastic properties, and boundary conditions. On the basis of this model, a diamond-based helical framework consisting of two or three helical segments has been fabricated to mimic the shapes of natural plants. Further experiment has been done to extend this approach to other materials and material combinations, such as MoSe₂/Cr, Cr/Pt, and VO₂. To demonstrate the possible application accessible by our technology to new fields, VO₂-based helical microscale actuation has been demonstrated with photocontrollable bending in a selected region, as well as morphable and recognizable helix. This study offers a new way to construct helical mesostructures that combine special properties of the advanced materials, thus possess novel features and potential applications

Reconfigurable Vanadium Dioxide Nanomembranes and Microtubes with Controllable Phase Transition Temperatures

Two additional structural forms, free-standing nanomembranes and microtubes, are reported and added to the vanadium dioxide (VO₂) material family. Free-standing VO₂ nanomembranes were fabricated by precisely thinning as-grown VO₂ thin films and etching away the sacrificial layer underneath. VO₂ microtubes with a range of controllable diameters were rolled-up from the VO₂ nanomembranes. When a VO₂ nanomembrane is rolled-up into a microtubular structure, a significant compressive strain is generated and accommodated therein, which decreases the phase transition temperature of the VO₂ material. The magnitude of the compressive strain is determined by the curvature of the VO₂ microtube, which can be rationally and accurately designed by controlling the tube diameter during the rolling-up fabrication process. The VO₂ microtube rolling-up process presents a novel way to controllably tune the phase transition temperature of VO₂ materials over a wide range toward practical applications. Furthermore, the rolling-up process is reversible. A VO₂ microtube can be transformed back into a nanomembrane by introducing an external strain. Because of its tunable phase transition temperature and reversible shape transformation, the VO₂ nanomembrane-microtube structure is promising for device applications. As an example application, a tubular microactuator device with low driving energy but large displacement is demonstrated at various triggering temperatures

Reconfigurable Vanadium Dioxide Nanomembranes and Microtubes with Controllable Phase Transition Temperatures

Two additional structural forms, free-standing nanomembranes and microtubes, are reported and added to the vanadium dioxide (VO₂) material family. Free-standing VO₂ nanomembranes were fabricated by precisely thinning as-grown VO₂ thin films and etching away the sacrificial layer underneath. VO₂ microtubes with a range of controllable diameters were rolled-up from the VO₂ nanomembranes. When a VO₂ nanomembrane is rolled-up into a microtubular structure, a significant compressive strain is generated and accommodated therein, which decreases the phase transition temperature of the VO₂ material. The magnitude of the compressive strain is determined by the curvature of the VO₂ microtube, which can be rationally and accurately designed by controlling the tube diameter during the rolling-up fabrication process. The VO₂ microtube rolling-up process presents a novel way to controllably tune the phase transition temperature of VO₂ materials over a wide range toward practical applications. Furthermore, the rolling-up process is reversible. A VO₂ microtube can be transformed back into a nanomembrane by introducing an external strain. Because of its tunable phase transition temperature and reversible shape transformation, the VO₂ nanomembrane-microtube structure is promising for device applications. As an example application, a tubular microactuator device with low driving energy but large displacement is demonstrated at various triggering temperatures

Multifunctional Nanocracks in Silicon Nanomembranes by Notch-Assisted Transfer Printing

Manipulating nanocracks to produce various nanodevices has attracted increasing interest. Here, based on the mature transfer printing technique, a novel notch-assisted transfer printing technique was engaged to produce nanocracks by simply introducing notch structures into the transferred nanomembranes. Both experiments and finite element simulations were used to elucidate the probability of nanocrack formation during the transfer process, and the results demonstrated that the geometry of nanomembranes played a key role in concentrating stress and producing nanocracks. We further demonstrated that the obtained nanocrack can be used as a surface-enhanced Raman scattering substrate because of the significant enhancement of electric fields. In addition, the capillary condensation of water molecules in the nanocrack led to an obvious change of resistance, thus providing an opportunity for the crack-based structure to be used as an ultrasensitive humidity sensor. The current approach can be applied to producing nanocracks from multiple materials and will have important applications in the field of nanodevices

Asymmetrically Curved Hyperbolic Metamaterial Structure with Gradient Thicknesses for Enhanced Directional Spontaneous Emission

We demonstrate hyperbolic metamaterials (HMMs) on a curved surface for an efficient outcoupling of nonradiative modes, which lead to an enhanced spontaneous emission. Those high-wavevector plasmonic modes can propagate along the curved structure and emit into the far field, realizing a directional light emission with maximal fluorescent intensity. Detailed simulations disclose a high Purcell factor and a spatial power distribution in the curved HMM, which agrees with the experimental result. Our work presents remarkable enhancing capability in both the Purcell factor and emission intensity, which could suggest a unique structure design in metamaterials for potential application in, e.g., high-speed optical sensing and communications